ITW DEVCON CORP, -- TITANIUM PUTTY RESIN, DE036
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Material Safety Data Sheet
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MSDS Num: CJLSB
MSDS NAME: TITANIUM PUTTY RESIN, DE036
Responsible Party
Name: ITW DEVCON CORP,
Address: 30 ENDICOTT ST
City: DANVERS MA 01923
Info Phone: 508-777-1100
Emergency Phone Number: (800)424-9300
Resp. Party Other MSDS No.: 0619, PART NO. 0113
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DEVCON CORP
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3753
Phone: 1-508-777-1100
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Ingredients
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Cas: 25068-38-6
RTECS #: CE6880000
Name: BISPHENOL A-EPICHLOROHYDRIN RESIN
% low Wt: 25.
% high Wt: 50.
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Health Hazards Data
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LD50 LC50 Mixture: LD50: (ORAL,RAT): 30 G/KG
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: SKIN: MODERATE IRRITANT. CONTACT AT ELEVATED
TEMPERATURES CAN CAUSE THERMAL BURNS. MAY CAUSE SKIN SENSITIZATION (RASHES,
HIVES). EYES: MODERATE IRRITANT. CONTACT AT ELEVATED TEMPERATURES CAN CA USE
THERMAL BURNS. INHAL: THE LOW VAPOR PRESSURE OF RESIN MAKES INHAL UNLIKELY IN
NORMAL USE. INGEST: ACUTE ORAL TOXICITY IS LOW. MAY CAUSE GASTRIC DISTRESS.
CHRONIC: RPLNGD/RPTD SKIN CONTACT MAY CAUS E SENSITIZATION, WITH ITCHING,
SWELLING, OR RASHES ON LATER EXPOSURE. OTHER CHRONIC EFTS: 2-YEAR BIOASSAYS
IN MICE EXPOSED BY DERMAL ROUTE TO EPON 828, DGEBPA OR OTHER COMMERCIAL
RESINS YIELDED (EFTS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: EFTS OF OVEREXP: LIMITED EVIDENCE OF WEAK
CARCINOGENICITY. THE AUTHORS CONCLUDED THAT THE RENAL TUMOR EVIDENCE WITH
EPON 828 "WAS OF NO BIOLOGICAL SIGNIFICANCE: AND THAT THE RESIN "IS NOT A
SYSTEMIC C ARCINOGEN WHEN APPLIED TO THE DORSAL SKIN OF CF1 MICE."
Medical Cond Aggravated By Exposure: PREEXISTING EYE AND SKIN DISORDERS.
DEVELOPMENT OF PREEXISTING SKIN OR LUNG ALLERGY SYMPTOMS MAY INCREASE.
First Aid: EYES: FLUSH W/CLEAN WATER FOR AT LST 15 MINS WHILE GENTLY HOLDING
EYELIDS OPEN. GET IMMED MED ATTN. SKIN: IMMED REMOVE CONTAMD CLTHG &
EXCESS CONTAMINANT. FLUSH W/WATER. WASH THORO W/SOAP & WARM WATER .
CONSULT PHYS IF IRRIT DEVELOPS. INHAL: REMOVE TO FRESH AIR. ADMIN OXYG IF
BRTHG IS DFCLT. GET MED ATTN IF SYMS PERSIST. INGEST: DO NOT INDUCE VOMIT.
GIVE 2 GLASSES OF WATER TO DILUTE IF PATIENT IS C ONSCIOUS. GET MED ATTN. NOT
TO PHYS: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY IN HIGH VISCOSITY, LOW
VOLATILITY PRODUCTS, E.G., NEAT EPOXY RESINS.
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Handling and Disposal
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Spill Release Procedures: AVOID PERSONAL CONT. ELIM IGNIT SOURCES. VENTILATE
AREA. DIKE, CNTN & ABSORB W/CLAY, SAND OR OTHER SUITABLE MATL. FOR LG
SPILLS, PUMP TO STOR/SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB SUCH AS CLAY,
SA ND/OTHER SUITABLE MATL & DISPOSE OF PROPERLY. FLUSH AREA W/WATER TO
REMOVE TRACE RESIDUE. PVNT SPILL FROM ENTERING DRAINAGE/SEWER SYSTEMS,
WATERWAYS, AND SURFACE WATER.
Neutralizing Agent: NOT RELEVANT.
Waste Disposal Methods: IF THIS RESIN BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: AVOID CONTACT W/SKIN, EYES/CLOTHING. WASH
THOROUGHLY W/SOAP & WATER AFTER USING & PARTICULARLY BEFORE EATING,
DRINKING, SMKNG, APPLYING COSMETICS/USING TOILET FACILITIES. LAUNDER CONTAMD
CLTHG & PROT GEAR BEFORE REUSE. DISCARD CONTAMD LEATHER ARTICLES.
Other Precautions: HNDL MIXED RESIN & HARDENER I/A/W POTNTL HAZARD OF
CURING AGENT USED. PROVIDE APPROP VENT/NIOSH APPRVD RESP PROT AGAINST DECOMP
PRODS (SEE STABILITY & REACTIVITY SECTION) DURING WELDING/FLAME CUTTING
OPERATIONS & TO PROTECT AGAINST NUISANCE DUST DURING SANDING/GRIND OF
CURED PROD. (SUPDAT)
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: >204.4C, 400.F
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, AND FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). MATERIAL WILL NOT BURN UNLESS PREHEATED. COOL FIRE EXPOSED
CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard: HEATING >300F IN PRESENCE OF AIR MAY CAUSE
SLOW OXIDATIVE DECOMP & >500 F MAY CAUSE POLYMERIZATION. WHEN HEATED
TO DECOMP IT EMITS FUMES OF CL-, CARBON MONOXIDE, OTHER FUMES & VAPORS
VARYING IN COMPOS ITION AND TOXICITY.
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Control Measures
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Respiratory Protection: NONE REQUIRED AT NORMAL HNDLING TEMPERATURES AND
CONDITIONS. USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGES FOR UNCURED RESIN AND
NIOSH APPROVED DUST/PARTICLE RESPIRATORS DURING GRINDING/SANDING OPERATIO NS
OF CURED RESIN AS EXPOSURE LEVELS DICTATE.
Ventilation: LOCAL EXHST VENT IS PREFERRED ALTHOUGH GOOD GEN MECH VENT IS
USUALLY ADEQ FOR MOST INDUST APPLICATIONS. LOCAL EXHST IS REC FOR CONFINED
AREAS.
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPRVD CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). OTHER GEAR AS REQUIRED TO PREVENT SKIN CONTACT.
Work Hygienic Practices: WASH THOROUGHLY WITH SOAP & WATER AFTER USING &
PARTICULARLY BEFORE EATING, DRINKING, SMOKING, APPLYING COSMETICS, OR USING
TOILET FACILITIES.
Supplemental Safety and Health: OTHER PREC: STORE IN A COOL, DRY AREA AWAY FROM
HIGH TEMPERATURES AND FLAMES. CNDTNS TO AVOID (POLYMER): GENERATING
UNIDENTIFIED FUMES AND VAPORS WHICH MAY BE TOXIC.
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Physical/Chemical Properties
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Boiling Point: >260.C, 500.F
Vapor Pres: 0.03 MM HG AT 171F
Vapor Density: >1(AIR=1)
Spec Gravity: 1.1-1.3
PH: SEE OTHER INFO
Solubility in Water: NEGLIGIBLE
Appearance and Odor: VISCOUS LIQUID WITH LITTLE ODOR.
Percent Volatiles by Volume: 0
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: OPEN FLAME AND EXTREME HEAT.
Materials To Avoid: STRONG LEWIS OR MINERAL ACIDS, STRONG OXIDIZING AGENTS,
STRONG MINERAL AND ORGANIC BASES (ESPECIALLY PRIMARY AND SECONDARY ALIPHATIC
AMINES).
Hazardous Decomposition Products: OXIDES OF CARBON; ALDEHYDES, ACIDS AND OTHER
ORGANIC SUBSTANCES MAY BE FORMED DURNG COMBUSTION OR ELEVATED TEMPERATURE
(>500 DEG F) DEGRADATION.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: HEAT IS GENERATE WHEN RESIN IS MIXED
W/CURING AGENTS; RUN-A-WAY CURE RXNS MAY CHAR & DECOMPOSE RESIN, (SUPDAT)
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Toxicological Information
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Toxicological Information: BOTH RESIN & DIGLYCIDYL ETHER OF BISPHENOL (A
COMPONENT OF THIS PROD) HAVE PROVED TO BE INACTIVE WHEN TESTED BY IN VIVO
MUTAGENICITY ASSAYS. BOTH HAVE SHOWN ACTIVITY BY IN VITRO MICROBIAL
MUTAGENICITY SCREENING AND HAVE PRODUCED CHROMOSOMAL ABERRATIONS IN CULTURED
RAT LIVER CELLS. ORAL LD50 (MOUSE) = 15.6 G/KG
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Other Information: PH: NEUTRAL (5% SOLUTION OR SLURRY IN WATER. VOC
(GRAMS/LITER): 0
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HAZCOM Label
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MSDS NAME: TITANIUM PUTTY RESIN, DE036
Company: DEVCON CORP
Street: 30 ENDICOTT ST
City: DANVERS MA
Zipcode: 01923-3753
Health Emergency Phone: (800)424-9300
Label Required IND: Y
Date Of Label Review: 09/09/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: HAZ POLYMERIZATION MAY OCCUR. ACUTE: SKIN: MODERATE
IRRITANT. CONTACT AT ELEVATED TEMPERATURES CAN CAUSE THERMAL BURNS. MAY CAUSE
SKIN SENSITIZATION (RASHES, HIVES). EYES: MODERATE IRRITANT. CONTACT A T
ELEVATED TEMPERATURES CAN CAUSE THERMAL BURNS. INHAL: THE LOW VAPORPRESSURE
OF RESIN MAKES INHAL UNLIKELY IN NORMAL USE. INGEST: ACUTE ORAL TOXICITY IS
LOW. MAY CAUSE GASTRIC DISTRESS. CHRONIC: RPLN GD/RPTD SKIN CONTACT MAY CAUSE
SENSITIZATION, WITH ITCHING, SWELLING, OR RASHES ON LATER EXPOSURE. POSSIBLE
CARCINOGEN.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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