**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 557-31-3 |Allyl ethyl ether | 95.0 | 209-169-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and
skin.The toxicological properties of this material have not been
fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or
suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. Get
medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Use water spray to keep fire-exposed containers cool. Extremely
flammable liquid and vapor. Flammable liquid and vapor. Will be
easily ignited by heat, sparks or flame. Vapors may form an explosive
mixture with air. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. For large fires, use water spray, fog or
alcohol-resistant foam. Do NOT use straight streams of water. For
small fires, use carbon dioxide, dry chemical, dry sand, or
alcohol-resistant foam. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. If peroxide formation is suspected, do not
open or move container. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Do not distill since this removes peroxide-inhibitors.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Regularly
check inhibitor levels to maintain peroxide levels below 1%.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 557-31-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 179.3 mbar @ 20
Viscosity: Not available.
Boiling Point: 66-67 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -21 deg C ( -5.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .7700g/cm3
Molecular Formula: C5H10O
Molecular Weight: 86.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. This material may be
sensitive to peroxide formation.
Conditions to Avoid:
Incompatible materials, ignition sources, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong acids.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 557-31-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Allyl ethyl ether -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALLYL ETHYL ETHER
Hazard Class: 3 (6.1)
UN Number: 2335
Packing Group: II
IMO
Shipping Name: ALLYL ETHYL ETHER
Hazard Class: 3.2 (6.1)
UN Number: 2335
Packing Group: II
RID/ADR
Shipping Name: ALLYL ETHYL ETHER
Hazard Class: 3
UN Number: 2335
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 557-31-3: No information available.
Canada
CAS# 557-31-3 is listed on Canada's NDSL List.
CAS# 557-31-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 557-31-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/12/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cyclooctene, 99% (GC)
| 931-86-2 |
|
Paraffin wax (granular)
| 8002-74-2 |
|
Mineral oil
| 8042-47-5 |
|
Celite 521
| 61790-53-2 |
|
Celatom FW-50
| 60676-86-0 |
|
Celatom FW-60
| 60676-86-0 |
|
Celatom FW-80
| 60676-86-0 |
|
1-Penten-3-ol, 99%
| 616-25-1 |
|
Dimethyl Isophthalate, 99%
| 1459-93-4 |
|
2,5-Dimethylphenol, 99+%
| 95-87-4 |
|
Dl-3-octanol, 99+%
| 589-98-0 |
|
Dowex 50x2-100 Ion-Exchange Resin
| 12612-37-2 |
|
Dowex 50x2-400 Ion-Exchange Resin
| 12612-37-2 |
|
meso-2,3-Dibromosuccinic acid
| 526-78-3 |
|
Methylene Blue trihydrate, 95%
| 61-73-4 |
|
Gum arabic
| 9000-01-5 |
|
Propionaldehyde, 97%
| 123-38-6 |
|
Allyl ethyl ether, 95%
| 557-31-3 |
|
n-Nonaphenone, 98% (gc)
| 6008-36-2 |
|
Indole-3-acetic acid hydrazide, 97%
| 5448-47-5 |
|
Acetamide, P.A.
| 60-35-5 |
|
Acetanilide, 99+%
| 103-84-4 |
|
Acetic anhydride, 99+%
| 108-24-7 |
|
Acetic anhydride, reagent ACS, 97+%
| 108-24-7 |
|
n-(2-Acetamidophenethyl)-1-hydroxy-2- naphthamide
| 5254-41-1 |
|
Epsilon-caprolactone monomer, 99%
| 502-44-3 |
|
1,1,2,2-Tetrabromoethane, 99%
| 79-27-6 |
|
Acrylamide, 98.5%
| 79-06-1 |
|
Agarose, Pure Powder (MR = -0.10)
| 9012-36-6 |
|
Agarose, Pure Powder (MR = -0.02)
| 9012-36-6 |
|
Agarose, Pure Powder (MR = -0.25)
| 9012-36-6 |
|
Agarose, Pure Powder (MR = -0.17)
| 9012-36-6 |
|
Agarose, Pure Powder (MR = -0.13+/- 0.01)
| 9012-36-6 |
|
Agarose LE
| 9012-36-6 |
|
Agarose ME
| 9012-36-6 |
|
Gibberellic Acid, 90+%
| 77-06-5 |
|
Gibberellic Acid (in Dibasic Ammonium Phosphate)
| 77-06-5 |
|
Aluminon, p.a.
| 569-58-4 |
|
Aluminum ammonium sulfate dodecahydrate, 99%
| 7784-25-0 |
|
5-Methoxy-2-mercaptobenzimidazole, 99+% (HPLC)
| 37052-78-1 |
|
2-Pentanone 98+%
| 107-87-9 |
|
Ethyl 2-amino-4,5,6,7-tetrahydrobenzo(b)thiophene-3-carboxylate, 97%
| 4506-71-2 |
|
Aluminum chloride, anhydrous, granules, 99%
| 7446-70-0 |
|
Aluminum Oxide, Activated, Basic, for Column Chromatography(50-200
| 1344-28-1 |
|
Aluminum Oxide, Activated, 50-200 Micron, Neutral, for Column
| 1344-28-1 |
|
Aluminum Oxide, 99.9999%, Coarse Granular
| 1344-28-1 |
|
Aluminum Oxide, 99.999%, - 40 Mesh
| 1344-28-1 |
|
Aluminum Oxide, 99.99%
| 1344-28-1 |
|
Aluminum Oxide, 99%
| 1344-28-1 |
|
Aluminum Oxide (Morin Dyed)
| 1344-28-1 |
|
|