Search   
MSDS 
:
 Barbital
CAS 
:
 57-44-3
SYNONYMS 
:
 Barbital free acid; barbitone; ethylbarbital; diethyl barbituric acid
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 57-44-3 |Barbital | 100 | 200-331-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.

Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Not available.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
Not available.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Minimize dust generation and accumulation.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 57-44-3:


Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: white
Odor: odorless
pH: Acidic
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 374 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 1.2
Molecular Formula: C8H12N2O3
Molecular Weight: 184.0956

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
None reported.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 57-44-3: CQ3500000
LD50/LC50:
CAS# 57-44-3: Oral, mouse: LD50 = 600 mg/kg.
Carcinogenicity:
Barbital -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 57-44-3: 2
Canada
CAS# 57-44-3 is listed on Canada's DSL List.
CAS# 57-44-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 57-44-3 is not listed on the TSCA inventory.
It is for research and development use only.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 12/12/1997 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
Search More   
ALL MSDS PAGES IN THIS GROUP
NAMECAS
6-Chloro-2-hexanone, 98% 10226-30-9
1,4-Dihydroxynaphthalene, 1:1 mixture with 1,4-napthoquinone 130-15-4
2-Amino-3-Bromo-5-Nitro-Benzonitrile, 98% 17601-94-4
N-(Hydroxymethyl)Benzamide, 98% 6282-02-6
2,4-Diaminobenzenesulfonic Acid, 97% 88-63-1
2-Amino-5-Methoxybenzenesulfonic Acid, 98% 13244-33-2
3-Amino-4-Methoxybenzenesulfonic Acid, 98% 98-42-0
Formononetin, 99% 485-72-3
n-Hexadecyl palmitate, 98% 540-10-3
4-Iodobenzyl Bromide, 97% 0-01-1
3,4-Dicyanoaniline 56765-79-8
Vinyltris(Trimethylsilyloxy)Silane, 95% 5356-84-3
Dl-2,3-Dimercapto-1-Propanesulfonic Acid, Sodium Salt, Monohydrate 4076-02-2
(2S)-4-(1,3-Dioxoisoindolin-2-yl)-2-Hydroxybutanoic Acid, 96% 48172-10-7
(S)-(-)-4-Amino-2-Hydroxybutyric Acid, 96% 40371-51-5
N-(2-Hydroxy-4-aminophenyl)-phthalimide // Agfa Germany special 117346-08-4
o-Acetyl-L-Carnitine Hydrochloride, 98% 5080-50-2
(+/-)-Verapamil.hydrochloride (USP) 152-11-4
D-(+)-Maltose monohydrate, 90%, 69-79-4
Methyl 3-Aminocrotonate, 97% 14205-39-1
2-(3-Chlorophenyl)ethylamine, 98% 13078-79-0
Vinylmethylbis(Trimethylsilyloxy)Silane, 95% 5356-85-4
4-Acetylbenzenesulfonyl Chloride 1788-10-9
omega-Undecylenyl alcohol 112-43-6
3-Chlorothiophene, 98% 17249-80-8
Trimethylsilyl Methacrylate, Stabilized, 97% 13688-56-7
DL-3-Hydroxybutyric Acid, Sodium Salt, 99% 306-31-0
2-Pentyn-1-ol, 95% 6261-22-9
o-Nitrophenyl isocyanate (pract) 3320-86-3
Trimethoxy(7-Octen-1-yl)Silane, 90% 52217-57-9
Benzylacetone 2550-26-7
Tetrakis(trimethylsilyloxy)silane, 98% 3555-47-3
Ethyltriethoxysilane, 97% 78-07-9
1,1-Cyclopropanedicarboxylic acid 598-10-7
2-(2-(Trichlorosilyl)ethyl)pyridine, 96% 17082-69-8
6-Nitro-4-sulfo-2,1-naphthoquinone diazide, 97% 63589-25-3
N-(Trimethylsilyl)Allylamine, 95% 10519-97-8
3-Amino-5-nitrobenzothiazole, 97% 84387-89-3
2-Keto-L-gulonic acid, 90% 526-98-7
2,5-Diamino-4,6-dihydroxypyrimidine hydrochloride, 98% 56830-58-1
5-Nitrouracil, P.A. 611-08-5
1-Hydroxy-7-Azabenzotriazole, 98% 39968-33-7
4-Amino-3-Nitrobenzenesulfonic Acid, 97% 616-84-2
2-Chloro-4-aminopyridine, 97% 14432-12-3
2,5,6-Trimethylbenzoxazole, 98% 19219-98-8
2,6-Dichloro-3-fluoroacetophenone, 97% 0-01-1
Methyl beta-dimethylaminoisobutyrate, 99% 10205-34-2
2-Cyano-3-methylpyridine, 98% 20970-75-6
Barbital 57-44-3
4,4'-Methylenebis-(2,6-diisopropylaniline) 0-01-1

Free MSDS Search ( Providing 250,000+ Material Properties )
Chemcas.com| Ads link:todaystock.net