ITW DEVCON CORP, -- TITANIUM PUTTY HARDENER, 10770
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Material Safety Data Sheet
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MSDS Num: CJLRH
MSDS NAME: TITANIUM PUTTY HARDENER, 10770
Responsible Party
Name: ITW DEVCON CORP,
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3753
Info Phone: 508-777-1100
Emergency Phone Number: (800)424-9300
Resp. Party Other MSDS No.: 0619, PART NO. 0214
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DEVCON CORP
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3753
Phone: 1-508-777-1100
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Ingredients
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Cas: 32610-77-8
Name: FORMALDEHYDE POLYMER WITH PHENOL AND TETA
% low Wt: 30.
% high Wt: 50.
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Cas: 931-36-2
Name: 2-ETHYL-4-METHYLIMIDAZOLE
% low Wt: 5.
% high Wt: 10.
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Cas: 112-24-3
RTECS #: YE6650000
Name: TRIETHYLENETETRAMINE
% low Wt: 1.
% high Wt: 10.
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Cas: 108-95-2
RTECS #: SJ3325000
Name: PHENOL
< Wt: 5.
Other REC Limits: 5 PPM CANADA (MFR)
OSHA PEL: 19 MG/M3;5 PPM
ACGIH TLV: 19 MG/M3;5 PPM
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC; (MAGNESIUM SILICATE HYDRATE)
% low Wt: 10.
% high Wt: 30.
Other REC Limits: NIOSH 2MG/M3 (MFR)
OSHA PEL: see Table Z-3
ACGIH TLV: 2 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 65997-17-3
Name: GLASS, OXIDE, CHEMICALS; (FIBROUS GLASS)
% low Wt: 5.
% high Wt: 20.
OSHA PEL: 5 MG/M3 (RESIN)
ACGIH TLV: 10 MG/M3
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Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE-QUARTZ; (CRYSTALLINE SILICA)
< Wt: 1.
Other REC Limits: OSHA 0.1 MG/M3 (MFR)
OSHA PEL: see Table Z-3
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Health Hazards Data
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LD50 LC50 Mixture: LD50: (ORAL,RAT) >2200 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: SKIN: SEV IRRITANT. POTNTL SENSITIZER. EYES: SEV
IRRITANT. INHAL: IRRIT OF NOSE & THROAT; NAUS & VOMIT IN SEV CASES.
INGEST: MAY CAUSE BLEEDING OF GI TRACT & VOMIT OF BLOOD. CHRONIC: RPTD
SKIN CONT CAN CAUSE SENSITIZ, W/ITCHING, RASHES/SWELL OF SKIN. TETA MAY
CAUSE RESP SENSITIZ & CHRONIC LUNG TOXICITY (COUGH, TIGHTNESS OF CHEST,
SHORTNESS OF BREATH). OTHER EFTS: RPTD AND/OR PRLNGD EXPOSURE TO LOW CONCS
OF VAP MAY CAUSE :SORE THROAT, EYE IRRIT, NAUS, FAINTNESS, HDCH, WHICH ARE
TRANSIENT. RPTD AND/OR PRLNGD EXPOSURES MAY RSLT IN: ADVERSE SKIN EFTS (SUCH
AS DEFAT, RASH, IRRIT OR CORR), AD VERSE EYE EFTS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA., CRYSTALLINE-QUARTZ: IARC MONOGRAPHS,
SUPPLEMENT. VOL68 , PG 41, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINOGENS,
1994: ANTICIPATED TO BE CARCINOGEN.
Signs And Symptions Of Overexposure: EFTS OF OVEREXP: (SUCH AS CONJ/CORNEAL
DMG). PHENOL IS HUMAN POISON BY INGESTION.
Medical Cond Aggravated By Exposure: ASTHMA. CHRONIC RESPIRATORY DISEASE (E.G.
BRONCHITIS, EMPHYSEMA). EYE DISEASE. SKIN DISORDERS AND ALLERGIES.
First Aid: EYES: IMMED FLUSH W/CLEAN WATER FOR AT LST 15 MINS WHILE GENTLY
HOLDING EYELIDS OPEN. GET MED HELP AS SOON AS POSSIBLE. SKIN: IMMED REMOVE
CONTAMD CLTHG & SHOES & WASH WELL W/SOAP & WATER. SEE MD IF I
RRIT DEVELOPS. INHAL: REMOVE TO FRESH AIR. GIVE OXYG/ARTF RESP IF NEEDED. SEE
MD IF SYMPTOMS PERSIST. INGEST: DO NOT INDUCE VOMIT. DILUTE W/LOTS OF
MILK/WATER & GET IMMEDIATE MEDICAL HELP.
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Handling and Disposal
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Spill Release Procedures: AVOID PERSONAL CONTACT. ELIM IGNIT SOURCES. VENTILATE
AREA. DIKE, CNTN & ABSORB W/CLAY, SAND OR OTHER SUITABLE MATL. FOR LG
SPILLS, PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB SUCH AS CL
AY, SAND, OR OTHER SUITABLE MATL & DISPOSE OF PROPERLY. FLUSH W/WATER TO
REMOVE TRACE RESIDUE. PVNT SPILL FROM ENTERING DRAINAGE/SEWER SYS, WATERWAYS,
& SURFACE WATERS.
Waste Disposal Methods: IF THIS MATERIAL BECOMES WASTE, IT WOULD NOT BE
HAZARDOUS WASTE BY RCRA CRITERIA (40CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: CONT W/SKIN, EYES/CLTHG. WASH THORO W/SOAP
& WATER AFTER USING & PARTICULARLY BEFORE EATING, DRINKING, SMOKING,
APPLYING COSMETICS/USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG & PROT
GEAR BEFORE REU SE. DISCARD CONTAMD LEATHER ARTICLES.
Other Precautions: HNDL MIXED RESIN & HARDENER I/A/W POTNTL HAZARD OF
CURING AGENT USED. PROVIDE APPROP VENT/NIOSH APPRVD RESP PROT AGAINST DECOMP
PRODS(SEE STABILITY & REACTIVITY SECTION) DURING WELDING/FLAME CUTTING O
PEATIONS & TO PROTECT AGAINST SILICA DUST DURING SANDING/GRINDING OF
CURED PRODUCT. (SUPDAT)
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: =136.1C, 277.F
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: TOXIC FUMES WILL BE RELEASED WHEN THIS MATL
BURNS OR IS THERMALLY DECOMPOSED. OXIDES OF CARBON, OXIDES OF NITROGEN,
AMMONIA AND UNIDENTIFIED ORGANIC COMBUSTION PRODUCTS.
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Control Measures
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Respiratory Protection: NONE REQUIRED IN NORMAL USE WITH GOOD VENTILATION; IN
POORLY VENTILATED AREAS, WEAR NIOSH-APPROVED ORGANIC VAPOR MASK.
Ventilation: LOC EXHST IS REC FOR CONFINED AREAS & FOR PRLNGD/RPTD USE OF
PROD. GEN MECH VENT IS ADEQUATE FOR NORMAL USE.
Protective Gloves: CHEMICAL RESISTANT RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: OTHER PROTECTIVE GEAR AS REQUIRED TO PREVENT SKIN
CONTACT. EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N).
Work Hygienic Practices: WASH THORO W/SOAP & WATER AFTER USING & PARTICULARLY
BEFORE EATING, DRINKING, SMKNG, APPLYING COSMETICS/USING TOILET FACILITIES.
Supplemental Safety and Health: OTHER PREC: STORE IN COOL, DRY AREA AWAY FROM
HIGH TEMPERATURES AND FLAMES. PH: (5% SOLUTION/SLURRY IN WATER): 9.5-10.0.
VOC (GRAMS/LITER): 0.
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Physical/Chemical Properties
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Boiling Point: >176.7C, 350.F
Vapor Pres: <1 AT 70 F
Spec Gravity: 1.78
PH: SUPDAT
Solubility in Water: APPRECIABLE
Appearance and Odor: OFF-WHITE PASTE WITH AMMONIACAL ODOR.
Percent Volatiles by Volume: 0
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXPOSURE TO OPEN FLAME OR EXTREME HEAT.
Materials To Avoid: STRONG OXIDIZING AGENTS, ACIDS, AND CHLORINATED ORGANIC
COMPOUNDS.
Hazardous Decomposition Products: OXIDES OF NITROGEN AND CARBON, AMMONIA.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: HEAT IS RELEASED WHEN MATL IS MIXED W/EPOXY
RESIN; BE CAREFUL WHEN MIXING A POUND OR MORE.
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Toxicological Information
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Toxicological Information: ACUTE DERMAL EFTS: MOD IRRIT TO SKIN OF RABBIT.
PHENOL RAPIDLY ABSORB THRU SKIN & CAN CAUSE DEATH. EYE IRRIT: SEV IRRIT
OF RABBIT. OTHER CHRONIC EFTS: GEN OBSERVED IN ANIMAL STUDIES THAT
ALIPHATIC AMINES CAN CAUSE CHANGES IN LUNGS & HEART. TETA FOUND TO PROD
LIVER & KIDNEY DAMAGE& BRAIN CONGESTION IN DERMALLY EXPOSED ANIMALS.
2-ETHYL-4-METHYLLMIDAZOLE:ORAL LD50 (RAT): 3400 MG/KG; DERMAL LD50 (RABBIT):
>2000 MG/KG; INHAL LC50 4HR,(RAT): >10 MG/L. TRIETHYLENETETRAMINE: ORAL
LD50(RAT): 2460 MG/KG; DERMAL LD50(RABBIT): 850 MG/KG. PHENOL: ORAL
LD50(RAT): 317 MG/KG; DERMAL LD50(RABBIT): 850 MG/ KG; INHAL LC50 4HR, (RAT):
316 MG/M3.
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Ecological Information
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Ecological: MOBILITY AND PERSISTENCE: PHENOL: BIODEGRADABILITY = 99.5% AT 7
DAYS.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: FOR PURPOSES OF SARA SECTION 312 HAZARDOUS
MATERIALS INVENTORY REPORTING, THE FOLLOWING HAZARD CLASSES APPLY TO THIS
MATERIAL: IMMEDIATE HEALTH HAZARD - DELAYED HEALTH HAZARD
Federal Regulatory Information: TSCA: ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. PHENOL: CERCLA RQ
(LBS): 1000.0.
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Other Information
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HAZCOM Label
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MSDS NAME: TITANIUM PUTTY HARDENER, 10770
Company: DEVCON CORP
Street: 30 ENDICOTT ST
City: DANVERS MA
Zipcode: 01923-3753
Health Emergency Phone: (800)424-9300
Label Required IND: Y
Date Of Label Review: 09/08/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: HAZ POLYMERIZATION MAY OCCUR. ACUTE: SKIN: SEV IRRIT.
EYES: SEV IRRIT. INHAL: IRRIT OF NOSE & THROAT; NAUS & VOMIT.
INGEST: BLEEDING OF GI TRACT & VOMIT OF BLOOD. CHRONIC: CANCER HAZ.
CONTAINS SILI CA, CRYSTALLINE QUARTZ WHICH IS LISTED AS A HUMAN LUNG
CARCINOGEN (FP N). CAN CAUSE SKIN SENSITIZ, W/ITCHING, RASHES/SWELLING. RESP
SENSITIZ & LUNG TOXICITY, RPTD/PRLNGD EXPOS TO LOW CONCS OF VAP MAY
CAUSE: SORE THROAT, EYE IRRIT, NAUS, FAINTNESS, HDCH, WHICH ARE TRANSIENT.
RPTD/PRLNGD EXPOS MAY RSLT IN ADVERSE SKIN EFTS (SUCH AS DEFAT, RASH,
IRRIT/CORR), ADVERSE EYE EFTS (SUCH AS CONJ/CORNEAL DAM ). PHENOL HUMAN
POISON.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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