**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 589-17-3 |4-Bromobenzyl chloride | 98% | 209-638-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Lachrymator (substance which increases the flow of
tears).
Potential Health Effects
Eye:
Causes eye burns. Produces irritation, characterized by a burning
sensation, redness, tearing, inflammation, and possible corneal
injury. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Do NOT allow victim to rub eyes or keep eyes closed. In case of
contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use carbon dioxide or dry chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or
inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Use only with adequate ventilation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 589-17-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 136 - 139 @ 27mmHg
Freezing/Melting Point: 36 - 40 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C7H6BrCl
Molecular Weight: 205.399
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not currently available.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 589-17-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Bromobenzyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 589-17-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 589-17-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 589-17-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/07/2000 Revision #4 Date: 12/16/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Titanium(IV) tert-butoxide
| 119279-48-0 |
|
Basic Fuchsin, 88% (Titr.)
| 632-99-5 |
|
Aniline blue, w.s. (cert)
| 28631-66-5 |
|
Manganese(III)acetylacetonate
| 14284-89-0 |
|
Iron(II)acetylacetonate
| 14024-17-0 |
|
4-Bromobenzyl chloride, 98%
| 589-17-3 |
|
2,3-Dimethylanisole, 97%
| 2944-49-2 |
|
Ethyl 5-acetyloxyindole-2-carboxylate, Astra-Zeneca custom grade
| 0-01-1 |
|
Bromothymol Blue sodium salt, reagent ACS
| 34725-61-6 |
|
Bromocresol Green Sodium Salt, Reagent ACS, 95% (UV-Vis)
| 67763-24-0 |
|
Triethyleneglycol dibutylether
| 0-01-1 |
|
2-Cyano-3-morpholinoacrylamide, 98%
| 25229-97-4 |
|
Bromophenol Blue, Reagent ACS, 99% (UV-VIS)
| 115-39-9 |
|
Sodium Selenite, Anhydrous, 44-46% se
| 10102-18-8 |
|
Blue tetrazolium
| 1871-22-3 |
|
Bromocresol green, reagent acs, 98% (uv-vis)
| 76-60-8 |
|
2-Amino-4,5-Dichlorobenzothiazole, 97%
| 1849-71-4 |
|
4,5-Dihydroxynaphthalene-2,7-Disulfonic Acid, Disodium Salt,
| 129-96-4 |
|
Dimethyl (2-oxo-4-phenylbutyl)phosphonate, tech. , 85%
| 41162-19-0 |
|
Congo Red, High Purity Biological Stain
| 573-58-0 |
|
2,6-Dichloroindophenol sodium salt, hydrate, reagent ACS
| 620-45-1 |
|
Furaneol acetate, 98%
| 4166-20-5 |
|
Eosin Y, indicator grade
| 17372-87-1 |
|
p-Anisidine hydrochloride, 99% (titr.)
| 20265-97-8 |
|
2-(p-Tolyl)propionic acid
| 938-94-3 |
|
Tetrabutylammonium hydroxide, 1m solution in methanol
| 2052-49-5 |
|
Ethyl N-benzyl-3-oxo-4-piperidine-carboxylate hydrochloride, tech.,
| 52763-21-0 |
|
Evans Blue
| 314-13-6 |
|
n-Tridecane
| 629-50-5 |
|
Giemsa Stain (Cert), 80% (UV-Vis)
| 51811-82-6 |
|
2-(4-Bromomethyl)phenylpropionic acid, 97%
| 111128-12-2 |
|
Hematoxylin (Pract), 85% (UV-Vis)
| 517-28-2 |
|
3-Chloro-4-methyl-7-hydroxycoumarin, 96%
| 6174-86-3 |
|
Indigo Carmine (Cert.)
| 860-22-0 |
|
1,8-Dihydroxy-4,5-dinitroanthracene-9,10-dione, 97%
| 81-55-0 |
|
Methyl Red Sodium Salt, Reagent ACS, 95% (UV-Vis)
| 845-10-3 |
|
Iron(III)sulfate pentahydrate, 97%
| 142906-29-4 |
|
Methyl Orange, High Purity Biological Stain
| 547-58-0 |
|
Acid Black 1
| 1064-48-8 |
|
Alpha-Ethyl-3-Hydroxy-4-Methylphenethyl-Amine Hydrochloride
| 29440-91-3 |
|
2-Amino-2'-Fluoro-5-Bromobenzophenone, 98%
| 0-00-1 |
|
(1-Aminobutyl)phosphonic acid, 97%
| 13138-36-8 |
|
Neutral Red (cert)
| 553-24-2 |
|
Orange G (Cert)
| 1936-15-8 |
|
Orcein, certified, 95% (UV-VIS)
| 1400-62-0 |
|
3-Aminopropylphosphonic Acid, 97%
| 13138-33-5 |
|
1-(2-Pyridylazo)-2-naphthol, indicator grade
| 85-85-8 |
|
(1-Amino-1-phenylmethyl)phosphonic acid, 97%
| 18108-22-0 |
|
Basic fuchsin, 99% (uv-vis)
| 569-61-9 |
|
(1-Aminopentyl)phosphonic acid, 97%
| 13138-37-9 |
|
|