PIERCE CHEMICAL COMPANY -- PHENYLISOTHIOCYANATE, 0026922
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Material Safety Data Sheet
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MSDS Num: CJSSY
MSDS NAME: PHENYLISOTHIOCYANATE, 0026922
Responsible Party
Name: PIERCE CHEMICAL COMPANY
Box: 117
City: ROCKFORD IL 61105
Info Phone: 815-968-0747
Emergency Phone Number: 800-424-9300
Resp. Party Other MSDS No.: 299
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: PIERCE CHEMICAL COMPANY
Box: 117
City: ROCKFORD IL 61105
Phone: 815-968-0747
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Item Description Information
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Ingredients
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Cas: 103-72-0
RTECS #: NX9275000
Name: PHENYLISOTHIOCYANATE
Percent by Wt: 100.
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Health Hazards Data
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LD50 LC50 Mixture: WEAR NIOSH
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EMERGENCY OVERVIEW: COMBUSTIBLE LIQUID AND VAPOR. CAUSES
SEVERE EYE AND SKIN BURNS. HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH
SKIN.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: THERE IS NO KNOWN EFFECT FROM CHRONIC
EXPOSURE TO THIS PRODUCT. REPEATED OR PROLONGED EXPOSURE IS NOT KNOWN TO
AGGRAVATE MEDICAL CONDITION.
First Aid: EYE: IMMED FLUSH W/POTABLE WATER FOR AT LST 15 MINS. SEEK ASSISTANCE
FROM MD (FP N). CHECK FOR & REMOVE ANY CONT LENSES. DO NOT USE EYE
OINTMENT. SKIN: IF CHEM GOT ONTO CLOTHED PORTION OF BODY, REMOVE CONTAMD
CLOTHES AS QUICKLY AS POSS, PROTECTING YOUR OWN HANDS & BODY. PLACE
VICTIM UNDER DELUGE SHOWER. IF CHEM TOUCHES VICTIM'S EXPOSED SKIN, SUCH AS
HANDS: GENTLY & THOROUGHLY WASH CONTAMD SKIN W/R UNNING WATER &
NON-ABRASIVE SOAP. BE PARTICULARLY CAREFUL TO CLEAN FOLDS, CREVICES, CREASES
& GROIN. IF IRRIT PERSISTS, SEEK MED ATTN. WASH CONTAMD CLTHG BEFORE
REUSING. (SUPDAT)
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Handling and Disposal
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Spill Release Procedures: SM SPILL & LEAK: ABSORB W/INERT MATL & PUT
SPILLED MATL IN APPROP WASTE DISP. LG SPILL & LEAK: COMBUST MATL. CORR
LIQ. POISONOUS LIQ. KEEP AWAY FROM HEAT. KEEP AWAY FROM SOURCES OF IGNIT.
STOP LEAK IF W/OUT CNTNR. ABSORB W/DRY EARTH, SAND/OTHER NON-COMBUST MATL.
DO NOT GET WATER INSIDE CNTNR. DO NOT TOUCH SPILLED MATL. USE WATER SPRAY
CURTAIN TO DIVERT VAP DRIFT. (SUPDAT)
Waste Disposal Methods: DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE, AND
LOCAL REGULATIONS (FP N).
Handling And Storage Precautions: KEEP CONTAINER DRY. KEEP IN A COOL PLACE.
GROUND ALL EQUIPMENT CONTAINING MATERIAL.
Other Precautions: CORROSIVE MATERIALS SHOULD BE STORED IN A SEPARATE SAFETY
STORAGE CABINET OR ROOM.
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Fire and Explosion Hazard Information
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Flash Point Method: OC
Flash Point: =87.C, 188.6F
Extinguishing Media: COMBUSTIBLE. SMALL FIRE: USE DRY CHEMICAL, CO*2, WATER
SPRAY OR FOAM. LARGE FIRE: USE WATER SPRAY, FOG OR FOAM. DO NOT USE WATER
JET.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EUQIPMENT
(FP N). FIRE HAZARDS IN PRESENCE OF VARIOUS SUBSTANCES: NO SPECIFIC
INFORMATION IS AVAILABLE IN MANUFACTURER'S DATABASE REGARDING FLAMMABILITY OF
PRODUCT IN PRESENCE OF VARIOUS MATERIALS. SPECIAL REMARKS ON FIRE/EXPLOSION
HAZARDS: NO ADDITIONAL REMARK.
Unusual Fire/Explosion Hazard: PRODS OF COMBUST: THESE PRODS ARE CARBON OXIDES
(CO, CO*2), NITROGEN OXIDES (NO, NO*2). RISKS OF EXPLO OF PROD IN PRESENCE OF
MECH IMPACT: NOT AVAIL. RISKS OF EXPLO OF PROD IN PRESENCE OF STATIC DISCH
ARGE: NOT AVAIL. NO SPECIFIC INFO IS AVAIL IN MFR DATABASE REGARDING PROD'S
RISKS OF EXPLO IN PRESENCE OF VARIOUS MATLS.
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Control Measures
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Respiratory Protection: USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N). IN CASE OF LG SPILL: NIOSH APPRVD VAPOR RESPIRATOR. A
NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED TO AVOI D
INHALATION OF THE PRODUCT.
Ventilation: PROVIDE EXHST VENT/OTHER ENGINEERING CTLS TO KEEP AIRBORNE CONC OF
VAPS BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). FULL
SUIT. SUGGESTED PROT CLTHG MIGHT NOT BE SUFFICIENT; CONSULT SPECIALIST BEFORE
HNDLG THIS PROD.
Supplemental Safety and Health: FIRST AID PROC: INHAL: ALLOW VICTIM TO REST IN
WELL VENTILATED AREA. SEEK IMMED MED ATTN. INGEST: DO NOT INDUCE VOMIT. HAVE
CONSCIOUS PERSON DRINK SEVERAL GLASSES OF WATER/MILK. SEEK IMMED MED ATTN. S
PILL RELEASE: USE WATER SPRAY TO REDUCE VAPS. PVNT ENTRY INTO SEWERS ,
BASEMENTS/CONFINED AREAS; DIKE IF (OTHER INFO)
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Physical/Chemical Properties
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Boiling Point: =221.C, 429.8F
Melt/Freeze Pt: =-21.C, -5.8F
Spec Gravity: 1.13 (WATER =1)
Appearance and Odor: LIQUID.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THE PRODUCT IS STABLE.
Materials To Avoid: NO SPECIFIC INFORMATION IS AVAILABLE IN OUR DATABASE
REGARDING THE REACTIVITY OF THIS MATERIAL IN PRESENCE OF VARIOUS OTHER
MATERIALS.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: TOX TO ANIMALS: ACUTE ORAL TOXICITY (LD50): 87 MG/KG
(MOUSE). ACUTE DERMAL TOX (LD50): 250 MG/KG (MOUSE). CHRONIC ON HUMANS:
SUBSTANCE IS TOXIC TO KIDNEYS, BLADDER. TOXICITY OF PROD TO REPRODUCTIVE SY
STEM: NOT AVAIL. OTHER TOXIC EFTS ON HUMANS: NO SPECIFIC INFO IS AVAIL IN
DATABASE REGARDING OTHER TOXIC EFTS OF THIS MATL FOR HUMANS. SPECIAL REMARKS
ON TOX TO ANIMALS: NO ADDNL REMARK. SPEC REMARKS ON CHRONIC EFTS ON HUMANS:
NO ADDNL REMARK. SPEC REMARKS ON OTHER TOXIC EFTS ON HUMANS: NO ADDL REMARK.
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Ecological Information
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Ecological: ECOTOXICITY: NOT AVAIL. BOD5 AND COD: NOT AVAIL. POSSIBLY HAZARDOUS
SHORT TERM DEGRADATON PRODS ARE NOT LIKELY. HOWEVER, LONG TERM DEGRADATION
PRODS MAY ARISE. TOX OF PRODS OF BIODEGRADATION: PRODS OF DEGRADATION ARE
LESS TOXIC THAN PRODUCT ITSELF. SPECIAL REMARKS ON PRODS OF BIODEGRADATION:
NO ADDITIONAL REMARK.
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MSDS Transport Information
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Transport Information: DOT CLASSIFICATION: DOT CLASS 6.1: POISONOUS MATERIAL.
TDG CLASSIFICATION: TDG CLASS 6.1: POISONOUS MATERIAL. ADR/RID
CLASSIFICATION: ADR CLASS 6.1: HIGHLY TOXIC SUBSTANCE W/FLASH POINT BELOW
21C(70F) AND BOILING POINT BELOW 200C(392F). ADR CLASS 8: CORROSIVE LIQUID.
HIGHLY CORROSIVE LIQUID. HIGHLY CORROSIVE. IMO/IMDG CLASSIFICATION: IMDG
CLASS 6.1: POISONOUS MATERIAL. ICAO/IATA CLASSIFICATION: IA TA CLASS 6.1:
POISONOUS MATERIAL.
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Regulatory Information
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Federal Regulatory Information: INTERNATIONAL REGS: W (CANADA): W CLASS B-3:
COMBUST LIQ W/FLASH POINT BETWEEN 37.8C(100F) AND 93.3C(200F). W CLASS D-1B:
MATERIAL CAUSING IMMED AND SERIOUS TOXIC EFTS (TOXIC). DSCL(EEC): R34-CAUSES
BURNS. R23/25-TOXIC BY INHALATION AND IF SWALLOWED. R42/43-MAY CAUSE
SENSITIZATION BY INHALATION AND SKIN CONTACT. INTERNATIONAL LISTS: NO
PRODUCTS WERE FOUND.
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Other Information
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Other Information: SUPDAT: NEEDED. ELIM ALL SOURCES OF IGNIT. CALL FOR
ASSISTANCE ON DISP. HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.): HEALTH-3,
FIRE HAZARD-2, REACTIVITY-0, PERSONAL PROTECTION-A, NATIONAL FIRE PROT ECTION
ASSOCIATION (U.S.A.): HEATH-2, REACTIVITY-0.
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HAZCOM Label
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MSDS NAME: PHENYLISOTHIOCYANATE, 0026922
Company: PIERCE CHEMICAL COMPANY
PO Box: 117
City: ROCKFORD IL
Zipcode: 61105
Health Emergency Phone: 800-424-9300
Label Required IND: Y
Date Of Label Review: 10/12/1999
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE LIQUID AND VAPOR. ACUTE: CAUSES SEVERE EYE
AND SKIN BURNS. HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH SKIN.
CHRONIC: NONE LISTED BY MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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