PPG INDUSTRIES, INC. -- DURABLE YELLOW COLORANT, 96-7
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Material Safety Data Sheet
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MSDS Num: CJLXH
MSDS NAME: DURABLE YELLOW COLORANT, 96-7
Responsible Party
Name: PPG INDUSTRIES, INC.
Address: 4325 ROSANNA DR
Box: 9
City: ALLISON PARK PA 15101
Info Phone: 412-592-5555
Emergency Phone Number: 304-843-1300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: CITY GLASS AND PAINT
Address: 719 W 17TH ST
City: BLOOMINGTON IN 47401
Phone: 812-336-0138
Name: PPG INDUSTRIES, INC.
Address: 4325 ROSANNA DR
Box: 9
City: ALLISON PARK PA 15101
Phone: 412-592-5555
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Item Description Information
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Ingredients
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Cas: 107-21-1
RTECS #: KW2975000
Name: ETHYLENE GLYCOL
% low Wt: 20.
% high Wt: 30.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: C127 MG/M3;C50 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC (POWDER), CONTAINING NO ASBESTOS FIBERS
% low Wt: 10.
% high Wt: 20.
Other REC Limits: N/K (FP N)
OSHA PEL: see Table Z-3
OSHA STEL: N/K (FP N)
ACGIH TLV: 2 MG/M3
ACGIH STEL: N/K (FP N)
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Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE- QUARTZ
% low Wt: .1
% high Wt: 1.
Other REC Limits: N/K (FP N)
OSHA PEL: see Table Z-3
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: N/K (FP N)
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Name: ALKYL PHOSPHATE
% low Wt: 1.
% high Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Cas: 9084-06-4
RTECS #: EC4850000
Name: BLANCOL; (SURFACTANT)
% low Wt: 1.
% high Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: INGEST:HARMFUL IF SWALLOWED. EYES: CAUSES IRRIT.
SKIN: MAY CAUSE SLIGHT IRRIT. INHAL: VAP &/OR SPRAY MIST MAY BE HARMFUL
IF INHALED. CHRONIC: AVOID LONG-TERM & RPTD CONT. THIS PROD CONTAINS A F
ORM OF CRYSTALLINE SILICA/QUARTZ WHICH IARC ASSOCIATES W/AN INCRD RISK OF
CANCER IN LAB ANIMALS. LONG-TERM EXPOS TO CRYSTALLINE SILICA/QUARTZ MAY ALSO
LEAD TO A DISABLING INJURY KNOWN AS SILICOSIS. TH ESE EFTS ARE ASSOC W/BRTHG
EXCESS AMTS OF SILICA DUST. APPLICATION OF THI S PROD IS NOT EXPECTED TO
GENERATE EXCESS AMTS OF RESP SILICA/QUARTZ. INGEST OF PRODS CONTAINING
ETHYLENE GLYCOL MAY DMG KIDNE YS & LIVER & HAS BEEN (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE-QUARTZ: IARC MONOGRAPHS,
SUPPLEMENT, VOLUME 68, 1997: GROUP 1. NTP 8TH ANNUAL REPORT ON CARCINOGENS,
1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN. HUMAN: LUNG.
Signs And Symptions Of Overexposure: HLTH HAZS: SHOWN TO CAUSE BIRTH DEFECTS IN
LAB ANIMALS. NO EVIDENCE OF THESE EFTS HAS BEEN FOUND IN HUMANS. THIS PROD
CONTAINS TALC. IN A LIFETIME INHAL STUDY FEMALE RATS EXPOSED TO ELEVATED RESP
CONC (9 TIMES PEL) OF COSMETIC GRADE TALC DEVELOPED LUNG CANCER. TO DATE, NO
U.S. REGULATORY AGENCY HAS CLASSIFIED TALC AS CARCIN BASED ON THIS DATA. THIS
PROD CONTAINS ALKYL PHOSPHATE THAT HAS CAUSED BLA DDER TUMORS/CELL
ENLARGEMENT, LIVER TUMORS, INCRD LIVER WT FOLLOWING LONG-TERM ORAL ADMIN IN
ANIMALS. SIGNS & SYMPS OF OVEREXP: REDNESS, ITCH, BURNING SENSATION,
& VISUAL DISTURBS MAY INDICATE EXCESS EYE CONT. (SUP DAT)
First Aid: INGEST: IF SWALLOWED, DO NOT INDUCE VOMIT. GENTLY WIPE OUT INSIDE
MOUTH TO REMOVE ANY RESIDUAL MATL. EYES: REMOVE CONT LENSES & FLUSH EYES
IMMED W/GENTLE STREAM OF LUKE WARM WATER FOR AT LEAST 15 MINS . SKIN: FLUSH
IMMED W/PLENTY OF WATER FOR AT LEAST 15 MINS FOLLOWED BY WASHING W/SOAP &
WATER. INHAL: IF AFFECTED BY INHAL OF VAP/SPARY MIST, REMOVE TO FRESH AIR.
APPLY ARTF RESP & OTHER SUPPORT MEASU RES AS REQUIRED. OTHER: IF INGEST,
ANY TYPE OF OVEREXP/SYMPS OF OVEREXP OCCUR DURING/FOLLOWING USE OF THIS PROD,
CONT POISON CONTROL CENTER, EMERGENCY ROOM/MD IMMED; HAVE MSDS INFO
AVAILABLE.
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Handling and Disposal
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Spill Release Procedures: PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED
WITH PROPER NIOSH APPROVED RESPIRATORY, SKIN, & EYE PROTECTION SHOULD BE
PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP SPILLED MAT
ERIAL WITH SAND, VERMICULITE, OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL
& PLACE IN CLEAN, EMPTY CONTAINERS FOR DISPOSAL. ONLY THE SPILLED
MATERIAL & THE ABSORBENT SHOULD BE PLACED IN THIS CONTAINER.
Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE, PROVINCIAL, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WA STE
MANAGEMENT FACILITY.
Handling And Storage Precautions: PROTECT FROM FREEZING.
Other Precautions: IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT SYSTEM,
READ THE MATERIAL SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT OR COMPONENTS
BEFORE BLENDING, AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS
PARTS.
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: =110.C, 230.F
Lower Limits: 9.5%
Upper Limits: NOT AVAIL
Extinguishing Media: USE NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY
CHEMICAL OR UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA
CLASS IIIB COMBUSTIBLE LIQUID FIRES.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY MAY BE USED TO
COOL CLOSED CONTAINERS THAT ARE EXPOSED TO EXTREME HEAT. IF WATER IS USED,
FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE OR BURST (DUE TO
THE BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
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Control Measures
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Respiratory Protection: WHERE VENT IS INADEQUATE, USE NIOSH APPROVED AIR
PURIFYING RESPIRATOR W/APPROPRIATE CHEMICAL CARTRIDGES/POSITIVE-PRESSURE,
AIR-SUPPLIED RESPIRATOR. READ RESPIRATOR MANUFACTURER'S INSTRUCTIONS &
LITERA TURE CAREFULLY TO DETERMINE TYPE OF AIRBORNE CONTAMINANTS AGAINST
WHICH RESPIRATOR IS EFFECTIVE, ITS LIMITATIONS, & HOW IT IS TO BE
PROPERLY FITTED & USED.
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP
CONC OF INGS BELOW LOWEST SUGGESTED EXPOS LIMS, LEL BELOW STATED LIM, &
TO REMOVE DECOMP (SUP DAT)
Protective Gloves: NEOPRENE RUBBER, NITRILE RUBBER, OR LATEX GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). WEAR PROTECTIVE CLOTHING.
Work Hygienic Practices: CLEAN CONTAM CLTHG & SHOES. NO SPECIFIC
PERMEATION/DEGRADATION TESTING HAVE BEEN DONE ON PROT CLTHG FOR PROD. RECS
FOR SKIN PROT ARE BASED ON INFREQUENT CONT W/PROD. FOR FREQUENT CONT/TOTAL
(SUP DAT)
Supplemental Safety and Health: EFTS OF OVEREXP: DRYNESS, ITCH, CRACKING,
BURNING, REDNESS, & SWELL ARE CNDTNS ASSOC W/EXCESS SKIN CONT. VENT:
PRODS DURING WELDING/FLAME CUTTING. HYGIENE PRACTS: CONT MFR OF PROT CLTHG
FOR APPROP CHE M IMPERVIOUS EQUIP. PHYSICAL/CHEM PROPERTIES: WT/GALLON: 8.65
LBS (U.S.); % SOLIDS BY WT: 52.30.
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Physical/Chemical Properties
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Boiling Point: >37.8C, 100.F
B.P. Text: 100F - 527F
Vapor Pres: 17.2 MMHG
Vapor Density: HVR/AIR
Spec Gravity: 1.038
Evaporation Rate & Reference: 49 (BUTYL ACETATE=100)
Solubility in Water: 67.8%
Appearance and Odor: VISCOUS LIQ W/ODOR CHARACTERISTIC OF CHEM FAMILY & ANY
OTHER SOLVS LISTED.
Percent Volatiles by Volume: 52.470
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THIS PRODUCT IS NORMALLY STABLE AND WILL NOT
UNDERGO HAZARDOUS REACTIONS.
Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS,
OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRODUCE THE FOLLOWING HAZARDOUS
DECOMPOSITION PRODUCTS WHEN EXPOSED TO EXTREME HEAT: CARBON MONOXIDE, CARBON
DIOXIDE. EXTREME HEAT INCLUDES, BUT IS NOT LIMITED TO, FLAME CUTTING,
BRAZING, & WELDING.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: SEE HEALTH HAZARDS SECTIONS.
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Regulatory Information
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Sara Title III Information: SARA 102 RQ (LBS): ETHYLENE GLYCOL=8000 LBS. SARA
302 TPQ (LBS): NOT ESTABLISHED.
SARA 313: ETHYLENE GLYCOL. SARA 311/312 CATEGORIES FOR THIS PRODUCT: ACUTE=Y
(ETHYLENE GLYCOL), CHRONIC=Y (ETHYLENE GL YCOL, QUARTZ), FLAMMABILITY=N,
PRESSURE=N, REACTIVITY=N.
Federal Regulatory Information: THIS MATERIAL SAFETY DATA SHEET HAS BEEN
PREPARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200), THE SUPPLIER NOTIFICATION REQUIREMENTS OF SARA TITLE III, SECTION
313, A ND OTHER APPLICABLE RIGHT-TO-KNOW REGULATIONS. ALL CHEMICAL SUBSTANCES
IN THIS PRODUCT ARE LISTED ON THE U.S. TSCA INVENTORY OR ARE OTHERWISE EXEMPT
FROM TSCA INVENTORY REPORTING REQUIREMENTS.
State Regulatory Information: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
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Other Information
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Other Information: PPG SAFETY AND HEALTH IN-PLANT INDEX SYSTEM (SHIS):
HEALTH=3*, FLAMMABILITY=1, REACTIVITY=0. ACUTE HAZARD RATING SYSTEM:
0=MINIMAL, 1=SLIGHT, 2=MODERATE, 3=SERIOUS, 4=SEVERE. CHRONIC HAZARD RATING
SYS TEM: 3* OR 4*. SHIS RATINGS ARE ASSIGNED TO IDENTIFY THE RELATIVE
MAGNITUDE OF POTENTIAL HAZARDS. SAFE HANDLING OF THIS PRODUCT REQUIRES THAT
ALL OF THE INFORMATION ON THE MSDS BE EVALUATED FOR SPECIF IC WORK
ENVIRONMENTS.
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HAZCOM Label
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MSDS NAME: DURABLE YELLOW COLORANT, 96-7
Assigned IND: Y
Company: PPG INDUSTRIES, INC.
Street: 4325 ROSANNA DR
PO Box: 9
City: ALLISON PARK PA
Zipcode: 15101
Health Emergency Phone: 304-843-1300
Label Required IND: Y
Date Of Label Review: 06/09/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INGEST:HARMFUL IF SWALLOWED. EYES: CAUSES IRRIT.
SKIN: MAY CAUSE SLIGHT IRRIT. INHAL: VAP &/OR SPRAY MIST MAY BE HARMFUL
IF INHALED. SIGNS AND SYMPTOMS OF OVEREXPOS: EYE: REDNESS, ITCH, BURNING
SENSATION, & VISUAL DISTURBS. INGEST: SKIN: DRYNESS, ITCH, CRACKING,
BURNING, REDNESS, & SWELL. CHRONIC: CANCER HAZARD. CONTAINS SILICA,
CRYSTALLINE-QUARTZ WHICH IS LISTED AS A HUMAN LUNG CARCINOGEN (FP N).
POSSIBLE SILICOSIS. POSSIBLE LIVER AND KIDNEY DAMAGE. POSSIBLE BIRTH
DEFECTS. POSSIBLE BLADDERTUMORS/CELL ENLARGEMENT, LIVER TUMORS, INCREASED
LIVER WEIGHT.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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