**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7440-41-7 |Beryllium | 0.1 | 231-150-7 |
|----------------|--------------------------------------|----------|-----------|
| 7647-01-0 |Hydrochloric acid | 2 | 231-595-7 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 97.9 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T+
Risk Phrases: 25 26 36/37/38 43 49 48/23
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Very toxic by inhalation. Irritating to eyes,
respiratory system and skin. May cause sensitization by skin
contact. May cause cancer by inhalation. Toxic : danger of serious
damage to health by prolonged exposure through inhalation.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal tract irritation.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Chronic beryllium disease, an immunologically mediated response
occurring after a latent period ranging from a few weeks to many
years, causes difficult breathing on exertion, weight loss,
nonproductive cough, fatigue, chest pain, anorexia, and weakness.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose
upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Do not breathe dust, vapor,
mist, or gas. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Do not ingest or inhale. Discard
contaminated shoes.
Storage:
Keep container closed when not in use. Poison room locked.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7440-41-7:
United Kingdom, WEL - TWA: 0.002 mg/m3 TWA
United Kingdom, WEL - STEL: 0.006 mg/m3 STEL
United States OSHA: 2 ug/m3 TWA; 5 ??g/m3 Ceiling
Belgium - TWA: 0.002 mg/m3 VLE
France - VME: 0.002 mg/m3 VME
Germany: 0.005 mg/m3 TWA (inhalable fraction, sharpen from metal
alloys); 0.002 mg/m3
Japan: 0.002 mg/m3 OEL
Malaysia: 0.002 mg/m3 TWA
Russia: 0.001 mg/m3 TWA
Spain: 0.002 mg/m3 VLA-ED
CAS# 7647-01-0:
United Kingdom, WEL - TWA: 1 ppm TWA (aerosol mist and gas); 2 mg
TWA (aerosol mist and gas)
United Kingdom, WEL - STEL: 5 ppm STEL (aerosol mist and gas); 8
mg/m3 STEL (aerosol mist and gas)
United States OSHA: ; 5 ppm Ceiling; 7 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 8 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 15 mg/m3 VLE
France - VLE: 5 ppm VLE; 7.5 mg/m3 VLE
Germany: 8 mg/m3 TWA
Japan: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Malaysia: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Netherlands: 10 ppm STEL; 15 mg/m3 STEL
Netherlands: 5 ppm MAC; 8 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 7.6 mg/m3 VLA-ED
Spain: 10 ppm VLA-EC; 15 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: 1.005g/cm3
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Heat.
Incompatibilities with Other Materials:
Strong bases, metals.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-41-7: DS1750000
CAS# 7647-01-0: MW4025000 MW4031000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation,
mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940
mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation,
rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M;
Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 =
45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral,
rabbit: LD50 = 900 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Beryllium -
ACGIH: A1 - Confirmed Human Carcinogen (listed as Beryllium compo
California: carcinogen, initial date 10/1/87
NTP: Known carcinogen
IARC: Group 1 carcinogen
Hydrochloric acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BERYLLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1566
Packing Group: II
IMO
Shipping Name: BERYLLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1566
Packing Group: II
RID/ADR
Shipping Name: BERYLLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1566
Packing group: II
USA RQ: CAS# 7440-41-7: 10 lb final RQ (no reporting of releases of this hazardo
USA RQ: CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 49 May cause cancer by inhalation.
R 25 Toxic if swallowed.
R 26 Very toxic by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
R 48/23 Toxic : danger of serious damage to health
by prolonged exposure through inhalation.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7440-41-7: No information available.
CAS# 7647-01-0: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7440-41-7 is listed on Canada's DSL List.
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7440-41-7 is listed on Canada's Ingredient Disclosure List.
CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-41-7 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 36/37/38 Irritating to eyes, respiratory system and
skin.
MSDS Creation Date: 9/02/1997 Revision #7 Date: 9/04/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dihydrocholesterol, 96%
| 80-97-7 |
|
1-Iodododecane, 98%
| 4292-19-7 |
|
Olivetol , 98%
| 500-66-3 |
|
Cis-3-Hexenoic Acid
| 4219-24-3 |
|
3,5-Di-tert-butyl-o-benzoquinone, 98%
| 3383-21-9 |
|
Tetrabromophenol Blue, Water Soluble
| 4430-25-5 |
|
O-Arsanilic Acid, 98%
| 2045-00-3 |
|
1,5-Diazabicyclo[4,3,0]non-5-ene, 98%
| 3001-72-7 |
|
2-Fluorobiphenyl, 97%
| 321-60-8 |
|
1,8-Dinitronaphthalene, 85+%
| 602-38-0 |
|
DL-P-Fluorophenylalanine, 97%
| 51-65-0 |
|
3,5-Dimethylpyrazole-1-Carbinol 99%
| 85264-33-1 |
|
4-Hydroxy-2,2,6,6-Tetramethylpiperidinooxy - Free Radical
| 2226-96-2 |
|
n,n-Dimethyl-n'-ethylethylenediamine, 98%
| 123-83-1 |
|
Molecular Sieves, 4A, 4 to 8 Mesh
| 0-00-1 |
|
(S)-(-)-Alpha, Alpha-Diphenyl-2-Pyrrolidinemethanol, 99+%
| 112068-01-6 |
|
1-Methylisatin, 98%
| 2058-74-4 |
|
2,6-Lutidine-Alpha-2,3-Diol, 99%
| 42097-42-7 |
|
Safrole, 97%
| 94-59-7 |
|
Isobutyrophenone, 97%
| 611-70-1 |
|
2-Chloro-4-nitrophenol, 96%
| 619-08-9 |
|
3,4-Diaminotoluene, 97%
| 496-72-0 |
|
4-Benzyloxy-3-methoxystyrene, 95%
| 55708-65-1 |
|
Acetylferrocene, 95%
| 1271-55-2 |
|
Yohimbine hydrochloride, 99%
| 65-19-0 |
|
4-Methyl-6,7-Bis(Sulfoxy)-2H-1-Benzopyran-2-One,Disodium
| 29334-07-4 |
|
o-Chlorophenylacetic acid, 98.5+%
| 2439-55-6 |
|
N-epsilon-Acetyl-L-lysine, 99%
| 692-04-6 |
|
4-Methyl-2-nitroaniline, 99%
| 89-62-3 |
|
2-(Hexamethyleneimino)-Ethyl Chloride Hydrochloride, 98%
| 26487-67-2 |
|
1-Piperonylpiperazine, 97%
| 32231-06-4 |
|
Octadecanamide, tech., ca 60%
| 124-26-5 |
|
2-(Bromomethyl)-2-(2,4-Dichlorophenyl)- 1,3-Dioxolane, 98%
| 60207-30-9 |
|
4-Methoxymetanilyl Fluoride, 97%
| 498-74-8 |
|
2,2,6,6-Tetramethylpiperidinooxy, 98%
| 2564-83-2 |
|
Poly(vinyl butyral), Fine Granular Powder, Nominal M.W. 36,000
| 63148-65-2 |
|
1-Phenyl-4-methyl-3-pyrazolidone, 98.5+%
| 2654-57-1 |
|
4-Quaterphenyl, Laser Grade, 99+% (UV-Vis)
| 135-70-6 |
|
5-Aminoindole, 97%
| 5192-03-0 |
|
Phosphorus atomic absorption standard solution, 1 mg/mL P in water
| 7723-14-0 |
|
Iodoform (Pract)
| 75-47-8 |
|
Gluconic Acid, Sodium Salt, 98%
| 527-07-1 |
|
Phthalic acid, p.a.
| 88-99-3 |
|
1-Bromo-4-iodobenzene, 98%
| 589-87-7 |
|
2,3-Dinitrotoluene, 99%
| 602-01-7 |
|
2-Methylnaphthalene, 99% (gc)
| 91-57-6 |
|
3-Isobutyl-1-Methylxanthine 99+%
| 28822-58-4 |
|
Beryllium atomic absorption standard solution, 1 mg/ml Be in 2% HCl
| 7440-41-7 |
|
2,2-Diphenylpropane, 97%
| 778-22-3 |
|
Dimethylglyoxime Disodium Salt, Octahydrate
| 60908-54-5 |
|
|