**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 602-01-7 |2,3-Dinitrotoluene | 99 | 210-013-5 |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T N
Risk Phrases: 23/24/25 45 48/22 62 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. May
cause cancer. Harmful : danger of serious damage to health by
prolonged exposure if swallowed. Possible risk of impaired
fertility. Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
May cause skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause irritation of the digestive tract. May cause liver damage.
Methemoglobinemia is characterized by dizziness, drowsiness,
headache, shortness of breath, cyanosis (bluish discoloration of
skin due to deficient oxygenation of the blood), rapid heart rate and
chocolate-brown colored blood. Overexposure may cause
methemoglobinemia. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
blood. Inhalation can cause systemic acidosis and methemoglobinemia.
May cause liver damage.
Chronic:
Prolonged exposure may cause anemia and methemoglobinemia,
characterized by dizziness, drowsiness, headache, breath shortness,
cyanosis (bluish skin due to deficient oxygenation of the blood),
rapid heart rate and chocolate-brown colored blood. May cause cancer
according to animal studies. Chronic exposure may cause liver
damage. There is a danger of cumulative effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Alcoholic beverage consumption may enhance the toxic effects of this
substance. For methemoglobinemia, administer oxygen alone or with
Methylene Blue depending on the methemoglobin concentration in the
blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 602-01-7:
CAS# 25321-14-6:
United States OSHA: 1.5 mg/m3 TWA
Belgium - TWA: 0.15 mg/m3 VLE
Malaysia: 0.2 mg/m3 TWA
Spain: 0.15 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 59.00 - 61.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H6N2O4
Molecular Weight: 182.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 602-01-7: XT1400000
CAS# 25321-14-6: XT1300000
LD50/LC50:
CAS# 602-01-7: Draize test, rabbit, skin: 500 mg/24H Mild; Oral,
mouse: LD50 = 1072 mg/kg; Oral, rat: LD50 = 911 mg/kg.
CAS# 25321-14-6: Oral, mouse: LD50 = 750 mg/kg.
Carcinogenicity:
2,3-Dinitrotoluene -
Not listed by ACGIH, IARC, or NTP.
Dinitrotoluene (mixed isomers) -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 5/1/96
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: 330ug/L; 96H; Static
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DINITROTOLUENES
Hazard Class: 6.1
UN Number: 2038
Packing Group: II
IMO
Shipping Name: DINITROTOLUENES
Hazard Class: 6.1
UN Number: 2038
Packing Group: II
RID/ADR
Shipping Name: DINITROTOLUENES
Hazard Class: 6.1
UN Number: 2038
Packing group: II
USA RQ: CAS# 25321-14-6: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 45 May cause cancer.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 48/22 Harmful : danger of serious damage to health
by prolonged exposure if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 62 Possible risk of impaired fertility.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 602-01-7: No information available.
CAS# 25321-14-6: No information available.
Canada
CAS# 602-01-7 is listed on Canada's NDSL List.
CAS# 25321-14-6 is listed on Canada's DSL List.
CAS# 602-01-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 25321-14-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 602-01-7 is listed on the TSCA inventory.
CAS# 25321-14-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #5 Date: 7/22/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dihydrocholesterol, 96%
| 80-97-7 |
|
1-Iodododecane, 98%
| 4292-19-7 |
|
Olivetol , 98%
| 500-66-3 |
|
Cis-3-Hexenoic Acid
| 4219-24-3 |
|
3,5-Di-tert-butyl-o-benzoquinone, 98%
| 3383-21-9 |
|
Tetrabromophenol Blue, Water Soluble
| 4430-25-5 |
|
O-Arsanilic Acid, 98%
| 2045-00-3 |
|
1,5-Diazabicyclo[4,3,0]non-5-ene, 98%
| 3001-72-7 |
|
2-Fluorobiphenyl, 97%
| 321-60-8 |
|
1,8-Dinitronaphthalene, 85+%
| 602-38-0 |
|
DL-P-Fluorophenylalanine, 97%
| 51-65-0 |
|
3,5-Dimethylpyrazole-1-Carbinol 99%
| 85264-33-1 |
|
4-Hydroxy-2,2,6,6-Tetramethylpiperidinooxy - Free Radical
| 2226-96-2 |
|
n,n-Dimethyl-n'-ethylethylenediamine, 98%
| 123-83-1 |
|
Molecular Sieves, 4A, 4 to 8 Mesh
| 0-00-1 |
|
(S)-(-)-Alpha, Alpha-Diphenyl-2-Pyrrolidinemethanol, 99+%
| 112068-01-6 |
|
1-Methylisatin, 98%
| 2058-74-4 |
|
2,6-Lutidine-Alpha-2,3-Diol, 99%
| 42097-42-7 |
|
Safrole, 97%
| 94-59-7 |
|
Isobutyrophenone, 97%
| 611-70-1 |
|
2-Chloro-4-nitrophenol, 96%
| 619-08-9 |
|
3,4-Diaminotoluene, 97%
| 496-72-0 |
|
4-Benzyloxy-3-methoxystyrene, 95%
| 55708-65-1 |
|
Acetylferrocene, 95%
| 1271-55-2 |
|
Yohimbine hydrochloride, 99%
| 65-19-0 |
|
4-Methyl-6,7-Bis(Sulfoxy)-2H-1-Benzopyran-2-One,Disodium
| 29334-07-4 |
|
o-Chlorophenylacetic acid, 98.5+%
| 2439-55-6 |
|
N-epsilon-Acetyl-L-lysine, 99%
| 692-04-6 |
|
4-Methyl-2-nitroaniline, 99%
| 89-62-3 |
|
2-(Hexamethyleneimino)-Ethyl Chloride Hydrochloride, 98%
| 26487-67-2 |
|
1-Piperonylpiperazine, 97%
| 32231-06-4 |
|
Octadecanamide, tech., ca 60%
| 124-26-5 |
|
2-(Bromomethyl)-2-(2,4-Dichlorophenyl)- 1,3-Dioxolane, 98%
| 60207-30-9 |
|
4-Methoxymetanilyl Fluoride, 97%
| 498-74-8 |
|
2,2,6,6-Tetramethylpiperidinooxy, 98%
| 2564-83-2 |
|
Poly(vinyl butyral), Fine Granular Powder, Nominal M.W. 36,000
| 63148-65-2 |
|
1-Phenyl-4-methyl-3-pyrazolidone, 98.5+%
| 2654-57-1 |
|
4-Quaterphenyl, Laser Grade, 99+% (UV-Vis)
| 135-70-6 |
|
5-Aminoindole, 97%
| 5192-03-0 |
|
Phosphorus atomic absorption standard solution, 1 mg/mL P in water
| 7723-14-0 |
|
Iodoform (Pract)
| 75-47-8 |
|
Gluconic Acid, Sodium Salt, 98%
| 527-07-1 |
|
Phthalic acid, p.a.
| 88-99-3 |
|
1-Bromo-4-iodobenzene, 98%
| 589-87-7 |
|
2,3-Dinitrotoluene, 99%
| 602-01-7 |
|
2-Methylnaphthalene, 99% (gc)
| 91-57-6 |
|
3-Isobutyl-1-Methylxanthine 99+%
| 28822-58-4 |
|
Beryllium atomic absorption standard solution, 1 mg/ml Be in 2% HCl
| 7440-41-7 |
|
2,2-Diphenylpropane, 97%
| 778-22-3 |
|
Dimethylglyoxime Disodium Salt, Octahydrate
| 60908-54-5 |
|
|