**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4771-80-6 |3-Cyclohexenecarboxylic acid | 97.0 | 225-314-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 21 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Irritating to eyes, respiratory system
and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation. May be fatal if absorbed through the
skin.
Ingestion:
Causes digestive tract irritation.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Provide ventilation. Cover with dry earth, dry
sand, or other non-combustible material followed with plastic sheet
to minimize spreading and contact with water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4771-80-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 128 - 131 C @18 mmHg
Freezing/Melting Point: 17 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.08
Molecular Formula: C7H10O2
Molecular Weight: 126.0688
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
No data available.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4771-80-6: GW3675000
LD50/LC50:
CAS# 4771-80-6: Draize test, rabbit, skin: 5 mg/24H Severe; Oral,
rat: LD50 = 4260 mg/kg; Skin, rabbit: LD50 = 1 mL/kg.
Carcinogenicity:
3-Cyclohexenecarboxylic acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21 Harmful in contact with skin.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 4771-80-6: No information available.
Canada
CAS# 4771-80-6 is listed on Canada's NDSL List.
CAS# 4771-80-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4771-80-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/04/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dipiperidinomethane, 99%
| 880-09-1 |
|
2,2,6,6-Tetramethylpiperdine Hydrobromide
| 935-21-7 |
|
Aqualine Electrolyte A
| 67-56-1 |
|
Aqualine Electrolyte C
| 56-23-5 |
|
2-Butynoic Acid, 98%
| 590-93-2 |
|
Methyl palmitate ,95%
| 112-39-0 |
|
3-Cyclohexenecarboxylic acid, 97%(GC)
| 4771-80-6 |
|
N-Methylaniline, p.a.
| 100-61-8 |
|
Acetic acid, 75%
| 64-19-7 |
|
Dimanganese decacarbonyl, 98%
| 10170-69-1 |
|
2,3:5,6-Di-O-Isopropylidene-Alpha-D-Mannofuranose, 98%
| 14131-84-1 |
|
Quinalizarin, 95% (uv-vis)
| 81-61-8 |
|
Methyl 4-Fluorophenylacetate
| 34837-84-8 |
|
N,N'-Dicyclohexyl-4-Morpholinecarboxamide
| 4975-73-9 |
|
2-Bromobenzoyl chloride, 98%
| 7154-66-7 |
|
ICP Standard Metal Solution in Nitric Acid
| 7697-37-2 |
|
ICP Standard Metal Solution in 1% Nitric Acid
| 7697-37-2 |
|
4-Bromo Trityl Imidazole
| 0-00-1 |
|
ICP Standard Metal Solution in 2% Nitric Acid
| 7697-37-2 |
|
Barrier Coating Solution
| 64-17-5 |
|
Hexanes, pesticide residue analysis grade
| 110-54-3 |
|
Ethyl isocyanatoacetate, 99+% (gc)
| 2949-22-6 |
|
Ethyl bis(2,4-dinitrophenyl)acetate
| 5833-18-1 |
|
Bis(4-Chlorophenyl)diselenide, 98%
| 20541-49-5 |
|
Chlorodimethylsilane, 96% (gc)
| 1066-35-9 |
|
Acetic acid, 33%
| 64-19-7 |
|
Protran 2 Solution
| 109-99-9 |
|
Tripopionin, 97%
| 139-45-7 |
|
CIPAC A, C and D Solutions
| 7439-95-4 |
|
Methyl 2-Chloro-6-Fluorophenylacetate
| 103473-99-0 |
|
Methyl 1-Benzyl-5-Oxo-3-Pyrrolidine-Carboxylate, 98%
| 51535-00-3 |
|
1,3,5-Tri-Tert-Butylbenzene
| 1460-02-2 |
|
Triisopropylorthoformate, 95%
| 4447-60-3 |
|
Five Alcohol Custom Blend
| 67-63-0 |
|
Bis(Dimethylamino)Dimethylsilane, 96%
| 3768-58-9 |
|
Perfluoro Hexanoic Acid
| 307-24-4 |
|
2-Aminomethylpyrimidine
| 75985-45-4 |
|
2-Pyrimidinethiocarboxamide
| 4537-73-9 |
|
0.05-0.5M Iodine in 90% pyridine/10% water
| 110-86-1 |
|
1H-Tetrazole
| 288-94-8 |
|
P-Cyanopentylbenzene
| 10270-29-8 |
|
Allyl-2-(hydroxy)isobutyrate
| 19444-21-4 |
|
N,N-Dimethylformamide-D7, Packaged in 0.75ml Ampules, 99.5 Atom % D
| 4472-41-7 |
|
4.625% w/v Hydrochloric acid
| 7647-01-0 |
|
Dichloroacetic acid, 3% in toluene
| 79-43-6 |
|
trans-2-Octene, 98%
| 13389-42-9 |
|
DL-Alpha-Methoxyphenylacetic Acid, 99% (Titr.)
| 7021-09-2 |
|
SDS Page Solution Kit
| 77-86-1 |
|
N-Trityl-Imidazolpyruvic Acid
| 0-00-1 |
|
BOC-6-Amino-2-Oxo-Hexanoic Acid
| 0-00-1 |
|
|