**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 78-07-9 |Ethyltriethoxysilane | 97 | 201-080-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: 10
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Ingestion of large amounts may cause CNS
depression.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Aspiration may
lead to pulmonary edema. May be harmful if inhaled. Vapors may cause
dizziness or suffocation. May cause burning sensation in the chest.
Chronic:
Ethanol is mainly metabolized in the liver, which is also one of the
primary target organs. While ethanol is well known to cause cirrhosis
of the liver in alcoholics, liver cirrhosis has also been produced in
rabbits exposed by inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Flammable liquid and vapor. Vapors may
be heavier than air. They can spread along the ground and collect in
low or confined areas. Contact with water liberates highly flammable
gases.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use water spray, dry chemical, carbon dioxide, or
chemical foam. Do NOT get water inside containers. Do NOT use
straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not allow contact with water. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Keep from contact with moist air and steam.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 78-07-9:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: characteristic odor
pH: Not available.
Vapor Pressure: 10 mm Hg @ 50 deg C
Viscosity: Not available.
Boiling Point: 158 - 159 deg C
Freezing/Melting Point: -78 deg C
Autoignition Temperature: 235 deg C ( 455.00 deg F)
Flash Point: 29 deg C ( 84.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 0.896
Molecular Formula: C8H20O3Si
Molecular Weight: 192.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. Material generates ethanol on contact with water.
Conditions to Avoid:
Ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, silicon dioxide, ethanol.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 78-07-9: VV4205000
LD50/LC50:
CAS# 78-07-9: Draize test, rabbit, eye: 500 mg/24H Mild; Oral, rat:
LD50 = 14 gm/kg; Skin, rabbit: LD50 = 16 mL/kg.
Carcinogenicity:
Ethyltriethoxysilane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 78-07-9: No information available.
Canada
CAS# 78-07-9 is listed on Canada's NDSL List.
CAS# 78-07-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 78-07-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/02/2000 Revision #5 Date: 7/09/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
ALL MSDS PAGES IN THIS GROUP
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6-Chloro-2-hexanone, 98%
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1,4-Dihydroxynaphthalene, 1:1 mixture with 1,4-napthoquinone
| 130-15-4 |
2-Amino-3-Bromo-5-Nitro-Benzonitrile, 98%
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2,4-Diaminobenzenesulfonic Acid, 97%
| 88-63-1 |
2-Amino-5-Methoxybenzenesulfonic Acid, 98%
| 13244-33-2 |
3-Amino-4-Methoxybenzenesulfonic Acid, 98%
| 98-42-0 |
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n-Hexadecyl palmitate, 98%
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3,4-Dicyanoaniline
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Vinyltris(Trimethylsilyloxy)Silane, 95%
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Dl-2,3-Dimercapto-1-Propanesulfonic Acid, Sodium Salt, Monohydrate
| 4076-02-2 |
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| 48172-10-7 |
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| 40371-51-5 |
N-(2-Hydroxy-4-aminophenyl)-phthalimide // Agfa Germany special
| 117346-08-4 |
o-Acetyl-L-Carnitine Hydrochloride, 98%
| 5080-50-2 |
(+/-)-Verapamil.hydrochloride (USP)
| 152-11-4 |
D-(+)-Maltose monohydrate, 90%,
| 69-79-4 |
Methyl 3-Aminocrotonate, 97%
| 14205-39-1 |
2-(3-Chlorophenyl)ethylamine, 98%
| 13078-79-0 |
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| 5356-85-4 |
4-Acetylbenzenesulfonyl Chloride
| 1788-10-9 |
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| 112-43-6 |
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| 17249-80-8 |
Trimethylsilyl Methacrylate, Stabilized, 97%
| 13688-56-7 |
DL-3-Hydroxybutyric Acid, Sodium Salt, 99%
| 306-31-0 |
2-Pentyn-1-ol, 95%
| 6261-22-9 |
o-Nitrophenyl isocyanate (pract)
| 3320-86-3 |
Trimethoxy(7-Octen-1-yl)Silane, 90%
| 52217-57-9 |
Benzylacetone
| 2550-26-7 |
Tetrakis(trimethylsilyloxy)silane, 98%
| 3555-47-3 |
Ethyltriethoxysilane, 97%
| 78-07-9 |
1,1-Cyclopropanedicarboxylic acid
| 598-10-7 |
2-(2-(Trichlorosilyl)ethyl)pyridine, 96%
| 17082-69-8 |
6-Nitro-4-sulfo-2,1-naphthoquinone diazide, 97%
| 63589-25-3 |
N-(Trimethylsilyl)Allylamine, 95%
| 10519-97-8 |
3-Amino-5-nitrobenzothiazole, 97%
| 84387-89-3 |
2-Keto-L-gulonic acid, 90%
| 526-98-7 |
2,5-Diamino-4,6-dihydroxypyrimidine hydrochloride, 98%
| 56830-58-1 |
5-Nitrouracil, P.A.
| 611-08-5 |
1-Hydroxy-7-Azabenzotriazole, 98%
| 39968-33-7 |
4-Amino-3-Nitrobenzenesulfonic Acid, 97%
| 616-84-2 |
2-Chloro-4-aminopyridine, 97%
| 14432-12-3 |
2,5,6-Trimethylbenzoxazole, 98%
| 19219-98-8 |
2,6-Dichloro-3-fluoroacetophenone, 97%
| 0-01-1 |
Methyl beta-dimethylaminoisobutyrate, 99%
| 10205-34-2 |
2-Cyano-3-methylpyridine, 98%
| 20970-75-6 |
Barbital
| 57-44-3 |
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| 0-01-1 |
|
|