**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 95-80-7 |2,4-Diaminotoluene | 98.0 | 202-453-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 21 25 36 43 45 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Toxic if swallowed. Irritating to
eyes. May cause sensitization by skin contact. May cause cancer.
Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation. May cause blepharitis (inflammation of the
eyelids), keratoconjunctivitis and corneal opacity. May cause
severe inflammation and edema of the eye and conjunctiva or deeper
structures of the eye. May produce tearing and permanent blindness.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
If absorbed, may cause symptoms similar to those for ingestion. May
cause a deep staining of the skin. May cause severe dermatitis and
urticaria(hives).
Ingestion:
May cause irritation of the digestive tract. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death.
Methemoglobinemia is characterized by dizziness, drowsiness,
headache, shortness of breath, cyanosis (bluish discoloration of
skin due to deficient oxygenation of the blood), rapid heart rate and
chocolate-brown colored blood. Ingestion may cause gastritis,
vertigo, tremors, convulsions, and possible coma.
Inhalation:
May cause effects similar to those described for ingestion. May
cause asthma and shortness of breath.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray to cool fire-exposed containers. For small fires,
use dry chemical, carbon dioxide, or water spray. Cool containers
with flooding quantities of water until well after fire is out. For
large fires, use water spray, fog or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 95-80-7:
Germany: 0.1 mg/m3 TWA
Germany: Skin absorber
Russia: 2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: brown
Odor: None reported.
pH: Not available.
Vapor Pressure: 1 mm Hg @106.5C
Viscosity: Not available.
Boiling Point: 292 deg C
Freezing/Melting Point: 99 deg C
Autoignition Temperature: 365 deg C ( 689.00 deg F)
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 50 g/l (25 c)
Specific Gravity/Density:
Molecular Formula: C7H10N2
Molecular Weight: 122.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Acids - acid chlorides - acid anhydrides - chloroformates - strong
oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 95-80-7: XS9625000
LD50/LC50:
CAS# 95-80-7: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, eye: 100 mg/24H; Draize test, rabbit, skin: 500 mg/24H
Mild; Draize test, rabbit, skin: 500 mg/24H; Oral, rat: LD50 = 590
mg/kg/24H; Skin, rabbit: LD50 = 650 mg/kg/24H.
Carcinogenicity:
2,4-Diaminotoluene -
California: carcinogen, initial date 1/1/88
NTP: Suspect carcinogen
IARC: Group 2B carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 2,4-TOLUYLENEDIAMINE
Hazard Class: 6.1
UN Number: 1709
Packing Group: III
IMO
Shipping Name: 2,4-TOLUYLENEDIAMINE
Hazard Class: 6.1
UN Number: 1709
Packing Group: III
RID/ADR
Shipping Name: 2,4-TOLUYLENEDIAMINE
Hazard Class: 6.1
UN Number: 1709
Packing group: III
USA RQ: CAS# 95-80-7: 10 lb final RQ (Listed under Toluenediamine); 4.54 kg fina
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 45 May cause cancer.
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
R 36 Irritating to eyes.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 95-80-7: 3
Canada
CAS# 95-80-7 is listed on Canada's DSL List.
CAS# 95-80-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 95-80-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/11/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Diiodo-4-Nitrophenol, 99%
| 305-85-1 |
|
Benzo-18-Crown-6, 97%(TLC)
| 14098-24-9 |
|
Xylan, ex avena
| 9014-63-5 |
|
2,4-Diaminotoluene, 98%
| 95-80-7 |
|
2-Methyl-3-(3,4-Methylenedioxyphenyl) Propanal, 98+%
| 1205-17-0 |
|
Isobutyl acetate, 98%
| 110-19-0 |
|
2-Hydroxy-4-methylquinoline, 97%
| 607-66-9 |
|
3-Phenoxyphenol
| 713-68-8 |
|
Potassium tert.-Butoxide, 95-99%
| 865-47-4 |
|
Benzyltriethylammonium tetrafluoroborate, 98+%
| 77794-93-5 |
|
4-Methoxybenzophenone, 97%
| 611-94-9 |
|
p-Butylbenzaldehyde diethyl acetal, 99%
| 83803-80-9 |
|
2-Chlorobenzoic Acid, 98%
| 118-91-2 |
|
1,3-Cyclohexanediol (Mixture of Cis and Trans), 98%
| 504-01-8 |
|
1-Chloro-2-Nitrobenzene, 99+%
| 88-73-3 |
|
2-Amino-4-Chloro-6-Methylpyrimidine 98%
| 5600-21-5 |
|
Dowex 1x8-200 ion-exchange resin
| 12627-85-9 |
|
Chromium(III) chloride, sublimed, anhydrous, 99%
| 10025-73-7 |
|
o-Methylphenethyl alcohol, 98%
| 19819-98-8 |
|
1-Chloroacetyl-3-Pyrazolidinone, 99%
| 0-00-1 |
|
Molecular Sieves, 3A, Powder, Max. Grain-Size 50 Micrometer
| 308080-99-1 |
|
Benzyl thiocyanate, 97%
| 3012-37-1 |
|
Bromochloromethane, 98%
| 74-97-5 |
|
Xanthopterin monohydrate
| 5979-01-1 |
|
2-Ethyl-1-Butanol, 98%
| 97-95-0 |
|
Oleyl alcohol, tech., 70% (gc)
| 143-28-2 |
|
alpha,alpha,alpha,2-Tetrachloro-6-fluorotoluene, 98%
| 84473-83-6 |
|
bis(4-Diethylaminodithiobenzil)nickel, laser grade, 99% (uv-vis)
| 51449-18-4 |
|
4-Nitrotoluene, 99%
| 99-99-0 |
|
2-Cyanopyridine, 99%
| 100-70-9 |
|
N-Carbobenzyloxy-L-Aspartic Acid, 98%
| 1152-61-0 |
|
Alizarin Red S (cert), 90% (uv-vis)
| 130-22-3 |
|
4-Chloroaniline, 99% (Titr.)
| 106-47-8 |
|
Methyl-2-methyl-3-furancarboxylate, 99%
| 6141-58-8 |
|
Ethyl Red Iodide, 98%
| 634-21-9 |
|
Hafnium chloride, 99%, -80 mesh
| 13499-05-3 |
|
Trans-2-Cyano-1-Cyclohexanol, 99+%
| 63301-31-5 |
|
3,3-Dimethoxy-Propanenitrile, 97%
| 57597-62-3 |
|
Scandium atomic absorption standard solution, 1 mg/ml Sc in 2% HNO3
| 7440-20-2 |
|
2-Vinylquinoline, 99% (Titr.)
| 772-03-2 |
|
4-Cumylphenol, 99%
| 599-64-4 |
|
2-Chlorobenzyl Bromide, 98%
| 611-17-6 |
|
Ethyl bis(ethylthio)acetate, 99%
| 20461-95-4 |
|
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| 2498-20-6 |
|
4-Ethyl-3-Thiosemicarbazide, 97%
| 13431-34-0 |
|
3',5'-Dimethoxy-4'-Hydroxyacetophenone 97%
| 2478-38-8 |
|
4,5-Dimethyl-2-isobutylthiazole, 98%
| 53498-32-1 |
|
1,1-Diphenyl-2-propanol, 98%
| 29338-49-6 |
|
Fast Violet B Salt, Purified
| 14726-28-4 |
|
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| 6205-69-2 |
|
|