ITW DEVCON -- TITANIUM PUTTY HARDENER, 10760; 0214
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Material Safety Data Sheet
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MSDS Num: CJSLX
MSDS NAME: TITANIUM PUTTY HARDENER, 10760; 0214
Responsible Party
Name: ITW DEVCON
Address: 30 ENDICOTT ST
City: DANVERS MA 01923
Info Phone: 978-777-1100
Emergency Phone Number: 800-424-9300
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DEVCON CORP
Address: 30 ENDICOTT ST
City: DANVERS MA 01923-3753
Phone: 1-508-777-1100
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Item Description Information
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Item Name: SEALING COMPOUND
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Ingredients
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Cas: 108-95-2
RTECS #: SJ3325000
Name: PHENOL
< Wt: 10.
Other REC Limits: 5 PPM (CANADA)
OSHA PEL: 19 MG/M3;5 PPM
ACGIH TLV: 19 MG/M3;5 PPM
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 112-24-3
RTECS #: YE6650000
Name: TRIETHYLENETETRAMINE OTHER LIMITS: 1PPM (SKIN) (AIHA).
< Wt: 10.
Other REC Limits: 1 PPM (SKIN)(ALHA)
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Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE-QUARTZ
< Wt: 1.
Other REC Limits: 0.1 MG/M3 (CANADA)
OSHA PEL: 0.1 MG/M3
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 32610-77-8
Name: FORMALDEHYDE POLYMER WITH PHENOL AND TETA
% low Wt: 20.
% high Wt: 40.
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Cas: 931-36-2
Name: 2-ETHYL-4-METHYLIMIDAZOLE
< Wt: 10.
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Health Hazards Data
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LD50 LC50 Mixture: LD50: (ORAL,RAT) >2200 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: SKIN: SEVERE IRRITANT. POTENTIAL SENSITIZER. EYES:
SEVERE IRRITANT. INHAL: IRRITATION OF NOSE & THROAT; NAUSEA &
VOMITING IN SEVERE CASES. INGEST: INGESTION MAY CAUSE BLEEDING OF
GASTROINTESTIN AL TRACT & VOMITING OF BLOOD. CHRONIC: REPEATED SKIN CONT
CAN CAUSE SENSITIZATION, WITH ITCHING, RASHES, OR SWELLING OF SKIN. TETA MAY
CAUSE RESPIRATORY SENSITIZATION & CHRONIC LUNG TOXICITY (COUGH, T
IGHTNESS OF CHEST, SHORTNESS OF BREATH). OTHER EFTS: REPEATED AND/OR
PROLONGED EXPOSURE TO LOW CONCS OF VAPOR MAY CAUSE: SORE THROAT, EYE
IRRITATION, NAUSEA, FAINTNESS, HEADACHE, WHICH ARE TRANSIENT. (EFTS OF
OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE-QUARTZ: MONOGRAPHS, VOL 68,
PG 41, 1997: NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998: REASONABLY
ANTICIPATED TO BE HUMAN CARCINOGEN.
Signs And Symptions Of Overexposure: HLTH HAZS: REPEATED AND/OR PROLONGED
EXPOSURES MAY RESULT IN: ADVERSE SKIN EFFECTS (SUCH AS DEFATTING, RASH,
IRRITATION OR CORROSION), ADVERSE EYE EFFECTS (SUCH AS CONJUNCTIVITIS OR
CORNEAL DAMAGE). P HENOL IS A HUMAN POISON BY INGESTION.
Medical Cond Aggravated By Exposure: ASTHMA. CHRONIC RESPIRATORY DISEASE (E.G.
BRONCHITIS, EMPHYSEMA). EYE DISEASE. SKIN DISORDERS AND ALLERGIES.
First Aid: EYES: IMMEDIATELY FLUSH W/CLEAN WATER FOR AT LST 15 MINS WHILE
GENTLY HOLDING EYELIDS OPEN. GET MED HELP AS SOON AS POSSIBLE. SKIN:
IMMEDIATELY REMOVE CONTAMD CLOTHING & SHOES & WASH WELL W/SOAP &
WAR M WATER. SEE DOCTOR IF IRRITATION DEVELOPES. INHAL: REMOVE PATIENT TO
FRESH AIR. GIVE OXYGEN OR ARTF RESP IF NEEDED. SEE DOCTOR IF SYMPTOMS
PERSIST. INGEST: DO NOT INDUCE VOMITING. DILUTE WITH LOTS OF MILK OR WATER
AND GET IMMEDIATE MEDICAL HELP.
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Handling and Disposal
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Spill Release Procedures: SPILL CTL: AVOID PERSONAL CONT. ELIM IGNIT SOURCES.
VENTILATE AREA. CONTAINMENT: DIKE, CNTN & ABSORB W/CLAY, SAND/OTHER
SUITABLE MATL. CLEANUP: LG SPILLS, PUMP TO STOR/SALV VESSELS. SOAK UP RESIDUE
W/ ABSORB SUCH AS CLAY, SAND/OTHER SUITABLEMATL & DISPOSE OF PROPERLY.
FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE. SPEC PROC: PVNT SPILL FROM
ENTERING DRAINAGE/SEWER SYSTEMS, WATERWAYS, & SURF WATERS.
Waste Disposal Methods: IF THIS MATERIAL BECOMES A WASTE, IT WOULD NOT BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40CFR261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN COOL, DRY AREA AWAY FROM HIGH TEMPS
& FLAMES. AVOID CONT W/SKIN, EYES/CLTHG. WASH THOROUGHLY W/SOAP &
WATER AFTER USING & PARTICULARLY BEFORE EATING, DRINKING, SMKNG, APPLYING
COSMETICS/USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG & PROT GEAR
BEFORE REUSE.
Other Precautions: DISCARD CONTAMD LEATHER ARTICLES. HNDL MIXED RESIN &
HARDENER I/A/W POTNTL HAZ OF CURING AGENT USED. PROVIDE APPROP VENT/NIOSH
APPRVD RESP PROT AGAINST DECOMP PRODS (SEE STABILITY & REACTIVITY SECTION
) DURING WELDING/FLAME CUTTING OPERATIONS & TO PROTECT AGAINST SILICA
DUST DURING SANDING/GRINDING O F CURED PROD.
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: =136.1C, 277.F
Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR NIOSH APPRVD SELF-CONTAINED
BREATHING APPARATUS & SUFFICIENT PROTECTIVE CLOTHING TO PREVENT EYE AND
SKIN CONTACT.
Unusual Fire/Explosion Hazard: TOXIC FUMES WILL BE RELEASED WHEN THIS MATL
BURNS/IS THERMALLY DECOMPOSED. HAZ PRODS OF COMBUST: OXIDES OF CARBON, OXIDES
OF NITROGEN, AMMONIA & UNIDENTIFIED ORGANIC COMBUSTION PRODUCTS.
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Control Measures
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Respiratory Protection: NONE REQD IN NORMAL USE W/GOOD VENT; IN POORLY
VENTILATED AREAS, WEAR NIOSH-APPROVED ORGANIC VAPOR MASK.
Ventilation: LOC EXHST IS REC FOR CONFINED AREAS & FOR PRLNGD USE OF PROD.
GEN MECH VENT IS ADEQ FOR NORMAL USE.
Protective Gloves: CHEMICAL RESISTANT RUBBER GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
OTHER PROTECTIVE GEAR AS REQURIED TO PREVENT SKIN CONTACT.
Work Hygienic Practices: WASH THOROUGHLY W/SOAP & WATER AFTER USING &
PARTICULARLY BEFORE EATING, DRINKING, SMKNG, APPLYING COSMETICS/USING TOILET
FACILITIES.
Supplemental Safety and Health: VOC(G/L): 0. PH: (5% SOLN OF SLURRY IN H*2O):
9.5-10.0. %SOLIDS BY WT:100. TOXIC INFO: TOX INFO ON HAZ CHEM CONSTITUENTS OF
THIS PROD. PHENOL-ORAL LD50(RAT) 317 MG/KG, DERMAL LD50(RABBIT) 850 MG/KG, I
NHAL LC50 4HR,(RAT) 316 MG/M3.TRIETHYLENETETRAMINE-ORAL LD50(RAT) 2460 MG/KG,
DERMAL LD50(RABBIT) 805 MG/KG.(OTHER INFO)
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Physical/Chemical Properties
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Boiling Point: >176.7C, 350.F
M.P/F.P Text: LIQUID
Vapor Pres: <1 AT 70F
Spec Gravity: 1.78
PH: SUPDAT
Solubility in Water: APPRECIABLE
Appearance and Odor: OFF-WHITE PASTE WITH AMMONIACAL ODOR.
Percent Volatiles by Volume: 0
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXPOSURE TO OPEN FLAME OR EXTREME HAZARD.
Materials To Avoid: STRONG OXIDIZING AGENTS, ACIDS, AND CHLORINATED ORGANIC
COMPOUNDS.
Hazardous Decomposition Products: OXIDES OF NITROGEN AND CARBON; AMMONIA.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: HEAT IS RELEASED WHEN THIS MATL IS MIXED
W/EPOXY RESIN; BE CAREFUL WHEN MIXING POUND/MORE.
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Toxicological Information
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Toxicological Information: ACUTE ORAL EFTS: LD50(RAT): >2200 MG/KG. ACUTE
DERMAL EFTS: LD50(RABBIT): NOT AVAIL. A MOD IRRITANT TO SKIN OF RABBIT.
PHENOL IS RAPIDLY ABSORBED THROUGH SKIN & CAN CAUSE DEATH. ACUTE INHAL
EFTS: LC50 (RAT): NOT AVAIL. EYE IRRIT: SEV IRRITANT TO EYE OF RABBIT.
SUBCHRONIC EFTS: NO DATA. CARCINOGENICITY, TERATOGENICITY, &
MUTAGENICITY: NO DATA. OTHER CHRONIC EFTS: IT HAS BEEN GENERALLY OBSERVED IN
AN IMAL STUDIES THAT ALIPHATIC AMINES CAN CAUSE CHANGES IN LUNGS & HEART.
TETA HAS BEEN FOUND TO PRDCE LIVER & KIDNEY DMG & BRAIN CONGESTION IN
DERMALLY EXPOSED ANIMALS. (SUPDAT)
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Ecological Information
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Ecological: ECOTOXICITY: NO DATA. MOBILITY AND PERSISTENCE: PHENOL:
BIODEGRADABILITY = 99.5% AT 7 DAYS. ENVIRONMENTAL FATE: NO DATA.
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MSDS Transport Information
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Transport Information: PROPER SHIPPING NAME: NON-REGULATED. TECHNICAL NAME:
N/A. HAZARD CLASS: N/A. UN NUMBER: N/A. PACKING GROUP: N/A. EMERGENCY
RESPONSE GUIDE NO.: N/A. IMDG PAGE NUMBER: N/A. OTHER: N/A.
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Regulatory Information
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Sara Title III Information: CONSULT APPROP REGS FOR EMER PLANNING & RELEASE
RPTG REQUIREMENTS FOR SUBSTANCES ON SARA 302 EXTREMELY HAZ SUBSTANCE LIST.
SUBSTANCES FOR WHICH "TOXIC CHEM" COLUMN IS MARKED "YES" ARE ON SARA SECTION
313 LIST OF TOX CHEMS, FOR WHICH RELEASE RPTG MAY BE REQUIRED: PHENOL: YES.
FOR SPECIFIC REQUIEMENTS CONSULT APPROP REGS. FOR PURPOSES OF SARA SECTION
312 HAZ MATLS INVENTORY RPTG, FOLLOWING HAZARD CLASSES APPLY TO THIS MATL:
IMMED HLTH HAZ--DELAYED HLTH HAZ.
Federal Regulatory Information: U.S. FED REGS. TSCA - ALL INGREDS OF THIS PROD
ARE LISTED/ARE EXEMPT FROM LISTING, ON TSCA INVENTORY. THE FOLLOWING RCRA
CODE(S) APPLIES TO THIS MATL IF IT BECOMES WASTE: NONE. REGULATORY STATUS OF
HA Z CHEM CONSTITUENTS OF PROD: PHENOL - EXTREMELY HAZ* - YES, TOXIC CHEM** -
YES, CERCLA RQ(LBS) - 1000.0, TSCA 12B EXPORT NOTIFICATION - NOT REQUIRED.
CANADIAN REGS-W HAZ CLASS(ES): D2B; D2A. ALL COMPONENTS OF THIS PROD ARE ON
DOMESTIC SUBSTANCES LIST. REATINGS: HEALTH-3, FLAMMABILITY-1, R EACTIVITY-
1.
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Other Information
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Other Information: THE FOLLOWING INFORMATION APPLIES TO THE HARDENER COMPONENT
OF THE TWO-PART KIT FOR METAL REBUILD AND REPAIR COMPOUNDS. WHEN PROPERLY
MIXED AND CURED, THE PRODUCT IS NOT HAZARDOUS. SUPDAT: 2-ETHYL-4
-METHYLIMIDAZOLE - ORAL LD50(RAT) 3400MG/KG, DERMAL LD50(RABBIT) >2000
MG/KG, INHAL LC50 4HR,(RAT) >10 MG/L.
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Transportation Information
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Trans ID NO: 150559
MSDS NAME: TITANIUM PUTTY HARDENER, 10760; 0214
MSDS Prepared Date: 12/04/1998
Review Date: 12/06/1999
Multiple KIT Number: 0
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: TITANIUM PUTTY HARDENER, 10760; 0214
Company: DEVCON CORP
Street: 30 ENDICOTT ST
City: DANVERS MA
Zipcode: 01923-3753
Health Emergency Phone: 800-424-9300
Label Required IND: Y
Date Of Label Review: 11/08/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SKIN & EYES: SEV IRRIT. INHAL: IRRIT OF NOSE
& THROAT; NAUS & VOMITING IN SEV CASES. INGEST: MAY CAUSE BLEEDING OF
GI TRACT & VOMIT OF BLOOD. CHRONIC: CANCER HAZ. CONTAINS SILICA,
CRYSTALLINE-Q UARTZ WHICH IS LISTED AS A HUMAN LUNG CARCIN (FP N). RPTD SKIN
CONT CAN CAUSE SENSITIZ, WITH ITCHING, RASHES/SWELLING. TETA MAY CAUSE RESP
SENSITIZ & CHRONIC LUNG TOXICITY (COUGH, TIGHTNESS OF CHEST, SHORT
BREATH). OTHER EFTS: RPTD/PRLNGD EXPOS MAY CAUSE: SORE THROAT, EYE
IRRITATION, NAUSEA, FAINTNESS, HEADACHE, WHICH ARE TRANSIENT; ADVERSE SKIN
EFTS (DEFATING, RASH, IRRIT, CORR); ADVERSE EYE EFT S (CONJ, CORNEAL DMG).
PHENOL IS HUMAN POISON.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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