**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 496-72-0 |3,4-Diaminotoluene | 97% | 207-826-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 36/37/38 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Limited evidence of
a carcinogenic effect.Possible risks of irreversible effects.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. May cause central nervous
system depression.
Inhalation:
Causes respiratory tract irritation. May cause cardiac
abnormalities. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed. Possible risk of irreversible effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode when heated. Non-combustible, substance itself does not
burn but may decompose upon heating to produce irritating, corrosive
and/or toxic fumes. Runoff from fire control or dilution water may
cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. For small fires,
use dry chemical, carbon dioxide, or water spray. For large fires,
use dry chemical, carbon dioxide, alcohol-resistant foam, or water
spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 496-72-0:
Germany: (listed as toluene 2,4-diamine): Skin absorber
Russia: (listed as toluene 2,4-diamine): 2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Chips
Color: light brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 155 - 156 deg C @ 18.00mmHg
Freezing/Melting Point: 88.00 - 90.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 16 g/l (20 c)
Specific Gravity/Density:
Molecular Formula: C7H10N2
Molecular Weight: 122.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 496-72-0: XS9820000
LD50/LC50:
Not available.
Carcinogenicity:
3,4-Diaminotoluene -
California: carcinogen, initial date 1/1/88 (listed as Toluene 2,4-dia
NTP: Suspect carcinogen (listed as Toluene 2,4-diamine).
IARC: Group 2B carcinogen (listed as Toluene 2,4-diamine).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
USA RQ: CAS# 496-72-0: 10 lb final RQ (Listed under Toluenediamine); 4.54 kg fin
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 496-72-0: 2
Canada
CAS# 496-72-0 is listed on Canada's NDSL List.
CAS# 496-72-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 496-72-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dihydrocholesterol, 96%
| 80-97-7 |
|
1-Iodododecane, 98%
| 4292-19-7 |
|
Olivetol , 98%
| 500-66-3 |
|
Cis-3-Hexenoic Acid
| 4219-24-3 |
|
3,5-Di-tert-butyl-o-benzoquinone, 98%
| 3383-21-9 |
|
Tetrabromophenol Blue, Water Soluble
| 4430-25-5 |
|
O-Arsanilic Acid, 98%
| 2045-00-3 |
|
1,5-Diazabicyclo[4,3,0]non-5-ene, 98%
| 3001-72-7 |
|
2-Fluorobiphenyl, 97%
| 321-60-8 |
|
1,8-Dinitronaphthalene, 85+%
| 602-38-0 |
|
DL-P-Fluorophenylalanine, 97%
| 51-65-0 |
|
3,5-Dimethylpyrazole-1-Carbinol 99%
| 85264-33-1 |
|
4-Hydroxy-2,2,6,6-Tetramethylpiperidinooxy - Free Radical
| 2226-96-2 |
|
n,n-Dimethyl-n'-ethylethylenediamine, 98%
| 123-83-1 |
|
Molecular Sieves, 4A, 4 to 8 Mesh
| 0-00-1 |
|
(S)-(-)-Alpha, Alpha-Diphenyl-2-Pyrrolidinemethanol, 99+%
| 112068-01-6 |
|
1-Methylisatin, 98%
| 2058-74-4 |
|
2,6-Lutidine-Alpha-2,3-Diol, 99%
| 42097-42-7 |
|
Safrole, 97%
| 94-59-7 |
|
Isobutyrophenone, 97%
| 611-70-1 |
|
2-Chloro-4-nitrophenol, 96%
| 619-08-9 |
|
3,4-Diaminotoluene, 97%
| 496-72-0 |
|
4-Benzyloxy-3-methoxystyrene, 95%
| 55708-65-1 |
|
Acetylferrocene, 95%
| 1271-55-2 |
|
Yohimbine hydrochloride, 99%
| 65-19-0 |
|
4-Methyl-6,7-Bis(Sulfoxy)-2H-1-Benzopyran-2-One,Disodium
| 29334-07-4 |
|
o-Chlorophenylacetic acid, 98.5+%
| 2439-55-6 |
|
N-epsilon-Acetyl-L-lysine, 99%
| 692-04-6 |
|
4-Methyl-2-nitroaniline, 99%
| 89-62-3 |
|
2-(Hexamethyleneimino)-Ethyl Chloride Hydrochloride, 98%
| 26487-67-2 |
|
1-Piperonylpiperazine, 97%
| 32231-06-4 |
|
Octadecanamide, tech., ca 60%
| 124-26-5 |
|
2-(Bromomethyl)-2-(2,4-Dichlorophenyl)- 1,3-Dioxolane, 98%
| 60207-30-9 |
|
4-Methoxymetanilyl Fluoride, 97%
| 498-74-8 |
|
2,2,6,6-Tetramethylpiperidinooxy, 98%
| 2564-83-2 |
|
Poly(vinyl butyral), Fine Granular Powder, Nominal M.W. 36,000
| 63148-65-2 |
|
1-Phenyl-4-methyl-3-pyrazolidone, 98.5+%
| 2654-57-1 |
|
4-Quaterphenyl, Laser Grade, 99+% (UV-Vis)
| 135-70-6 |
|
5-Aminoindole, 97%
| 5192-03-0 |
|
Phosphorus atomic absorption standard solution, 1 mg/mL P in water
| 7723-14-0 |
|
Iodoform (Pract)
| 75-47-8 |
|
Gluconic Acid, Sodium Salt, 98%
| 527-07-1 |
|
Phthalic acid, p.a.
| 88-99-3 |
|
1-Bromo-4-iodobenzene, 98%
| 589-87-7 |
|
2,3-Dinitrotoluene, 99%
| 602-01-7 |
|
2-Methylnaphthalene, 99% (gc)
| 91-57-6 |
|
3-Isobutyl-1-Methylxanthine 99+%
| 28822-58-4 |
|
Beryllium atomic absorption standard solution, 1 mg/ml Be in 2% HCl
| 7440-41-7 |
|
2,2-Diphenylpropane, 97%
| 778-22-3 |
|
Dimethylglyoxime Disodium Salt, Octahydrate
| 60908-54-5 |
|
|