**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 60731-73-9 |2,6-Difluorobenzoyl isocyanate | >80 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.Heat sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May
cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Organic isocyanates can
cause local irritation and allergic reactions.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage.
Inhalation:
Causes respiratory tract irritation. Exposure produces central
nervous system depression. At high concentrations, isocyanates affect
mucous membranes of the respiratory tract and may lead to fatal
pulmonary edema. Exposure to low and often even unmeasurable
isocyanate concentration results in sensitization. Can produce
delayed pulmonary edema. In rare instances, exposure may cause
sensitization, resulting in inflammation of the mucous membranes and
in eczematous eruptions.
Chronic:
May cause liver and kidney damage. Effects may be delayed. May cause
lung damage. Repeated or prolonged exposure may cause allergic
reactions in sensitive individuals. Inhalation of product may
aggravate existing chronic repiratory problems such as asthma,
emphysema or bronchitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
For ingestion, the stomach sould be intubated, aspirated, and
lavaged with a slurry of activated charcoal--protect the airway from
aspiration of gastric contents. Treat symptomatically and
supportively.
Antidote:
Always have a cyanide antidote kit on hand when working with cyanide
compounds. Get medical advice to use.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Will react with water to form toxic and corrosive fumes. Contact
with water can cause violent liberation of heat and splattering of
the material. Contact with metals may evolve flammable hydrogen gas.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For large fires, use water spray, fog or
alcohol-resistant foam. For small fires, use carbon dioxide, dry
chemical, dry sand, or alcohol-resistant foam. Most foams will react
with the material and release corrosive/toxic gases. Use water
spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Wash clothing before
reuse. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Deep freeze
(below -20C).
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 60731-73-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid or liquid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 66 deg C @ .20mm Hg
Freezing/Melting Point: 28.4 deg C (dec)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 28.4 deg C
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H3F2NO2
Molecular Weight: 183.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not currently available.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide,
hydrocarbons.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 60731-73-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,6-Difluorobenzoyl isocyanate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOCYANATES, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2206
Packing Group: III
IMO
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing Group: III
RID/ADR
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 60731-73-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 60731-73-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 60731-73-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/14/1999 Revision #6 Date: 7/22/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
6-Amino-2-Naphthoic Acid, 90%
| 11668-47-4 |
|
Zirconium (IV) Oxide, P.A.
| 1314-23-4 |
|
cis-Dichlorodiamineplatinum(II), 99.99%
| 15663-27-1 |
|
1-Bromonaphthalene 96%, contains max. 2% 2-bromonaphthalene
| 90-11-9 |
|
1-Heptanesulfonic acid, sodium salt, monohydrate, HPLC grade
| 207300-90-1 |
|
1-Hexanesulfonic acid sodium salt, HPLC grade
| 2832-45-3 |
|
5-Bromo-1-pentene, 96%
| 1119-51-3 |
|
2,6-Diphenylphenol
| 2432-11-3 |
|
L-Cystine
| 56-89-3 |
|
1-Pentanesulfonic Acid, Sodium Salt Monohydrate, HPLC Grade
| 22767-49-3 |
|
1,1,2-Trichloroethane Density Standard
| 79-00-5 |
|
2-Ethoxyethanol, 99%
| 110-80-5 |
|
Antimony Trichloride
| 10025-91-9 |
|
2-Ethoxyethyl acetate 99%
| 111-15-9 |
|
DL-2-Octanol, 97%
| 123-96-6 |
|
2,2,2-Trifluoroethanol
| 75-89-8 |
|
5-Amino-2-methylindole, 98%
| 7570-49-2 |
|
Bromoacetaldehyde Diethyl Acetal, 97%
| 2032-35-1 |
|
2-Acetylcyclohexanone, 97%
| 874-23-7 |
|
Lauric acid, 98%
| 143-07-7 |
|
4-Methoxy-2-nitroaniline, 98%
| 96-96-8 |
|
1-Nitroso-2-naphthol-3,6-disulfonic acid disodium salt
| 0-00-0 |
|
Toluidine Blue O Zinc Chloride Double Salt
| 0-01-1 |
|
2,4,6-Triphenylpyrylium Chloride, 90%
| 40836-01-9 |
|
2-Isopropoxyethanol, 98%
| 109-59-1 |
|
2,6-Difluorobenzoyl Isocyanate
| 60731-73-9 |
|
1-(4-Chlorophenyl)-1-Cyclopropane- Carboxylic Acid, 99%
| 72934-37-3 |
|
1-Bromo-1-propene, mixture of isomers, 95%
| 590-14-7 |
|
3-Aminopyrrolidine Dihydrochloride
| 103831-11-4 |
|
2,2,4-Trimethylpentane, p.a.
| 540-84-1 |
|
Phenyl Salicylate, 99% (UV-Vis)
| 118-55-8 |
|
MOPS
| 1132-61-2 |
|
P-Naphtholbenzein, 90+% (UV-VIS)
| 145-50-6 |
|
1-Amino-4-Hydroxyanthraquinone, 96%
| 116-85-8 |
|
4-Aminoantipyrine, 98%
| 83-07-8 |
|
Sodium metatungstate, 2.82 density solution in water, stabilized
| 7732-18-5 |
|
8-Hydroxyquinoline, p.a.
| 148-24-3 |
|
3-Methyl-2-Cyclohexen-1-One, 98%
| 1193-18-6 |
|
Cerium(IV) sulfate tetrahydrate
| 10294-42-5 |
|
Sodium metatungstate hydrate, crystalline
| 12141-67-2 |
|
O-Methylbenzyl Cyanide, 98%
| 22364-68-7 |
|
l(-)-Glutathione, oxidized, hydrate, 95%
| 27025-41-8 |
|
Antimony Trioxide
| 1309-64-4 |
|
Dibutyl L-Tartrate
| 87-92-3 |
|
(-)-Terpinen-4-ol, 97%
| 562-74-3 |
|
3,5-Dinitrosalicylic Acid Monosodium Salt, Monohydrate, 97% (Titr.)
| 46506-88-1 |
|
4-Tert.-Butyl-Calix[4]arene-Crown-4-Complex
| 171058-95-0 |
|
4-Tert.-Butyl-Calix[4]Arene-Crown-5-Complex
| 99314-01-9 |
|
4-Tert.-Butyl-Calix[4]Arene-Crown-6-Complex
| 129518-51-0 |
|
2,3,4,5-Tetrafluoro-6-nitrobenzoic acid
| 16583-08-7 |
|
|