2-propenoic acid, 2-cyano-, ethyl ester; (ethyl cyanoacrylate) polymethylmethacrylate; (poly (methyl methacrylate) hydroquinone (sara 302/313) (cercla) supdat: polyethylene gloves & apron when hdnlg lg amts of adhesive. ing 5:warm, soapy water. peel/roll surfs apart w/aid of blunt edge, eg, ing 6: from skin w/soap & water. do not try to pull surfs apart ing 7: eyeball adhesion: in event eyelids are stuck together/bonded to ing 8: least 15 min & apply gauze patch. eye will open w/out further ing 9:be no residual dmg. do not try to open eyes by manipulation. ing 10:into eyes will attach itself to eye protein & will disassoc ing 11: covering several hrs. this will cause periods of weeping until ing 12: contam, double vision may be experienced together w/lachrymatory ing 13: cause & realize that disassoc will norm occur w/in matter of ing 14: are accidentally stuck together, apply lots of warm water to lips ing 15: saliva inside mouth. peel/roll lips apart. do not try to pull ing 16: almost impossible to swallow cyanoacrylate. adhesive solidifies ing 17:adhesive in one half to two days. in case a lump forms in mouth, ing 18: when it detaches. burns:cyanoacrylates give off heat on ing 19: in temp enough to cause burn. burns should be treated norm after ing 20: tiss as described above. surgery: it should never be nec to use ing 21: accidentally bonded skin. eye prot: and full length faceshield (fp n).
LOCTITE CORP -- PRISM 406 SURF-INSENSITIVE INST ADH, 40640
=======================================================
Material Safety Data Sheet
=======================================================
NIIN: 01-388-0735
MSDS Num: BZRBQ
MSDS NAME: PRISM 406 SURF-INSENSITIVE INST ADH, 40640
Responsible Party
Name: LOCTITE CORP
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Info Phone: 203-571-5100
Emergency Phone Number: 203-571-5100
Preparer's Name: STEPHEN REPETTO
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORP
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
Name: LOCTITE CORP
Address: 705 N MT RD
City: NEWINGTON CT 06111
Phone: 312-689-6200
=======================================================
Item Description Information
=======================================================
Item Name: ADHESIVE
=======================================================
Ingredients
=======================================================
Cas: 7085-85-0
RTECS #: UD3300000
Name: 2-PROPENOIC ACID, 2-CYANO-, ETHYL ESTER; (ETHYL CYANOACRYLATE)
% Wt: 95-100
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE; (POLY (METHYL METHACRYLATE)
% Wt: 1-3
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE (SARA 302/313) (CERCLA)
% Wt: 0.1-0.5
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Name: SUPDAT: POLYETHYLENE GLOVES & APRON WHEN HDNLG LG AMTS OF ADHESIVE.
SKIN ADHESION:FIRST IMMERSE BONDED SURFS IN
-----------------------------
Name: ING 5:WARM, SOAPY WATER. PEEL/ROLL SURFS APART W/AID OF BLUNT EDGE, EG,
SPATULA/TSP HANDLE; THEN REMOVE ADHESIVE
-----------------------------
Name: ING 6: FROM SKIN W/SOAP & WATER. DO NOT TRY TO PULL SURFS APART
W/DIRECT OPPOSING ACTION. EYELID TO EYELID OR
-----------------------------
Name: ING 7: EYEBALL ADHESION: IN EVENT EYELIDS ARE STUCK TOGETHER/BONDED TO
EYEBALL, WASH THORO W/WARM WATER FOR AT
-----------------------------
Name: ING 8: LEAST 15 MIN & APPLY GAUZE PATCH. EYE WILL OPEN W/OUT FURTHER
ACTION, TYPICALLY IN 1-4 DAYS. THERE WILL
-----------------------------
Name: ING 9:BE NO RESIDUAL DMG. DO NOT TRY TO OPEN EYES BY MANIPULATION.
ADHESIVE ON EYEBALL:CYANOACRYLATE INTRODUCED
-----------------------------
Name: ING 10:INTO EYES WILL ATTACH ITSELF TO EYE PROTEIN & WILL DISASSOC
FROM IT OVER INTERMITTENT PERIODS, GENERALLY
-----------------------------
Name: ING 11: COVERING SEVERAL HRS. THIS WILL CAUSE PERIODS OF WEEPING UNTIL
CLEARANCE IS ACHIEVED. DURING PERIOD OF
-----------------------------
Name: ING 12: CONTAM, DOUBLE VISION MAY BE EXPERIENCED TOGETHER W/LACHRYMATORY
EFT & IT IS IMPORTANT TO UNDERSTAND
-----------------------------
Name: ING 13: CAUSE & REALIZE THAT DISASSOC WILL NORM OCCUR W/IN MATTER OF
HRS, EVEN W/GROSS CONTAM. MOUTH: IF LIPS
-----------------------------
Name: ING 14: ARE ACCIDENTALLY STUCK TOGETHER, APPLY LOTS OF WARM WATER TO LIPS
& ENCOURAGE MAX WETTING & PRESS FROM
-----------------------------
Name: ING 15: SALIVA INSIDE MOUTH. PEEL/ROLL LIPS APART. DO NOT TRY TO PULL
LIPS W/DIRECT OPPOSING ACTION. IT IS
-----------------------------
Name: ING 16: ALMOST IMPOSSIBLE TO SWALLOW CYANOACRYLATE. ADHESIVE SOLIDIFIES
& ADHERES IN MOUTH. SALIVA WILL LIFT
-----------------------------
Name: ING 17:ADHESIVE IN ONE HALF TO TWO DAYS. IN CASE A LUMP FORMS IN MOUTH,
POSITION PATIENT TO PVNT INGEST OF LUMP
-----------------------------
Name: ING 18: WHEN IT DETACHES. BURNS:CYANOACRYLATES GIVE OFF HEAT ON
SOLIDIFICATION. IN RARE CASES LG DROP WILL INCR
-----------------------------
Name: ING 19: IN TEMP ENOUGH TO CAUSE BURN. BURNS SHOULD BE TREATED NORM AFTER
LUMP OF CYANOACRYLATE IS RELSD FROM
-----------------------------
Name: ING 20: TISS AS DESCRIBED ABOVE. SURGERY: IT SHOULD NEVER BE NEC TO USE
SUCH DRASTIC METH TO SEPARATE
-----------------------------
Name: ING 21: ACCIDENTALLY BONDED SKIN.
-----------------------------
Name: EYE PROT: AND FULL LENGTH FACESHIELD (FP N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50: (ORAL) > 5000 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: VAPOR IS IRRITATING TO EYES AND MUCOUS MEMBRANES ABOVE
TLV. PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE ALLERGIC
REACTIONS WITH ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS. SKIN CONTAC T
MAY CAUSE BURNS. BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE IRRITANT.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INHAL:REMOVE TO FRESH AIR. IF SYMPS PERSIST, OBTAIN MED ATTN.
CYANOACRYLATE ADHESIVE IS VERY FAST SETTING & STRONG ADHESIVE; BONDS
HUMAN TISS INCL SKIN IN SECONDS. EXPERIENCE HAS SHOWN ACCIDENTS DUE T O
CYANOACRYLATES ARE HANDLED BEST BY PASSIVE, NONSURGICAL FIRST AID. TREATMENT
OF SPECIFIC TYPES ARE AS FOLLOWS: SKIN CNTCT: REMOVE EXCESS ADHESIVE. SOAK IN
WARM, SOAPY WATER. ADHESIVE WILL (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE COMPLETELY. POLYMER
MAY BE HANDLED AS A NON-TOXIC WASTE.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: AFTER POLYMERIZATION, INCINERATE FOLLOWING EPA,
FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE BELOW 75. CONTACT MANUFACTURER CUSTOMER
SERVICE 1-800-243-4874 FOR SHELF LIFE INFORMATION).
Other Precautions: AVOID PROLONGED SKIN OR EYE CONTACT. AVOID BREATHING VAPOR.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >150F,>66C
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: NITRILE OR POLYETHYLENE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
APRONS. DO NOT USE COTTON.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRST AID PROC: COME LOOSE FROM SKIN IN SEVERAL
HRS. CURED ADHESIVE DOES NOT PRESENT HLTH HAZ EVEN WHEN BONDED TO SKIN. AVOID
CNTCT W/CLTHG, FABRICS, RAGS/TISS. CNTCT W/THESE MATLS MAY CAUSE POLYM. PO
LYM OF LG AMTS OF ADHESIVE WILL GENERATE HEAT CAUSING SMOKE, SKIN BURNS &
STRONG, IRRIT VAPS. WEAR NITRILE OR
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >300F,>149C
Vapor Pres: <0.2
Vapor Density: APPROX 3
Spec Gravity: 1.05 @ 75F
VOC Grams/Liter: 857
Solubility in Water: POLYMERIZED
Appearance and Odor: WATER WHITE TO STRAW COLORED LIQUID; SHARP, IRRITATING
ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: POLYMERIZED BY CONTACT WITH WATER, ALCOHOLS, AMINES OR
ALKALIES.
Hazardous Decomposition Products: BY FIRE OR THERMAL DECOMPOSITION: IRRITATING
ORGANIC FRAGMENTS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PRISM 406 SURF-INSENSITIVE INST ADH, 40640
Company: LOCTITE CORP
Street: 705 N MT RD
City: NEWINGTON CT
Zipcode: 06111
Health Emergency Phone: 203-571-5100
Label Required IND: Y
Date Of Label Review: 10/26/1995
Status Code: C
Label Date: 10/26/1995
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: VAPOR IS IRRITATING TO EYES AND
MUCOUS MEMBRANES ABOVE TLV. PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAY
PRODUCE ALLERGIC REACTIONS WITH ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDI
VIDUALS. SKIN CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY AND STRONGLY. SKIN
AND EYE IRRITANT. CHRONIC: NONE LISTED BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.