HARWICK CHEMICAL CORP -- MASTERMIX ETU 9442-MC
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Material Safety Data Sheet
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MSDS Num: CFSNR
MSDS NAME: MASTERMIX ETU 9442-MC
Responsible Party
Name: HARWICK CHEMICAL CORP
Address: 60 SOUTH SEIBERLING ST
Box: 9360
City: AKRON OH 44305-0360
Info Phone: 330-798-9300
Emergency Phone Number: 330-798-9300
Published: Y
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Contractor Summary
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Name: HARWICK CHEMICAL CORPORATION
Address: 60 SOUTH SEIBERLING STREET
Box: 9360
City: AKRON OH 44305
Phone: 216-798-9300
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Ingredients
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Cas: 96-45-7
RTECS #: NI9625000
Name: 2-IMIDAZOLIDINETHIONE; (ETHYLENE THIOUREA) (SARA 313) (CERCLA)
% Wt: 70-80
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 471-34-1
RTECS #: FF9335000
Name: CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE). PEL:15 MG/M3; 5
MG/M3 (MFR).
% Wt: 1-5
OSHA PEL: SEE INGREDIENT
ACGIH TLV: 10 MG/M3 (MFR)
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:ETU IS IRRIT TO SKIN & CAN BE ABSORBED THRU
SKIN. MATL IS IRRIT TO EYES. ACUTE EXPOS VIA INGEST BY ANIMALS HAS CAUSED
FETAL PULM EDEMA. CHRONIC:ETU PRDCD THYROID CARCINOMAS IN RATS BY ORAL ADMIN
& INCR INCIDENCE OF LIVER CELL TUMORS IN 2 STRAINS OF MICE FOLLOWING ORAL
ADMIN. ETHYLENE THIOUREA IS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: ETHYLENE THIOUREA:IARC MONOGRAPHS, SUPP, VOL 7,
PG 207, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ:A GOITROGEN, TERATOGEN, POSS
CARCIN & MAY CAUSE CHROMOSOMAL ABERRATION. ETU ACCUMS IN THYROID GLAND.
PREGNANT WOMEN & WOMEN OF CHILDBEARING YEARS ARE AT INCREASED RISK FROM
EXPOS. NOTE:THIS P ROD IS ENCAPSULATED IN A POLYMERIC BINDER WHICH
REDUCES/ELIMS AIRBORNE PARTICULATES & MINS SKIN CONT. LIKEWISE, (SUPDAT)
Medical Cond Aggravated By Exposure: EXISTING THYROID OR LIVER DISORDERS OR
CONDITIONS.
First Aid: INHAL:MOVE TO FRESH AIR IMMEDIATELY. GET MEDICAL ATTENTION IF
RESPIRATORY IRRITATION DEVELOPS OR IF BREATHING BECOMES DIFFICULT. INGEST:GET
MEDICAL ATTENTION IMMEDIATELY. SKIN:IMMEDIATELY REMOVE CONTA MINATED
CLOTHING. WASH W/SOAP & WATER. EYES:FLUSH W/WATER FOR AT LEAST 15
MINUTES. IF IRRITATION PERSISTS, CONSULT MD.
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Handling and Disposal
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Spill Release Procedures: SWEEP OR VACUUM UP. PLACE IN A SUITABLE CONTAINER FOR
REUSE OR DISPOSAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF I/A/W ALL FEDERAL, STATE & LOCAL
REGULATIONS.
Handling And Storage Precautions: AVOID CONTACT W/EYES, SKIN & CLOTHING.
STORE IN A COOL, DRY PLACE.
Other Precautions: IT IS RECOMMENDED THAT WOMEN OF CHILDBEARING AGE BE EXCLUDED
WHERE INHALATION OR CONTACT W/ETU IS POSSIBLE.
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Fire and Explosion Hazard Information
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Extinguishing Media: CO*2, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE KNOWN.
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Control Measures
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Respiratory Protection: A NIOSH APPROVED RESPIRATOR ABOVE PEL OR TLV OR AS
NECESSARY.
Ventilation: LOCAL EXHAUST &/OR MECHANICAL (GENERAL): RECOMMENDED TO
MINIMIZE EXPOSURE.
Protective Gloves: CHEMICAL RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER (FP
N). WEAR APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT ANY (SUPDAT)
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. A SHOWER IS
RECOMMENDED AFTER HANDLING THIS PRODUCT.
Supplemental Safety and Health: EXPLAN OF CARCIN:TO BE CARCIN. EFTS OF
OVEREXP:ADVERSE HLTH EFTS ASSOC W/THESE RTES OF EXPOS ARE ALSO
REDUCED/ELIMINATED. OTHER PROT EQUIP:POSSIBILITY OF SKIN CONTACT.
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Physical/Chemical Properties
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Spec Gravity: 1.25 (H*2O=1)
Solubility in Water: NEGLIGIBLE
Appearance and Odor: CREAM CUBE; NO ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: OVERHEATING DURING PROCESSING OR HIGH
TEMPERATURES DURING STORAGE.
Materials To Avoid: ACIDS, OXIDIZING AGENTS.
Hazardous Decomposition Products: NO*X, SO*X, NITROGEN AMINES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: MASTERMIX ETU 9442-MC
Company: HARWICK CHEMICAL CORPORATION
Street: 60 SOUTH SEIBERLING STREET
PO Box: 9360
City: AKRON OH
Zipcode: 44305
Health Emergency Phone: 330-798-9300
Label Required IND: Y
Date Of Label Review: 12/02/1997
Status Code: C
Label Date: 12/02/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:ETHYLENE THIOUREA IS IRRITATING TO SKIN AND CAN
BE ABSORBED THROUGH SKIN. MATERIAL IS IRRITATING TO EYES. ACUTE EXPOSURE VIA
INGESTION BY ANIMALS HAS CAUSED FETAL PULMONARY EDEMA. CHRONIC:CANCER
HAZARD. CONTAINS ETHYLENE THIOUREA, WHICH IS LISTED AS AN ANIMAL LIVER
CARCINOGEN (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
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utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.