bisphenol a epoxy resin; (epoxy resin) titanium oxide; (titanium dioxide) barium sulfate amorphous silica gel; (silica, amorphous) aluminum hydroxide sup dat: titanium dioxide: lab studies show that inhal expos to high ing 7: causes cancerous tumors in rats. this response occurs at lower ing 8: overwhelming norm lung clearance mechanisms. the relevance of this ing 9: where tlv is observed. epoxy resin: in vitro lab studies have ing 10: mutagenic capabilities while others have not.
HERBERTS-O'BRIEN INC -- ASA 61 GRAY, EFH400S9
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CFSHL
MSDS NAME: ASA 61 GRAY, EFH400S9
Responsible Party
Name: HERBERTS-O'BRIEN INC
Address: 9800 GENARD RD
City: HOUSTON TX 77041-7624
Info Phone: 713-939-4025
Emergency Phone Number: 713-939-4000;800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: DUPONT POWDER COATINGS
Address: 9800 GENARD RD
City: HOUSTON TX 77041-7624
Phone: 713-939-4000
Name: HERBERTS-O'BRIEN INC
Address: 9800 GENARD RD
City: HOUSTON TX 77041-7624
Phone: 713-939-4000; -4025 FAX
=======================================================
Ingredients
=======================================================
Cas: 25036-25-3
Name: BISPHENOL A EPOXY RESIN; (EPOXY RESIN)
% Wt: 30-60
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 10-30
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 7727-43-7
RTECS #: CR0600000
Name: BARIUM SULFATE
% Wt: 5-10
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 112926-00-8
Name: AMORPHOUS SILICA GEL; (SILICA, AMORPHOUS)
% Wt: 0.5-1.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 21645-51-2
RTECS #: BD0940000
Name: ALUMINUM HYDROXIDE
% Wt: 0.5-1.5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: SUP DAT: TITANIUM DIOXIDE: LAB STUDIES SHOW THAT INHAL EXPOS TO HIGH
LEVELS (250 MG/KG) OF TITANIUM DIOXIDE
-----------------------------
Name: ING 7: CAUSES CANCEROUS TUMORS IN RATS. THIS RESPONSE OCCURS AT LOWER
EXPOS LEVELS & MAY BE DUE TO HIGH LEVELS
-----------------------------
Name: ING 8: OVERWHELMING NORM LUNG CLEARANCE MECHANISMS. THE RELEVANCE OF THIS
DATA TO HUMANS IS NOT SIGNIFICANT
-----------------------------
Name: ING 9: WHERE TLV IS OBSERVED. EPOXY RESIN: IN VITRO LAB STUDIES HAVE
SHOWN THAT SOME EPOXY RESINS HAVE
-----------------------------
Name: ING 10: MUTAGENIC CAPABILITIES WHILE OTHERS HAVE NOT.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: BARIUM SULFATE: INHAL OF DUSTS MAY BE IRRIT TO RESP
TRACT. CONT W/EYES MAY ALSO CAUSE IRRIT. TITANIUM DIOXIDE: INGEST: LOW ORAL
TOXICITY. INHAL: IRRIT TO UPPER RESP TRACT. EYE: IRRIT. ALUMINUM HYDROXIDE:
DUST EXPOS CAUSES EYE IRRIT;BASIC EYE BURNS ARE POSS DEPENDING UPON DURATION
OF CONT. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: THIS MATL IS REPORTED TO EXHIBIT
A LOW ORDER OF TOXICITY VIA INHAL & INGEST. PRLNG SKIN CONT MAY RSLT IN
MINOR MECH IRRIT. EPOXY RESIN: INGEST: LOW ORDER OF TOXICITY. INHAL: NOT A
LIKELY RTE OF EXPOS DUE TO VERY LOW VOLATILITY. EYE/SKIN: MAY CAUSE SLIGHT
IRRIT. SILICA, AMORPHOUS: CONT W/DUST MAY (SUP DAT)
Medical Cond Aggravated By Exposure: EPOXY RESIN: MAY AGGRAVATE EXISTING SKIN
CONDITIONS, A DERMAL ALLERGEN. SILICA, AMORPHOUS: PREEXISTING LUNG DISEASES
MAY INCREASE SUSCEPTIBILITY TO EFFECTS OF EXCESSIVE AMORPHOUS SILICA DUST
EXPOS.
First Aid: EYES: FLUSH WITH COOL WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY
LIFTING LIDS TO ENSURE THOROUGH RINSING. SEEK MEDICAL ASSISTANCE. SKIN: WASH
THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM A REA TO FRESH AIR.
INGESTION: DRINK 1 OR2 GLASSES OF WATER AND INDUCE VOMITING BY PLACING FINGER
AT BACK OF THROAT. SEEK MEDICAL ASSISTANCE.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SWEEP UP CAREFULLY OR USE EXPLOSION-PROOF VACUUM
CLEANER, THEN DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: MANAGE OR DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
Handling And Storage Precautions: KEEP ALL EQUIPMENT CLEAN AND PROPERLY
GROUNDED TO AVOID STATIC ELECTRICITY DISCHARGE. KEEP WORK AREAS FREE OF DUST.
AVOID EXCESSIVE SKIN CONTACT.
Other Precautions: DO NOT INGEST OR INHALE. KEEP OUT OF THE REACH OF CHILDREN.
KEEP CONTAINERS SEALED AND AVOID STATIC ELECTRICITY DISCHARGES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG, DRY SAND.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE A PROPERLY FITTED NIOSH APPROVED MECHANICAL
RESPIRATOR OR MASK TO AVOID BREATHING DUST. CAREFULLY FOLLOW RESPIRATOR
MANUFACTURER'S INSTRUCTIONS FOR USE.
Ventilation: PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP AIR CONTAM
CONC BELOW APPLIC OSHA PEL OR ACGIH TLV LIMIT.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). PROTECTIVE OVERALLS RECOMMENDED.
Work Hygienic Practices: REMOVE AND WASH SOILED CLOTHING.
Supplemental Safety and Health: EFTS OF OVEREXP: INCL EYE IRRIT (DISCOMFORT,
TEARING/BLURRING OF VISION) OR SLIGHT SKIN IRRIT (DISCOMFORT/RASH). OVEREXP
TO DUST BY INHAL MAY CAUSE TEMPORARY LUNG IRRIT (COUGH, DISCOMFORT/DFCLTY IN
BR THG). CHRONIC: BARIUM SULFATE: PRLNG EXPOS COULD CAUSE BENIGN
PNEUMOCONIOSIS CALLED BARITOSIS.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.60095
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: FUMES MAY CONTAIN CARBON MONOXIDE, CARBON
DIOXIDE, NO*2 OR OTHER NITROGEN COMPOUNDS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
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MSDS Transport Information
=======================================================
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Regulatory Information
=======================================================
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Other Information
=======================================================
Other Information: VOLATILE ORGANIC COMPOUND: 0 (US EPA VOC)
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: ASA 61 GRAY, EFH400S9
Assigned IND: Y
Company: HERBERTS-O'BRIEN INC
Street: 9800 GENARD RD
City: HOUSTON TX
Zipcode: 77041-7624
Health Emergency Phone: 713-939-4000;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 11/20/1997
Status Code: C
Label Date: 11/20/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: BARIUM SULFATE: INHALATION OF DUSTS MAY BE
IRRITATING TO RESPIRATORY TRACT. CONTACT WITH EYES MAY ALSO CAUSE IRRITATION.
TITANIUM DIOXIDE: INHALATION: IRRITATING TO UPPER RESPIRATORY TRACT. EYE S:
IRRITATION. ALUMINUM HYDROXIDE: DUSTEXPOSURE CAUSES EYE IRRITATION; BASIC EYE
BURNS ARE POSSIBLE DEPENDING UPON DURATION OF CONTACT. EPOXY RESIN:
EYES/SKIN: SLIGHT IRRITATION. AMORPHOUS SILICA: EYE S/SKIN/INHALATION:
IRRITATION. CHRONIC: BARITOSIS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.