**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 64-17-5 |Ethanol | 82 | 200-578-6 |
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methanol | 5 | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 1936-15-8 |Orange G | <1.0 | 217-705-6 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Deionized Water | Balance | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 12067-99-1 |Phosphotungstic Acid | <1.0 | 235-087-6 |
+----------------+--------------------------------------+----------+-----------+
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury. Vapors may cause
eye irritation. May cause painful sensitization to light.
Skin:
May cause skin irritation. May be absorbed through the skin in
harmful amounts.
Ingestion:
May be fatal or cause blindness if swallowed. May cause
gastrointestinal irritation with nausea, vomiting and diarrhea. May
cause systemic toxicity with acidosis. May cause liver and kidney
damage. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Harmful if inhaled. May cause liver and kidney damage. May cause
visual impairment and possible permanent blindness. May cause effects
similar to those described for ingestion. May cause respiratory tract
irritation. May cause narcotic effects. May cause drowsiness,
unconsciousness, and central nervous system depression.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Prolonged
or repeated eye contact may cause conjunctivitis. Chronic inhalation
and ingestion may cause effects similar to those of acute inhalation
and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Flammable Liquid.
Can release vapors that form explosive mixtures at temperatures
above the flashpoint. Use water spray to keep fire-exposed
containers cool.
Extinguishing Media:
Use water spray to cool fire-exposed containers. In case of fire use
water spray, dry chemical, carbon dioxide, or chemical foam.
Autoignition Temperature: 55 deg F ( 12.78 deg C)
Flash Point: Not applicable.
NFPA Rating: Not published.
Explosion Limits, Lower: 3.3
Upper: 1.9
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container. Remove all sources of
ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Avoid
contact with heat, sparks and flame. Avoid ingestion and inhalation.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: red
Odor: pungent
pH: Not available.
Vapor Pressure: 40 mm Hg @19C
Vapor Density: 1.59
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: 95 deg C
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: Soluble in water.
Specific Gravity/Density: 1
Molecular Formula: Not available.
Molecular Weight: Not available.
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, excess
heat.
Incompatibilities with Other Materials:
Ethanol is incompatible with acetic anhydride, acetyl bromide,
ammonia + silver nitrate, disulfuric acid + nitric acid,
dichloromethane + sulfuric acid, disulfuryl difluoride, magnesium
perchlorate, nitric acid + silver, oxidants, phosphorus (III) oxide,
platinum, potassium, potassium tert-butoxide, silver nitrate, silver
oxide, sodium, tetrachlorosilane, Methanol is incompatible with
acetyl bromide, alkylaluminum solutions, beryllium hydride, carbon
tetrachloride + metals, chloroform + sodium, chloroform + sodium
hydroxide, cyanuric chloride, dichloromethane, diethylzinc, metals,
oxidants,phosphorus (III) oxide, and potassium tert-butoxide.
Hazardous Decomposition Products:
Oxides of nitrogen, oxides of carbon.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 64-17-5: KQ6300000
CAS# 67-56-1: PC1400000
CAS# 1936-15-8: QJ6500000
CAS# 7732-18-5: ZC0110000
CAS# 12067-99-1: TH5650000
LD50/LC50:
CAS# 64-17-5: Inhalation, mouse: LC50 =39 gm/m3/4H; Inhalation, rat:
LC50 =20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit:
LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg.
CAS# 67-56-1: Inhalation, rat: LC50 =64000 ppm/4H; Oral, mouse: LD50
= 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 =
5628 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 1936-15-8.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 12067-99-1: Oral, rat: LD50 = 3300 mg/kg.
Carcinogenicity:
Ethanol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methanol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Orange G -
IARC: Group 3 carcinogen
Deionized Water -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Phosphotungstic Acid -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
No information available.
IATA
No information available.
RID/ADR
No information available.
Canadian TDG
Shipping Name: VINYL ACETATE
Hazard Class: 3(9.2)
UN Number: UN1301
Other Information: FLASHPOINT -8C
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 1936-15-8:
CAS# 7732-18-5:
CAS# 12067-99-1:
Canada
CAS# 64-17-5 is listed on Canada's DSL/NDSL List.
CAS# 67-56-1 is listed on Canada's DSL/NDSL List.
CAS# 1936-15-8 is listed on Canada's DSL/NDSL List.
CAS# 7732-18-5 is listed on Canada's DSL/NDSL List.
CAS# 12067-99-1 is listed on Canada's DSL/NDSL List.
This product has a WHMIS classification of B2, D1B, D2B.
CAS# 64-17-5 is listed on Canada's Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 1936-15-8 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 12067-99-1 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 64-17-5:. OEL-AUSTRALIA:TWA 1000 ppm (1900 mg/m3). OEL-BELGIUM:T
WA 1000 ppm (1880 mg/m3). OEL-CZECHOSLOVAKIA:TWA 1000 mg/m3;STEL 5000
mg/m3. OEL-DENMARK:TWA 1000 ppm (1900 mg/m3). OEL-FINLAND:TWA 1000 ppm
(1900 mg/m3);STEL 1250 ppm (2400 mg/m3). OEL-FRANCE:TWA 1000 ppm (190
0 mg/m3);STEL 5000 pp. OEL-GERMANY:TWA 1000 ppm (1900 mg/m3). OEL-HUNG
ARY:TWA 1000 mg/m3;STEL 3000 mg/m3. OEL-THE NETHERLANDS:TWA 1000 ppm (
1900 mg/m3). OEL-THE PHILIPPINES:TWA 1000 ppm (1900 mg/m3). OEL-POLAND
:TWA 1000 mg/m3. OEL-RUSSIA:STEL 1000 mg/m3. OEL-SWEDEN:TWA 1000 ppm (
1900 mg/m3). OEL-SWITZERLAND:TWA 1000 ppm (1900 mg/m3). OEL-THAILAND:T
WA 1000 ppm (1900 mg/m3). OEL-TURKEY:TWA 1000 ppm (1900 mg/m3). OEL-UN
ITED KINGDOM:TWA 1000 ppm (1900 mg/m3) JAN9. OEL IN BULGARIA, COLOMBIA
, JORDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNA
M check ACGI TLV
CAS# 67-56-1:. OEL-ARAB Republic of Egypt:TWA 200 ppm (260 mg/m3);Ski
n. OEL-AUSTRALIA:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL-BELGIU
M:TWA 200 ppm (262 mg/m3);STEL 250 ppm;Skin. OEL-CZECHOSLOVAKIA:TWA 10
0 mg/m3;STEL 500 mg/m3. OEL-DENMARK:TWA 200 ppm (260 mg/m3);Skin. OEL-
FINLAND:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL-FRANCE:TWA 200
ppm (260 mg/m3);STEL 1000 ppm (1300 mg/m3). OEL-GERMANY:TWA 200 ppm (2
60 mg/m3);Skin. OEL-HUNGARY:TWA 50 mg/m3;STEL 100 mg/m3;Skin JAN9. OEL
-JAPAN:TWA 200 ppm (260 mg/m3);Skin. OEL-THE NETHERLANDS:TWA 200 ppm (
260 mg/m3);Skin. OEL-THE PHILIPPINES:TWA 200 ppm (260 mg/m3). OEL-POLA
ND:TWA 100 mg/m3. OEL-RUSSIA:TWA 200 ppm;STEL 5 mg/m3;Skin. OEL-SWEDEN
:TWA 200 ppm (250 mg/m3);STEL 250 ppm (350 mg/m3);Skin. OEL-SWITZERLAN
D:TWA 200 ppm (260 mg/m3);STEL 400 ppm;Skin. OEL-THAILAND:TWA 200 ppm
(260 mg/m3). OEL-TURKEY:TWA 200 ppm (260 mg/m3). OEL-UNITED KINGDOM:TW
A 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL IN BULGARIA, COLOMBIA, JO
RDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNAM ch
eck ACGI TLV
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 1936-15-8 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 12067-99-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/12/1995 Revision #2 Date: 9/02/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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