LCI (LUCIER CHEMICAL INDUSTRIE -- FLUOROSILICIC ACID
=======================================================
Material Safety Data Sheet
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NIIN: 00-935-5817
MSDS Num: BZQWW
MSDS NAME: FLUOROSILICIC ACID
Responsible Party
Name: LCI (LUCIER CHEMICAL INDUSTRIES) LTD
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Info Phone: 904-241-1200
Emergency Phone Number: 904-241-1200, CHEMTREC 800-424-9300
Preparer's Name: J. MICHAEL COATES
Review Ind: Y
Published: Y
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Contractor Summary
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Name: HOC INDUSTRIES, INC
Address: 3511 N. OHIO
Box: 2609
City: WICHITA KS 67219
Phone: 316-838-4663
Name: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Address: 415 PABLO AVE N
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Phone: 904-241-1200
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Item Description Information
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Item Manager: S9G
Item Name: HYDROFLUOSILICIC ACID
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: DR
Quantitative Expression: 00000000140LB
UI Container Qty: 0
Type of Container: DRUM
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Ingredients
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Cas: 16961-83-4
RTECS #: VV8225000
Name: FLUOROSILIC ACID OR HYDROFLUOROSILICIC ACID OR HEXAFLUOROSILIC ACID
% Wt: 100
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Health Hazards Data
=======================================================
LD50 LC50 Mixture: TLV=2.5 MG/M3 (AS F)
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: LIQUID OR VAPORS CAUSE SEVERE IRRITATION AND BURNS
WHICH MAY NOT BE APPARENT FOR HOURS. CAN CAUSE SEVERE IRRITATION TO THE
LUNGS, NOSE, AND THROAT. IF SWALLOWED, CAN CAUSE SEVERE DAMAGE TO THRO AT AND
STOMACH. CHRONIC: PROLONGED OR REPEATED EXPOSURE MAY CAUSE BONE CHANGES,
ULCERATION OF NOSE/THROAT, FLUOROSIS...
Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR
GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Signs And Symptions Of Overexposure: INHALED-IRRITATION, COUGH. SKIN-SEVERE
IRRITATION. EYES-SEVERE IRRITATION. INGESTED-SEVERE DAMAGE TO THROAT AND
STOMACH.
Medical Cond Aggravated By Exposure: ANY SKIN CONDITION AND/OR PREEXISITING
RESPIRATORY DISEASE INCLUDING ASTHMA AND EMPHYSEMA.
First Aid: IN ALL CASES GET IMMEDIATE MEDICAL ATTENTION! EYES-FLUSH WITH WATER
FOR 15 MINUTES, LIFT LIDS. SKIN-REMOVE CONTAMINATED CLOTHES WHILE SHOWERING
IN FLOODING AMOUNTS OF WATER. INHALED-REMOVE TO FRESH AI R. ADMINISTER OXYGEN
OR ARTIFICIAL RESPIRATION AS NEEDED. INGESTED-IF CONSCIOUS, GIVE LOTS OF
WATER OR MILK TO DILUTE. DO NOT INDUCE VOMITING!!
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: ISOLATE AREA & DENY ENTRY. WEAR ACID-PROOF
PROTECTIVE CLOTHING & GEAR. STOP LEAK IF FEASIBLE. CONTAIN SPILL. KEEP
OUT OF SEWERS & WATERWAYS. ABSORB WITH INERT MATERIAL (EG SAND) &
SCOOP UP & PLACE IN A COMPATIBLE CONTAINER FOR DISPOSAL. REPORT SPILL.
Neutralizing Agent: DLA-: 20% SODIUM BICARBONATE SOLUTION.
Waste Disposal Methods: PER MFR PRODUCT NOT LISTED AS RCRA HAZWASTE. DISPOSE OF
IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS. DLA-:
EPA/RCRA HAZWASTE NUMBER D002 MAY APPLY TO UNUSED/UNCONTAMINATE D PRODUCT.
Handling And Storage Precautions: DLA-: STORE IN A COOL, DRY PLACE AWAY FROM
TEMPERATURES ABOVE 220F AND INCOMPATIBLE MATERIALS. KEEP CONTAINER CLOSED
WHEN NOT IN USE.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL
CHEMICAL PROTECTIVE SUIT. USE WATER TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: REACTS WITH MAY METALS TO PRODUCE FLAMMABLE
& EXPLOSIVE HYDROGEN GAS. DECOMPOSITION MAY PRODUCE TOXIC AND CORROSIVE
FUMES OF FLUORIDES.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN
EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH ACID CARTRIDGE
OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29 CFR 19 10.134.
Ventilation: USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN
EXPOSURE BELOW TLV(S).
Protective Gloves: ACID-PROOF: PVC, NEOPRENE, VITON.
Eye Protection: SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment: EYE WASH STATION & SAFETY SHOWER. ACID-PROOF BOOTS
(SAME AS GLOVES).
Work Hygienic Practices: WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING,
OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health: PH GIVEN IS FOR 1% AQUEOUS SOLUTION. MSDS
PROVIDED BY CAGE 0A9L8 FOR CONTRACT NUMBER SP0450-96-M-L-201.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: C1
B.P. Text: 222F,106C
M.P/F.P Text: -4F,-20C
Decomp Text: 227F,108C
Vapor Pres: 24
Vapor Density: UNKNOWN
Spec Gravity: 1.234
PH: 1.2
Viscosity: UNKNOWN
Evaporation Rate & Reference: UNKNOWN
Solubility in Water: COMPLETE
Appearance and Odor: WATER-WHITE TO STRAW YELLOW FUMING LIQUID; PUNGENT ODOR.
Corrosion Rate: UNKNOWN
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Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: DLA-: HEAT ABOVE 220F. CONTACT WITH INCOMPATIBLE
MATERIALS.
Materials To Avoid: METAL, GLASS, STONEWARE, ALKALI, STRONG CONCENTRATED ACIDS.
Hazardous Decomposition Products: WHEN HEATED TO DECOMPOSITION, PRODUCES TOXIC
& CORROSIVE FUMES OF HYDROGEN FLUORIDE, SILICA TETRAFLUORIDE, HYDROGEN GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 93278
MSDS NAME: FLUOROSILICIC ACID
MSDS Prepared Date: 03/01/1996
Review Date: 08/14/1996
Net Unit Weight: 110 LB
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 0
Type Of Container: DRUM
Additional Data: PSN IS PER MFR MSDS. PACKAGING IS PER DLSC-TIR.
=======================================================
Detail DOT Information
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DOT PSN Code: GMU
DOT Proper Shipping Name: FLUOROSILICIC ACID
Hazard Class: 8
UN ID Num: UN1778
DOT Packaging Group: II
Label: CORROSIVE
Special Provision: A6,A7,B2,B15,N3,N34,T12,T27
Packaging Exception: NONE
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 1 L
Max Qty Cargo: 30 L
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: HLP
IMO Proper Shipping Name: FLUOROSILICIC ACID
IMDG Page Number: 8176
UN Number: 1778
UN Hazard Class: 8
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 8-06
MED First Aid Guide NUM: 750
=======================================================
Detail IATA Information
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IATA PSN KC
IATA UN ID Num: 1778
IATA Proper Shipping Name: FLUOROSILICIC ACID
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: II
Packing Note Passenger: 809
Max Quant Pass: 1L
Max Quant Cargo: 30L
Packaging Note Cargo: 813
=======================================================
Detail AFI Information
=======================================================
AFI PSN KC
AFI Proper Shipping Name: FLUOROSILICIC ACID
AFI Hazard Class: 8
AFI UN ID NUM: UN1778
AFI Packing Group: II
Special Provisions: P5, A6, A7, N34, N3
Back Pack Reference: A12.3
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: FLUOROSILICIC ACID
Company: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Street: 415 PABLO AVE N
PO Box: 49000
City: JACKSONVILLE BEACH FL
Zipcode: 32240-9000
Health Emergency Phone: 316-838-4663
Label Required IND: Y
Date Of Label Review: 08/14/1996
Status Code: C
Label Date: 08/14/1996
Year Procured: 1996
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: CORROSIVE! LIQUID/VAPORS CAUSE SEVERE IRRITATION &
BURNS.CAN CAUSE SEVERE IRRITATION TO THE LUNGS,NOSE & THROAT.IF
SWALLOWED,CAN CAUSE SEVERE DAMAGE TO THROAT & STOMACH.PROLONGED/REPEATED
EXPOSURE MAY CAUSE BONE CHANGES,ULCERATION OF NOSE/THROAT,FLUOROSIS. TARGET
ORGANS:SKIN,EYS,LUNGS,BONES. FIRST AID:IN ALL CASES GET IMMEDIATE MEDICAL
ATTENTION!EYES-FLUSH WITH WATER FOR 15 MINUTES,LIFT LIDS.SKIN- REMOVE
CONTAMINATED CLOTHES WHILE SHOWERING IN FLOODING AMOUNTS OF
WATER.INHALED-REMOVE TO FRESH AIR.ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION
AS NEEDED.INGESTED-IF CONSCIOUS,GIVE LOTS OF WATER OR M ILK TO DILUTE.DO NOT
INDUCE VOMITING!!
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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