LUCAS-MILHAUPT INC -- SILVER-COPPER-PHOSPHORUS BRAZING ALLOYS, BRAZ
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Material Safety Data Sheet
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MSDS Num: CJXSR
MSDS NAME: SILVER-COPPER-PHOSPHORUS BRAZING ALLOYS, BRAZE 719 (32-719)
Responsible Party
Name: LUCAS-MILHAUPT INC
Address: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI 53110
Info Phone: 414-769-6000
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Address: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI 53110
Phone: 414-769-6000
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Item Description Information
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Ingredients
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Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER
% low Wt: 27.
% high Wt: 92.6
Other REC Limits: N/K (FP N)
OSHA PEL: 1 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 1 MG/M3
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7723-14-0
RTECS #: TH3495000
Name: PHOSPHORUS
% low Wt: .01
% high Wt: 7.25
Other REC Limits: N/K (FP N)
OSHA PEL: 0.1 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.1 MG/M3;0.02 PPM
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 7440-22-4
RTECS #: VW3500000
Name: SILVER
% low Wt: .9
% high Wt: 73.
Other REC Limits: N/K (FP N)
OSHA PEL: 0.01 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHAL: INHAL OF COMPONENTS OF THESE PRODS IS NOT
KNOWN TO PRESENT A SIGNIFICANT RISK TO HLTH WHEN USED ACCORDING TO
INSTRUCTIONS & W/APPROP PROT MEASURES. INHAL OF COMPONENT ELEMENTS HAS
BEEN R EPORTED TO CAUSE ONE/MORE OF THE FOLLOWING SYMPS & EFTS UPON
EXCESS HIGH/PRLNG EXPOS: COPPER: ACUTE EXPOS MAY CAUSE RESP TRACT IRRIT,
FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAK, & METALLIC TASTE. PHOSPHO RUS:
THE RED FORM OF PHOSPHORUS IS STABLE & RELATIVELY NON-TOX AT ROOM TEMP.
WHEN HEATED IN PRESENCE OF AIR, IT IS CONVERTED TO PHOSPHORUS PENTOXIDE,
WHICH IS CORR & IRRITATING TO EYES, NOSE, THROAT, & MUC MEMBS. (EFTS
OF OVEREXP)
Explanation Of Carcinogenicity: NONE OF THE COMPONENTS OF THESE PRODUCTS ARE
CLASSIFIED AS POTENTIAL OR DEMONSTRATED HUMAN CARCINOGENS BY IARC, NTP, OR
OSHA.
Signs And Symptions Of Overexposure: HLTH HAZ: SKIN: CONT W/THESE PRODS IN
FINELY-DIVIDED FORMS MAY CAUSE ARGYRIA, IRRIT, DISCOLORATION, &/OR CONT
DERM. EYES: CONT W/THESE PRODS IN FINELY-DIVIDED FORMS MAY CAUSE IRRIT,
ARGYRIA, CONJ, &/O R ULCERATION OF CORNEA. INGEST: INGEST OF THESE PRODS
IN FINELY-DIVIDED FORMS MAY CAUSE NAUS, VOMIT, & GI IRRIT. CHRONIC:
INHAL: COPPER: EXPOS MAY DMG LIVER, KIDNEY, SPLEEN, PANCREAS, & BRAIN.
SILVER: CHRONIC EXPOS MAY PRDCE ARGYRIA, A PERM BLUE-GRAY DISCOLORATION OF
SKIN, EYES, MUC MEMBS, & RESP TRACT. INGEST: LONG-TERM CHRONIC INGEST MAY
DMG LIVER, KIDNEYS, & GI SYS.
Medical Cond Aggravated By Exposure: PRE-EXISTING PULM DISEASES (BRONCH,
ASTHMA) MAY BE AGGRAVATED BY INHAL EXPOS, PARTICULARLY AS FUME. CHRONIC EXPOS
BY INHAL &/OR INGEST MAY AGGRAVATE PRE-EXISTING DISEASES OF LIVER,
KIDNEYS, & GI SYS.
First Aid: INHALATION: IF SIGNS AND SYMPTOMS OF TOXICITY ARE OBSERVED, REMOVE
SUBJECT FROM AREA, ADMINISTER OXYGEN, AND SEEK MEDICAL ATTENTION. KEEP THE
SUBJECT WARM AND AT REST. PERFORM ARTIFICIAL RESPIRATION I F BREATHING HAS
STOPPED. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREA WITH LARGE
QUANTITIES OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ASSISTANCE IF
NECESSARY. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL
ASSISTANCE IF NECESSARY. INGESTION: IF SUBJECT IS CONSCIOUS, INDUCE VOMITING.
IF UNCONSCIOUS OR CONVULSIVE, SEEK IMMEDIATE MEDICAL ASSISTANCE.
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Handling and Disposal
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Spill Release Procedures: IF A FINELY-DIVIDED FORM OF PRODUCT IS SPILLED, CLEAN
UP SPILLAGE SO AS TO MINIMIZE DISPERSION OF DUST. WET SWEEPING OR VACUUMING
USING HEPA FILTRATION ARE RECOMMENDED.
Waste Disposal Methods: CONSULT THE MANUFACTURER FOR DISPOSITION OF UNUSED OR
UNUSABLE PRODUCT. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS (FP N).
Handling And Storage Precautions: DO NOT STORE IN PROXIMITY TO INCOMPATIBLE
MATERIALS.
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Fire and Explosion Hazard Information
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Extinguishing Media: USE DRY CHEMICAL. DO NOT USE WATER.
Fire Fighting Procedures: WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: IN FINELY-DIVIDED FORM, THESE PRODUCTS MAY
IGNITE WHEN EXPOSED TO FLAME OR BY REACTION WITH INCOMPATIBLE MATERIALS. IF
PRESENT IN A FIRE OR EXPLOSION, THEY MAY EMIT FUMES OF THE CONSTITUENT METALS
OR METAL OXIDES AND PHOSPHORUS PENTOXIDE.
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Control Measures
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Respiratory Protection: IF EXPOSURE LEVEL EXCEEDS AN OSHA PEL/OTHER APPLICABLE
STANDARD, USE NIOSH-APPROVED RESPIRATOR HAVING CONFIGURATION (CLASS, TYPE OF
FACEPIECE, FILTER MEDIA, ASSIGNED PROTECTION FACTOR, ETC) APPROPRIAT E TO
CONCENTRATION OF CONTAMINANT(S) GENERATED. FOR GUIDANCE ON SELECTION &
USE OF RESPIRATORY PROTECTION, CONSULT ANSI Z88.2 (ANSI, NEW YORK, NY 10036
USA).
Ventilation: USE APPROP VENT (E.G., DILUTION, LOC EXHST) ADEQ TO MAINTAIN CONCS
OF ALL COMPONENTS & THEIR DECOMP BYPRODS TO W/IN THEIR RESPECTIVE OSHA
PEL/OTHER APPLIC STDS.
Protective Gloves: WEAR APPROPRIATE PROTECTIVE GLOVES. WEAR IMPERVIOUS GLOVES
(FP N).
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
WEAR APPROP PROT CLTHG TO PVNT SKIN INJURIES FROM HAZS OF BRAZING &/OR FOR
PRLNG/RPTD CONT W/FINELY-DIVIDED FORMS OF PROD. AVOID FLAMM FABRICS.
Work Hygienic Practices: TO MINIMIZE THE POSSIBILITY OF INGESTION, WASH HANDS
AND FACE BEFORE EATING, DRINKING, APPLYING COSMETICS, OR USING TOBACCO.
Supplemental Safety and Health: APPEARANCE/ODOR: TAPE, GRAIN, OR PREFORMED
SHAPES. MATERIALS TO AVOID: FERRIC CARBONYL, SELENINYL BROMIDE. CHEMICAL
FORMULA: ALLOYS OF SILVER, COPPER, AND PHOSPHORUS.
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Physical/Chemical Properties
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Melt/Freeze Pt: =643.3C, ######F
Spec Gravity: 7.86 - 8.44
Solubility in Water: INSOLUBLE
Appearance and Odor: ODORLESS LIGHT-COPPER METALS IN FORM OF WIRE, ROD, STRIP,
POWDER, (SUP DAT)
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Reactivity Data
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Stability Indicator: YES SULFIDE, (SUP DAT)
Stability Condition To Avoid: STABLE AT ROOM TEMPERATURE. SILVER AND COPPER CAN
FORM UNSTABLE ACETYLIDES UPON CONTACT WITH ACETYLENE GAS.
Materials To Avoid: AMMONIA, HNO*3, AZIDES, ETHANOL, ETHYLENE IMINE, MG,
CHLORATES, BROMATES & IODATES, INORG & ORG PEROXIDES, PEROXYFORMIC ACID,
NITROBENZENE, HALOGENS, PERMONOSULFONIC ACID, SEOCL, SEOF, SEF*4, HYDRAZINE
MONONITRATE, CARBON D
Hazardous Decomposition Products: HEATING TO ELEVATED TEMPERATURES MAY LIBERATE
METAL/METAL OXIDE FUME AND PHOSPHORUS PENTOXIDE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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MSDS Transport Information
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Transport Information: HAZARD CLASS: SHIPMENT NOT CONTROLLED BY USDOT/ICAO/IMO
REGULATIONS.
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Regulatory Information
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Sara Title III Information: HAZARD CLASSES: ACUTE HEALTH HAZARD, CHRONIC HEALTH
HAZARD. SECTION 313 SUPPLIER NOTIFICATION: THIS PRODUCT CONTAINS THE
FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION
313 OF THE EMERGENCY PLANNING & COMMUNITY RIGHT-TO-KNOW ACT (EPCRA) OF
1986 AND OF 40 CFR 372: COPPER, CAS # 7440-50-8, 27-92.6 PERCENT OF MIXTURE;
PHOSPHORUS, CAS # 7723-14-0, 0.01-7.25 PERCENT OF MIXTUR E; SILVER, CAS #
7440-22-4, 0.9-73 PERCENT OF MIXTURE. THIS INFORMATION MUST BE INCLUDED ON
ALL MSDS THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
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HAZCOM Label
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MSDS NAME: SILVER-COPPER-PHOSPHORUS BRAZING ALLOYS, BRAZE 719 (32-719)
Company: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Street: 5656 SOUTH PENNSYLVANIA AVENUE
City: CUDAHY WI
Zipcode: 53110
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 12/30/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHAL: INHAL OF COMPONENT ELEMENTS HAS BEEN
REPORTED TO CAUSE ONE/MORE OF THE FOLLOWING SYMPS & EFTS UPON EXCESS
HIGH/PRLNG EXPOS: RESP TRACT IRRIT, FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAK,
& M ETALLIC TASTE. IRRITATING TO EYES, NOSE, THROAT, & MUC MEMBS.
SKIN: MAY CAUSE ARGYRIA, IRRIT, DISCOLORATION &/OR CONTACT DERM. EYES:
MAY CAUSE IRRIT, ARGYRIA, CONJUCTIVITIS &/OR ULCERATION OF CORNEA.
INGEST: MAY CAUSE NAUS, VOMIT & GI IRRIT. CHRONIC: INHAL OVEREXP MAY
DAMAGE LIVER, KIDNEY, SPLEEN, PANCREAS & BRAIN. INGEST OVEREXP MAY DAMAGE
LIVER, KIDNEYS & GI SYSTEM.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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