DUPONT POWDER COATINGS USA INC -- ASA-70 GRAY, PFH502S8055
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CJXXQ
MSDS NAME: ASA-70 GRAY, PFH502S8055
Responsible Party
Name: DUPONT POWDER COATINGS USA INC
Address: 9800 GENARD RD
City: HOUSTON TX 77041-7624
Info Phone: 713-939-4000
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: DUPONT POWDER COATINGS USA INC
Address: 9800 GENARD RD
City: HOUSTON TX 77041-7624
Phone: 713-939-4000
=======================================================
Item Description Information
=======================================================
=======================================================
Ingredients
=======================================================
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM DIOXIDE
% low Wt: 10.
% high Wt: 30.
Other REC Limits: N/K (FP N)
OSHA PEL: 15 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 10 MG/M3
ACGIH STEL: N/K (FP N)
------------------------------
Cas: 1317-65-3
RTECS #: EV9580000
Name: LIMESTONE; (CALCIUM CARBONATE)
% low Wt: 7.
% high Wt: 13.
Other REC Limits: N/K (FP N)
OSHA PEL: 15 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 10 MG/M3
ACGIH STEL: N/K (FP N)
------------------------------
Cas: 2451-62-9
RTECS #: XZ1994900
Name: 1,3,5-TRIGLYCIDYL ISOCYANURATE
% low Wt: 1.
% high Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.05 MG/M3
ACGIH STEL: N/K (FP N)
------------------------------
Cas: 112926-00-8
RTECS #: VV7315000
Name: AMORPHOUS SYNTHETIC SILICA GEL; (SILICA, AMORPHOUS)
% low Wt: .5
% high Wt: 1.5
Other REC Limits: N/K (FP N)
OSHA PEL: see Table Z-3
OSHA STEL: N/K (FP N)
ACGIH TLV: 10 MG/M3
ACGIH STEL: N/K (FP N)
------------------------------
Name: NUISANCE DUST
Percent by Wt: 100.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: 10 MG/M3
ACGIH STEL: N/K (FP N)
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE TOXICOLOGICAL INFORMATION.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: THESE ACUTE & CHRONIC HLTH EFT STATEMENTS ADDRESS
EXPOS TO PURE CHEMS ONLY. IN A COATING POWDER THESE COMPONENTS ARE MIXED W/IN
COATING & DIRECT EXPOS TO THEM IS NOT LIKELY. ACUTE: CALCIUM CARBONATE:
IRRITATING TO EYES & SKIN. 1,3,5-TRIGLYCIDYL ISOCYANURATE: INGEST: MOD
TOX. SYMPS ARE NOT FULLY KNOWN, MAY INCLUDE LOSS OF APPETITE & NOSE
BLEEDING. INHAL: IRRITATING TO UPPER RESP TRACT. MAY CAUSE NO SEBLEEDS. EYES:
IRRITATING. SKIN: IRRITATING. CAN BE ABSORBED THRU SKIN IN HARMFUL AMTS. EFTS
SIMILAR TO INGEST. TITANIUM DIOXIDE: INGEST: LOW ORAL TOXICITY. NO TOX EFTS
DUE TO INGEST ARE DESCRIBED IN LITERATURE. (EFTS OF OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZ: INHAL: IRRITATING TO UPPER RESP
TRACT. EYES: IRRITATING. SILICA, AMORPHOUS: CONT W/DUST MAY INCLUDE EYE IRRIT
(DISCOMFORT, TEARING/BLURRING OF VISION)/SLIGHT SKIN IRRIT (DISCOMFORT/RASH).
OV EREXP TO DUST BY INHAL MAY CAUSE TEMPORARY LUNG IRRIT (COUGH,
DISCOMFORT/DFCLTY IN BRTHG). CHRONIC: 1,3,5-TRIGLYCIDYL ISOCYANURATE: IRRIT
OF EYES, SKIN & RESP TRACT; LOSS OF APPETITE, MAY CAUSE NOSEBL EEDS; TOX
BY INHAL & IF ABSORBED THRU SKIN. PRLNG/RPTD CONT MAY CAUSE SKIN SENSIT.
ANIMAL STUDIES SHOW THAT OVEREXP CAN RSLT IN TOX EFTS TO TESTES, POSS EFTS ON
LIVER & LUNGS, & POSS ADVERSE MALE REPR O EFTS. (SUP DAT)
Medical Cond Aggravated By Exposure: 1,3,5-TRIGLYCIDYL ISOCYANURATE: RESP
ILLNESS & DERM MAY BE AGGRAVATED BY EXCESS EXPOS. SILICA, AMORPHOUS:
PREEXISTING LUNG DISEASES MAY INCR SUSCEPTIBILITY TO EFTS OF EXCESS AMORPHOUS
SILICA DUST EXPOS.
First Aid: EYES: FLUSH WITH COOL WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY
LIFTING LIDS TO ENSURE THOROUGH RINSING. SEEK MEDICAL ASSISTANCE. SKIN: WASH
THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM A REA TO FRESH AIR.
INGESTION: DRINK 1 OR 2 GLASSES OF WATER AND INDUCE VOMITING BY PLACING
FINGER AT BACK OF THROAT. SEEK MEDICAL ASSISTANCE.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SWEEP UP CAREFULLY OR USE EXPLOSION-PROOF VACUUM
CLEANER, THEN DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Waste Disposal Methods: MANAGE OR DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
Handling And Storage Precautions: KEEP ALL EQUIPMENT CLEAN AND PROPERLY
GROUNDED TO AVOID STATIC ELECTRICITY DISCHARGE. KEEP WORK AREAS FREE OF DUST.
AVOID EXCESSIVE SKIN CONTACT. DO NOT INGEST OR INHALE. KEEP OUT OF THE REACH
OF CHIL DREN. KEEP CONTAINERS SEALED AND AVOID STATIC ELECTRICITY DISCHARGES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: FOAM, CO*2, DRY CHEMICAL, WATER FOG, DRY SAND.
Fire Fighting Procedures: WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: MEC >/= 26 G/M3 (SEE OTHER INFORMATION
SECTION). MEC = MINIMUM EXPLOSIVE CONCENTRATION.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE A PROPERLY FITTED NIOSH APPROVED MECHANICAL
RESPIRATOR OR MASK TO AVOID BREATHING DUST. CAREFULLY FOLLOW RESPIRATOR
MANUFACTURER'S INSTRUCTIONS FOR USE.
Ventilation: PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO KEEP AIR
CONTAMINATION CONCENTRATION BELOW APPLICABLE OSHA PEL OR ACGIH'S TLV TWA
LIMIT.
Protective Gloves: RECOMMENDED TO AVOID SKIN CONTACT. WEAR IMPERVIOUS GLOVES
(FP N).
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). PROTECTIVE OVERALLS RECOMMENDED.
Work Hygienic Practices: REMOVE AND WASH SOILED CLOTHING.
Supplemental Safety and Health: EFTS OF OVEREXP: TITANIUM DIOXIDE: LAB STUDIES
SHOW THAT INHALATION EXPOSURE TO HIGH LEVELS (250 MG/KG) OF TITANIUM DIOXIDE
CAUSES CANCEROUS TUMORS IN RATS. THIS RESPONSE OCCURS AT LOWER EXPOSURE LEVE
LS & MAY BE DUE TO HIGH LEVELS OVERWHELMING NORMAL LUNG CLEARANCE
MECHANISMS. (OTHER INFO)
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.52985
=======================================================
Reactivity Data
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Stability Indicator: YES
Hazardous Decomposition Products: FUMES MAY CONTAIN CO, CO*2, NO*2 OR OTHER
NITROGEN COMPOUNDS.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
Toxicological Information: TITANIUM DIOXIDE: LD50 (ORA, RAT): 9500.00 PPM.
CALCIUM CARBONATE: LD50 (ORAL, RAT): 6450.00 PPM. 1,3,5-TRIGLYCIDYL
ISOCYANURATE: LD50 (ORAL, RAT): 440.00 PPM.
=======================================================
Ecological Information
=======================================================
Ecological: NONE KNOWN.
=======================================================
MSDS Transport Information
=======================================================
Transport Information: NOT REGULATED.
=======================================================
Regulatory Information
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Federal Regulatory Information: ALL INGREDIENTS IN THIS PRODUCT ARE LISTED IN
THE TSCA INVENTORY. WEIGHT LOSS IS LESS THAN ONE PERCENT WHEN USING US EPA
FEDERAL REFERENCE METHOD 24 (ASTM D2369). THIS WEIGHT LOSS IS MOSTLY WATER
(AST M D4107) WITH A TRACE AMOUNT OF ORGANIC MATERIAL. THIS TRACE AMOUNT
SHOULD BE CONSIDERED VOLATILE ORGANIC COMPOUND (VOC) CONTENT.
=======================================================
Other Information
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Other Information: RATING: HEALTH = 1*; FIRE = 1; REACTIVITY = 0; PPE = E. NFPA
704 RATING: HEALTH = 1; FIRE = 1; REACTIVITY = 0. RATING DEFINITIONS: HEALTH:
1-SLIGHT HAZARD, IRRITATION POSSIBLE; HEALTH: *-LONG TER M HEALTH EFFECTS MAY
RESULT FROM REPEATED OVEREXPOSURE; FIRE: 1-SLIGHT HAZARD, NEEDS CONSIDERABLE
PREHEAT BEFORE COMBUSTION WILL OCCUR; REACTIVITY: 0-MINIMAL HAZARD, MATERIALS
ARE NORMALLY STABLE; PPE : E-SAFETY GLASSES, GLOVES, DUST RESPIRATOR. -- SUP
DAT: THE RELEVANCE OF THIS DATA TO HUMANS IS NOT SIGNIFICANT WHERE THE TLV IS
OBSERVED.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: ASA-70 GRAY, PFH502S8055
Company: DUPONT POWDER COATINGS USA INC
Street: 9800 GENARD RD
City: HOUSTON TX
Zipcode: 77041-7624
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 12/28/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: MAY BE IRRITATING TO EYES AND SKIN. MODERATELY
TOXIC BY INGESTION W/LOSS OF APPETITE, NOSE BLEEDING. INHAL: IRRITATING TO
UPPER RESP TRACT. MAY CAUSE NOSE BLEEDS. EYES: IRRITATING. SKIN:
IRRITATING. MAY BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. CHRONIC:
POSSIBLE SKIN SENSITIZATION. POSSIBLE TOXIC EFFECTS TO TESTES, MALE
REPRODUCTIVE SYSTEM, LIVER AND LUNGS. POSSIBLE CANCERO US TUMORS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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