**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 611-17-6 |2-Chlorobenzyl Bromide | 98% | 210-257-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light
sensitive.Moisture sensitive.Lachrymator (substance which increases
the flow of tears).
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury. Lachrymator
(substance which increases the flow of tears). May cause chemical
conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause cardiac disturbances. May cause central nervous system
depression. Causes digestive tract irritation.
Inhalation:
Causes respiratory tract irritation. May cause cardiac
abnormalities. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Containers may explode when heated.
Combustible material; may burn but does not ignite readily. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER! Do NOT
get water inside containers. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Store protected from
light. Do not allow contact with water. Wash clothing before reuse.
Keep from contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture. Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 611-17-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 103 - 104 deg C @ 1mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 108 deg C ( 226.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.5830g/cm3
Molecular Formula: ClC6H4CH2Br
Molecular Weight: 205.49
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, light, moisture, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, alcohols, amines, bases, steel.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 611-17-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Chlorobenzyl Bromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 611-17-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 611-17-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 611-17-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Diiodo-4-Nitrophenol, 99%
| 305-85-1 |
|
Benzo-18-Crown-6, 97%(TLC)
| 14098-24-9 |
|
Xylan, ex avena
| 9014-63-5 |
|
2,4-Diaminotoluene, 98%
| 95-80-7 |
|
2-Methyl-3-(3,4-Methylenedioxyphenyl) Propanal, 98+%
| 1205-17-0 |
|
Isobutyl acetate, 98%
| 110-19-0 |
|
2-Hydroxy-4-methylquinoline, 97%
| 607-66-9 |
|
3-Phenoxyphenol
| 713-68-8 |
|
Potassium tert.-Butoxide, 95-99%
| 865-47-4 |
|
Benzyltriethylammonium tetrafluoroborate, 98+%
| 77794-93-5 |
|
4-Methoxybenzophenone, 97%
| 611-94-9 |
|
p-Butylbenzaldehyde diethyl acetal, 99%
| 83803-80-9 |
|
2-Chlorobenzoic Acid, 98%
| 118-91-2 |
|
1,3-Cyclohexanediol (Mixture of Cis and Trans), 98%
| 504-01-8 |
|
1-Chloro-2-Nitrobenzene, 99+%
| 88-73-3 |
|
2-Amino-4-Chloro-6-Methylpyrimidine 98%
| 5600-21-5 |
|
Dowex 1x8-200 ion-exchange resin
| 12627-85-9 |
|
Chromium(III) chloride, sublimed, anhydrous, 99%
| 10025-73-7 |
|
o-Methylphenethyl alcohol, 98%
| 19819-98-8 |
|
1-Chloroacetyl-3-Pyrazolidinone, 99%
| 0-00-1 |
|
Molecular Sieves, 3A, Powder, Max. Grain-Size 50 Micrometer
| 308080-99-1 |
|
Benzyl thiocyanate, 97%
| 3012-37-1 |
|
Bromochloromethane, 98%
| 74-97-5 |
|
Xanthopterin monohydrate
| 5979-01-1 |
|
2-Ethyl-1-Butanol, 98%
| 97-95-0 |
|
Oleyl alcohol, tech., 70% (gc)
| 143-28-2 |
|
alpha,alpha,alpha,2-Tetrachloro-6-fluorotoluene, 98%
| 84473-83-6 |
|
bis(4-Diethylaminodithiobenzil)nickel, laser grade, 99% (uv-vis)
| 51449-18-4 |
|
4-Nitrotoluene, 99%
| 99-99-0 |
|
2-Cyanopyridine, 99%
| 100-70-9 |
|
N-Carbobenzyloxy-L-Aspartic Acid, 98%
| 1152-61-0 |
|
Alizarin Red S (cert), 90% (uv-vis)
| 130-22-3 |
|
4-Chloroaniline, 99% (Titr.)
| 106-47-8 |
|
Methyl-2-methyl-3-furancarboxylate, 99%
| 6141-58-8 |
|
Ethyl Red Iodide, 98%
| 634-21-9 |
|
Hafnium chloride, 99%, -80 mesh
| 13499-05-3 |
|
Trans-2-Cyano-1-Cyclohexanol, 99+%
| 63301-31-5 |
|
3,3-Dimethoxy-Propanenitrile, 97%
| 57597-62-3 |
|
Scandium atomic absorption standard solution, 1 mg/ml Sc in 2% HNO3
| 7440-20-2 |
|
2-Vinylquinoline, 99% (Titr.)
| 772-03-2 |
|
4-Cumylphenol, 99%
| 599-64-4 |
|
2-Chlorobenzyl Bromide, 98%
| 611-17-6 |
|
Ethyl bis(ethylthio)acetate, 99%
| 20461-95-4 |
|
Tetrapentylammonium Iodide, 99% (Titr.)
| 2498-20-6 |
|
4-Ethyl-3-Thiosemicarbazide, 97%
| 13431-34-0 |
|
3',5'-Dimethoxy-4'-Hydroxyacetophenone 97%
| 2478-38-8 |
|
4,5-Dimethyl-2-isobutylthiazole, 98%
| 53498-32-1 |
|
1,1-Diphenyl-2-propanol, 98%
| 29338-49-6 |
|
Fast Violet B Salt, Purified
| 14726-28-4 |
|
2-Acetamido-3,4,6-tri-o-acetyl-2-deoxy-bet ha-d-glucopyranosyl azide,
| 6205-69-2 |
|
|