**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 5968-11-6 |Sodium carbonate monohydrate | >99.5 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes severe eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Chronic inhalation may cause nasal septum ulceration and
perforation. Prolonged or repeated contact may cause skin necrosis
and/or ulceration of the skin.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Material will not burn.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Use with adequate ventilation. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 497-19-8:
Russia: 5 mg/m3 TWA
CAS# 5968-11-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: colorless to white
Odor: odorless
pH: 11.6 (1% solution)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 851 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 33% in water
Specific Gravity/Density: 2.25
Molecular Formula: Na2CO3.H2O
Molecular Weight: 124.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. Decomposed by acids with effervescence, evolution of carbon
dioxide.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Strong acids, aluminum, fluorine.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, toxic fumes of sodium oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 497-19-8: VZ4050000
CAS# 5968-11-6 unlisted.
LD50/LC50:
CAS# 497-19-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, eye: 50 mg Severe; Draize test, rabbit, skin: 500
mg/24H Mild; Inhalation, mouse: LC50 = 1200 mg/m3/2H; Inhalation,
rat: LC50 = 2300 mg/m3/2H; Oral, mouse: LD50 = 6600 mg/kg; Oral,
mouse: LD50 = 6600 mg/kg; Oral, rat: LD50 = 4090 mg/kg.
CAS# 5968-11-6.
Carcinogenicity:
Sodium carbonate anhydrous -
Not listed by ACGIH, IARC, or NTP.
Sodium carbonate monohydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36 Irritating to eyes.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 497-19-8: 1
CAS# 5968-11-6: 1
Canada
CAS# 497-19-8 is listed on Canada's DSL List.
CAS# 497-19-8 is listed on Canada's Ingredient Disclosure List.
CAS# 5968-11-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 497-19-8 is listed on the TSCA inventory.
CAS# 5968-11-6 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 6/25/1999 Revision #4 Date: 2/24/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Decyltrimethylammonium bromide,99% (Titr.)
| 2082-84-0 |
|
Phenyl 3-Hydroxy-2-Naphthoate, 98+%
| 7260-11-9 |
|
(n-Butylamino)acetonitrile, 98%
| 3010-04-6 |
|
2,6-Dichloro-4-nitroaniline, 95%(tlc)
| 99-30-9 |
|
Sodium Metal
| 7440-23-5 |
|
Monensin, Sodium Salt
| 22373-78-0 |
|
Sodium Acetate, Anhydrous
| 127-09-3 |
|
2,4-Dichlorophenylacetonitrile, 99+%
| 6306-60-1 |
|
Sodium Acetate Trihydrate
| 127-09-3 |
|
2-Methyl-2-Cyclopenten-1-One, 97%
| 1120-73-6 |
|
3-(Isopropylideneaminoamidino)-1-phenylthiourea
| 63467-30-1 |
|
m-Phenylene diacetate, 93% (GC)
| 108-58-7 |
|
2,4,6-Triisopropylbenzenesulfonyl Chloride , 97%
| 6553-96-4 |
|
7-Hydroxycoumarin, 99%
| 93-35-6 |
|
Sodium Ammonium Phosphate Tetrahydrate
| 7783-13-3 |
|
7-Ethoxy-6-methoxy-2,2-dimethylchromene, 99%
| 65383-73-5 |
|
Trans-2-Methylcyclopentanol, 97%
| 25144-04-1 |
|
N-Butyl Cyanoacetate, 99+%
| 5459-58-5 |
|
Sodium tetrafluoroborate, 98%
| 13755-29-8 |
|
DL-1-Amino-2-propanol, 99+%
| 78-96-6 |
|
1,1-Diethylurea
| 634-95-7 |
|
Sodium Azide
| 7732-18-5 |
|
Sodium Benzoate
| 532-32-1 |
|
Sodium Bicarbonate
| 144-55-8 |
|
Methylguanidine sulfate, 98% (titr.)
| 598-12-9 |
|
2,4,5-Trihydroxypyrimidine, 98%
| 496-76-4 |
|
(+)-2-Azabicyclo[2.2.1]Hept-5-en-3-One 98% (HPLC), >95% e.e.
| 130931-83-8 |
|
Sodium bisulfate monohydrate
| 7681-38-1 |
|
Nicotinamide-N-Oxide, 98%
| 1986-81-8 |
|
Sodium bisulfite
| 7446-09-5 |
|
Ethyl 4-chloro-2-methylthio-5-pyrimidine- carboxylate, 98%
| 5909-24-0 |
|
3,4-Dimethoxyphenylacetone, 97%
| 776-99-8 |
|
(2r,3r)-(-)-2,3-butanediol, 99+% e.e.
| 24347-58-8 |
|
Sodium tetraborate decahydrate
| 1303-96-4 |
|
1-Methyl-3-piperidinemethanol, 97%
| 7583-53-1 |
|
4-Chloro-2-Nitrobenzyl Alcohol, 98%
| 22996-18-5 |
|
3-Ethylrhodanine, 98+% (GC)
| 7648-01-3 |
|
Sodium borohydride, powder
| 16940-66-2 |
|
Sodium bromate
| 7789-38-0 |
|
DL-threo-3-Phenylserine hydrate, 99%
| 69-96-5 |
|
Ethyl ethynyl carbinol, 99%
| 4187-86-4 |
|
Sodium bromide
| 7647-15-6 |
|
3-Butyn-2-one
| 1423-60-5 |
|
Sodium Cacodylate Trihydrate
| 6131-99-3 |
|
Sodium carbonate
| 497-19-8 |
|
Sodium carbonate decahydrate
| 497-19-8 |
|
Sodium carbonate monohydrate
| 497-19-8 |
|
Acetyl-d3 chloride, 99+ atom % D
| 75-36-5 |
|
Strontium Cyclohexanebutyrate
| 62638-05-5 |
|
Guanosine 5'-triphosphate, disodium salt hydrate, 95+% (hplc)
| 56001-37-7 |
|
|