HENTZEN COATINGS INC -- RED OXIDE HIGH SOLIDS UNIVERSAL PRIMER, 02040
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CJXSW
MSDS NAME: RED OXIDE HIGH SOLIDS UNIVERSAL PRIMER, 02040RIP-1
Responsible Party
Name: HENTZEN COATINGS INC
Address: 6937 WEST MILL ROAD
Box: 18749
City: MILWAUKEE WI 53218
Info Phone: 414-353-4200
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Preparer's Name: JANE FREEMAN
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: HENTZEN COATINGS INC
Address: 6937 WEST MILL ROAD
Box: 18749
City: MILWAUKEE WI 53218
Phone: 414-353-4200
=======================================================
Item Description Information
=======================================================
=======================================================
Ingredients
=======================================================
Cas: 7727-43-7
RTECS #: CR0600000
Name: BARIUM SULFATE
% low Wt: 15.
% high Wt: 20.
Other REC Limits: N/K (FP N)
OSHA PEL: 15 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 10 MG/M3
ACGIH STEL: N/K (FP N)
------------------------------
Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC
% low Wt: 1.
% high Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: see Table Z-3
OSHA STEL: N/K (FP N)
ACGIH TLV: 2 MG/M3
ACGIH STEL: N/K (FP N)
------------------------------
Cas: 142-82-5
RTECS #: MI7700000
Name: HEPTANE
% low Wt: 1.
% high Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: 2000 MG/M3;500 PPM
OSHA STEL: 500 PPM
ACGIH TLV: 1640 MG/M3;400 PPM
ACGIH STEL: 2050 MG/M3;500 PPM
------------------------------
Cas: 7440-48-4
RTECS #: GF8750000
Name: COBALT; (COBALT COMPOUNDS)
Percent by Wt: .1
Other REC Limits: N/K (FP N)
OSHA PEL: 0.1 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.02 MG/M3
ACGIH STEL: N/K (FP N)
-----------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE
Percent by Wt: 2.4
Other REC Limits: SKIN NOTATION
OSHA PEL: see Table Z-2
OSHA STEL: N/K (FP N)
ACGIH TLV: 188 MG/M3;50 PPM
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE
Percent by Wt: 13.42
Other REC Limits: N/K (FP N)
OSHA PEL: 100 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 651 MG/M3;150 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 64742-95-6
RTECS #: WF3400000
Name: LIGHT AROMATIC SOLVENT NAPHTHA (PETROLEUM); (AROMATIC HYDROCARBONS
(MIXTURE OF C8'S TO C10'S))
% low Wt: 1.
% high Wt: 5.
Other REC Limits: 100 PPM (MFR'S LIM)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
------------------------------
Cas: 1309-37-1
RTECS #: NO7400000
Name: IRON OXIDE
% low Wt: 10.
% high Wt: 15.
Other REC Limits: N/K (FP N)
OSHA PEL: 10 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 5 MG/M3;2 PPM
ACGIH STEL: N/K (FP N)
------------------------------
Cas: 100-41-4
RTECS #: DA0700000
Name: ETHYLBENZENE; (ETHYL BENZENE)
Percent by Wt: 2.37
Other REC Limits: N/K (FP N)
OSHA PEL: 435 MG/M3;100 PPM
OSHA STEL: 125 PPM
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 543 MG/M3;125 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: EYES: CAN CAUSE IRRITATION. SKIN: CAN CAUSE
IRRITATION. MAY CAUSE DEFATTING OF THE SKIN. PROLONGED OR REPEATED SKIN
CONTACT MAY CAUSE DERMATITIS. INHALATION: ANESTHETIC. CAN CAUSE IRRITATION OF
RESPIRATORY TRACT OR ACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY THE
FOLLOWING PROGRESSIVE STEPS IF SEVERE OVEREXPOSURE IS CONTINUED: HEADACHE,
DIZZINESS, STAGGERING GAIT, CONFUSION OR UNCONSCIO USNESS. INGESTION: IF
SWALLOWED, CONSULT A PHYSICIAN IMMEDIATELY. CHRONIC: REPORTS HAVE ASSOCIATED
REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE, (EFFECTS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: THIS PRODUCT HAS NOT BEEN TESTED AS A WHOLE FOR
CARCINOGENICITY. THE COBALT COMPOUND IN THIS PRODUCT HAS NOT BEEN
SPECIFICALLY IDENTIFIED AS CAUSING CANCER IN HUMANS OR ANIMALS. HOWEVER, IARC
HAS LIST ED "COBALT AND COBALT COMPOUNDS" AS POSSIBLY CARCINOGENIC (GROUP 2B)
BASED UPON LABORATORY ANIMAL STUDIES.
Signs And Symptions Of Overexposure: HEALTH HAZARDS: LIVER AND KIDNEY DAMAGE.
THERE ARE REPORTS THAT LONG-TERM REPEATED EXPOSURE TO XYLENE MAY RESULT IN
SOME LOSS OF HEARING. THERE ARE REPORTS THAT LONG-TERM REPEATED EXPOSURE TO
TOLUENE MAY RESULT IN SOME LOSS OF HEARING. TOLUENE APPEARS ON THE NAVY
OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. SEEK CONSULTATION FROM
APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST I NFORMATION
AND SAFE HANDLING AND EXPOSURE INFORMATION (FP N).
Medical Cond Aggravated By Exposure: ASTHMA AND OTHER RESPIRATORY AILMENTS.
CHEMICAL SENSITIZATION.
First Aid: EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES WHILE LIFTING EYELIDS. TAKE TO PHYSICIAN FOR MEDICAL TREATMENT. SKIN:
WASH AFFECTED AREA WITH SOAP AND WATER. REMOVE CONTAMI NATED CLOTHING AND
WASH BEFORE REUSE. CONSULT A PHYSICIAN IF IRRITATION DEVELOPS OR PERSISTS.
INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET.
NOTIFY A PHYSICIAN. INGESTION: I F SWALLOWED, CALL A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVACUATE ALL NON-ESSENTIAL PERSONNEL & REMOVE ALL
SOURCES OF IGNITION (FLAMES, HOT SURFACES, ELECTRICAL, STATIC &
FRICTIONAL SPARKS). VENTILATE AREA. EQUIP CLEAN-UP CREW W/APPROP PROT EQUIP.
AVOID BRE ATHING VAPORS. AVOID SKIN CONTACT. PREVENT ENTRY INTO DRAINS,
SEWERS & WATERWAYS. NOTIFY APPROPRIATE AUTHORITIES IF NECESSARY. CONTAIN
& REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS.
Waste Disposal Methods: RECYCLE, FUEL BLEND/INCINERATE. DISPOSE OF I/A/W APPLIC
LAWS & REGS. IT IS THE RESPONSIBILITY OF THE OWNER OF WASTE TO DISPOSE OF
IT PROPERLY. LAB ANALYSIS IS REC TO PROFILE WASTE FOR PROPER DISP DETE
RMINATION. U.S. E.P.A. WASTE # & DESCRIPTION: D001, WASTE PAINT. HAZ
WASTE CHARACTERISTICS: IGNITABL E. DISPOSE OF I/A/W LOC, STATE, & FED
REGS (FP N).
Handling And Storage Precautions: USE ONLY W/ADEQ VENT. AVOID PRLNG BRTHG OF
VAPS. WEAR APPROP, PROPERLY FITTED RESP (NIOSH APPRVD) DURING & AFTER
APPLICATION UNLESS AIR MONITORING DEMONSTRATES THAT VAP/MIST LEVELS ARE BELOW
APPLIC EX POS LIMS. FOLLOW RESP MFR'S DIRECTIONS FOR USE. CAN CAUSE IRRIT TO
EYES, SKIN, NOSE & THROAT.
Other Precautions: AVOID CONT W/EYES & CLTHG. AVOID PRLNG/RPTD CONT W/SKIN.
USE GROUNDING & BONDING CONNECTION WHEN TRANSFERRING MATL TO PVNT STATIC
DISCHARGE, FIRE/EXPLO. AVOID FREE FALL OF LIQ IN EXCESS OF A FEW INCHE S. USE
SPK-PROOF TOOLS & EXPLO-PROOF EQUIP. DO NOT STORE >120F OR <32F.
STORE LGE QTYS IN BLDGS DESI GNED TO (SUP DAT)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point: =-6.5C, 20.F
Lower Limits: 1.00%
Upper Limits: 67.00%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN
FLAMES. CLSD CONTR MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. WATER SPRAY MAY
BE IN EFFECTIVE. WATER MAY BE USED TO COOL CLSD CONTRS TO PVNT PRESS
BUILD-UP/POSS AUTOIGNIT/EXPLO WHEN EXPOSED (OTHER INFO)
=======================================================
Control Measures
=======================================================
Respiratory Protection: WHEN SPRAY APPLIED & WHEN USED IN LIMITED VENT
AREAS, WEAR NIOSH APPRVD ORG VAP/PARTICULATE RESP DESIGNED TO REMOVE
COMBINATION OF PARTICULATE, GAS & VAP. WHEN USED IN CONFINED AREAS/POORLY
VENTILATED AREAS, USE NIOSH APPRVD AIR LINE RESP/HOOD. DURING
SANDING/GRINDING OPERATIONS, USE NIOSH APPRVD PARTICULATE RESP TO REMOVE
SOLID AIRBORNE (OTHER INFO)
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP
AIR CONTAMINANT CONC BELOW CURRENT APPLIC OSHA SFTY & HLTH REQS IN
MIXING, (ECOLOGICAL INFO)
Protective Gloves: CHEMICAL-RESISTANT GLOVES RECOMMENDED FOR PROLONGED OR
REPEATED CONTACT.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER
(FP N). EDUCATE AND TRAIN EMPLOYEES IN THE SAFE USE OF THIS PRODUCT. AN APRON
MAY BE APPROPRIATE TO PROTECT AGAINST SKIN CONTACT.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. IT IS GOOD INDUSTRIAL
HYGIENE PRACTICE TO MINIMIZE SKIN CONTACT. PREVENT PROLONGED SKIN CONTACT
WITH CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: OTHER PREC: COMPLY W/OSHA'S 29 CFR 1910.106.
KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. KEEP CONTRS CLOSED WHEN NOT IN
USE. KEEP CLOSURES TIGHT & UPRIGHT TO PREVENT LEAKAGE. EMPTIED CONTRS MAY
RETAIN H AZ RESIDUE. FOLLOW ALL HAZ PREC IN THIS MSDS UNTIL CONTR IS THORO
CLEANED/DESTROYED. (OTHER INFO)
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >92.8C, 199.F
B.P. Text: 199F TO 418F
Vapor Pres: 36.000
Vapor Density: 4.800
Spec Gravity: 1.5130
Evaporation Rate & Reference: 4.3000(N-BUTYL ACETATE=1)
Solubility in Water: NEGLIGIBLE
Appearance and Odor: OPAQUE LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume: 50.914
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: SEE HAZARDOUS DECOMPOSITION PRODUCTS.
Materials To Avoid: STRONG OXIDIZERS.
Hazardous Decomposition Products: MAY PRODUCE HAZARDOUS FUMES WHEN HEATED TO
DECOMPOSITION AS IN WELDING. FUMES MAY CONTAIN THE FOLLOWING: CARBON
MONOXIDE, CARBON DIOXIDE AND OTHER TOXIC VAPORS DEPENDING UPON THE
TEMPERATURE REACHED.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
Toxicological Information: SEE HEALTH HAZARDS SECTION. THIS PRODUCT CONTAINS
ONE OR MORE REPORTED CARCINOGENS OR SUSPECTED CARCINOGENS.
=======================================================
Ecological Information
=======================================================
Ecological: N/P. OTHER INFORMATION: AIR MONITORING OF THE WORKPLACE MAY BE
REQUIRED TO DETERMINE APPROPRIATE RESPIRATOR SELECTION. VENTILATION:
APPLICATION AND CURING AREAS, AND TO REMOVE DECOMPOSITION PRODUCTS D URING
WELDING AND FLAME CUTTING ON SURFACES COATED WITH THIS PRODUCT.
PHYSICAL/CHEMICAL PROPERTIES: VOC: 3.4930; VOC: 418.56 GRAMS/LITER; WEIGHT
PER GALLON: 12.59600 LB/GL; % NONEXEMPT SOLVENT BY WEIG HT: 27.733.
=======================================================
MSDS Transport Information
=======================================================
Transport Information: DOT PROPER SHIPPING NAME: PAINT. UN NUMBER: UN1263. DOT
HAZARD CLASS: 3. DOT LABEL: FLAMMABLE LIQUID. DOT PACKAGING GROUP: PG II.
U.S. POSTAL SERVICE: WILL NOT HANDLE.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372: COBALT
COM POUNDS, CAS # MIXTURE, 0.1010 PERCENT BY WEIGHT; TOLUENE, CAS # 108-88-3,
2.3960 PERCENT BY WEIGHT; XYLENE, CAS # 1330-20-7, 13.4250 PERCENT BY WEIGHT;
ETHYL BENZENE, CAS # 100-41-4, 2.3700 PERCENT BY WEIGHT.
=======================================================
Other Information
=======================================================
Other Information: PROD CLASS: POLYESTER. INFO: HLTH=2; FLAMM=3; REACTIVITY=0.
SUP DAT: TO AVOID SPONT COMBUST DURING TEMPORARY STOR, SOAK SOILED RAGS &
WASTE IMMED AFTER USE IN WATER-FILLED, CLSD CONTR. FIRE FIGHT PROC: TO
EXTREME HEAT. IF WATER IS USED, FOG NOZZ ARE PREF. DO NOT APPLY TO HOT
SURFACES. NEVER USE WELDING/CUTTING TORCH ON/NEAR PROD CONTR (EVEN EMPTY)
BECAUSE PROD (EVEN RESIDUE) CAN IGNITE EXPLOS IVELY. RESP PROT: PARTICLES OF
SANDING DUST. USE NIOSH APPRVD RESPS WHEN FLAME CUTTING, WELDING/BRAZING MATL
COATED W/THIS PROD. OBSERVE OSHA REGS FOR RESP USE (29 CFR 1910.134).
(ECOLOGICAL INFO)
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: RED OXIDE HIGH SOLIDS UNIVERSAL PRIMER, 02040RIP-1
Company: HENTZEN COATINGS INC
Street: 6937 WEST MILL ROAD
PO Box: 18749
City: MILWAUKEE WI
Zipcode: 53218
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 12/30/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: EYES: CAN CAUSE IRRITATION. SKIN: CAN
CAUSE IRRITATION. MAY CAUSE DEFATTING. INHALATION: ANESTHETIC. CAN CAUSE
IRRITATION OF RESPIRATORY TRACT OR ACUTE NERVOUS SYSTEM DEPRESSION CHA
RACTERIZED BY: HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION OR
UNCONSCIOUSNESS. INGESTION: IF SWALLOWED, CONSULT A PHYSICIAN IMMEDIATELY.
CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCC UPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE,
LIVER AND KIDNEY DAMAGE. SKIN: PROLONGED OR REPEATED CONTACT MAY CAUSE
DERMATITIS. TOLUENE: REPRODUCTIVE HAZARD (FP N ).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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