J. W. HARRIS & HARRIS WELCO, D -- STAY-SILV WHITE BRAZING FLUX
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Material Safety Data Sheet
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MSDS Num: CJXSQ
MSDS NAME: STAY-SILV WHITE BRAZING FLUX
Responsible Party
Name: J. W. HARRIS CO INC & HARRIS WELCO, DIVISION/J.W. HARRIS CO
Address: 1051 YORK RD
City: KINGS MOUNTAIN NC 28086
Info Phone: 704-739-6421
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Resp. Party Other MSDS No.: 0134
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Published: Y
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Preparer Co. when other than Responsible Party Co.
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Assigned Ind: Y
Name: CHEMICAL SAFETY ASSOCIATES, INC
Address: 9163 CHESAPEAKE DRIVE
City: SAN DIEGO CA 92123-1002
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Contractor Summary
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Name: J. W. HARRIS CO INC & HARRIS WELCO, DIVISION/J.W. HARRIS CO
Address: 1051 YORK RD
City: KINGS MOUNTAIN NC 28086
Phone: 704-739-6421
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Item Description Information
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: SEE TOXICOLOGICAL INFORMATION.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: SYMPS OF INHAL OVEREXP MAY INCL COUGHING, SNEEZING,
& DFCLTY BRTHG. DEPENDING ON DURATION & CONC OF OVEREXP, SKIN CONT
CAN SEV IRRITATE SKIN, & EYE CONT CAN CAN IRRITATE EYES. SEV INGEST
OVEREX P MAY BE FATAL. CHRONIC: RPTD/PRLNG SKIN OVEREXP MAY RSLT IN DERM
(RED, DRY, ITCHY SKIN). CHRONIC OVEREXP TO HYDROGEN FLUORIDE (POSS DECOMP
PROD) CAN CAUSE FLUOROSIS (WEAKENING & DEGENERATION OF BONE STRUCTURE
& POSS HEART, NERVE, & INTESTINAL PROBLEMS). CHRONIC INGEST OVEREXP
MAY CAUSE MOTTLING OF TOOTH ENAMEL & HARDENING/ABNORM DENSITY OF BONES.
TARGET ORGANS: SKIN, EYES, RESP SYS.
Signs And Symptions Of Overexposure: HLTH HAZ: INHAL: MOD TO SEV IRRIT OF NOSE,
THROAT, & RESP SYS. MAY INCL COUGHING, SNEEZING, & DFCLTY BRTHG. SKIN
CONT: MOD TO SEV IRRIT. RPTD/PRLNG OVEREXP MAY RSLT IN DERM (RED, DRY, ITCHY
SKIN). EYE S: IRRIT. CAN CAUSE TEARING, REDNESS, &TISS DMG. SKIN
ABSORPTION: HYDROGEN FLUORIDE EXTREMELY CORR & POISON BY ALL RTES OF
ENTRY. CAN PENETRATE SKIN & PRDCE BURNS. HYDROGEN FLUORIDE EXPOS
INVOLVING 20 % OF BODY/MORE CAN BE FATAL THRU SYSTEMIC FLUORIDE POIS. INGEST:
MAY IRRITATE MOUTH, THROAT, & OTHER TISS OF DIGESTIVE SYS. INJECTION: MAY
CAUSE LOC REDDENING, TISS SWELL, & DISCOMFORT IN ADDN TO WOUN D. CONT
NEHC FOR MORE INFO (FP N).
Medical Cond Aggravated By Exposure: DERMATITIS, OTHER SKIN DISORDERS, AND
RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY OVEREXPOSURE TO THESE FLUXES.
First Aid: SKIN: DECONTAM W/RUNNING WATER FOR AT LEAST 15 MINS. DO NOT
INTERRUPT FLUSHING. IF NEC, APPLY CALCIUM GLUCONATE GEL (2.5% CONC) AFTER
FLUSHING. REMOVE EXPOSED/CONTAM CLTHG. DO NOT CONTAM EYES. SEEK ME D ATTN IF
ANY ADVERSE RXN OCCURS. EYES: OPEN EYES WHILE UNDER GENTLY RUNNING WATER. USE
SUFFICIENT FORCE TO OPEN EYELIDS. "ROLL" EYES. FLUSH FOR AT LEAST 15 MINS,
W/OUT INTERRUPTING. SEEK IMMED MED AT TN. INHAL: REMOVE TO FRESH AIR. UF NEC,
USE ARTF RESP TO SUPPORT VITAL FUNCS. SEEK MED ATTN IF ANY ADVERSE RXN
OCCURS. INGEST: CALL MD/POIS CTL CTR FOR MOST CURRENT INFO. IF PROFESSIONAL
ADVICE NOT AV AIL, DO NOT INDUCE VOMIT. (SUP DAT)
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Handling and Disposal
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Spill Release Procedures: UNCONTROLLED RELEASES SHOULD BE RESPONDED TO BY
TRAINED PERS USING PRE-PLANNED PROC. USE PROPER PROT EQUIP. CLEAR AFFECTED
AREA, PROT PEOPLE, & RESPOND W/TRAINED PERS. IN EVENT OF INCIDENTAL
RELEASE, PERS SHOULD WEAR GLOVES, SFTY GLASSES/GOGGS, & FSHLD DURING
CLEAN UP. IN EVENT OF NON-INCIDENTAL RELEASE, MIN PERS PROT EQUIP SHOULD BE
LABEL B. CONT NEHC FOR MORE COMPLETE INFO (FP N).
Waste Disposal Methods: WASTE DISPOSAL MUST BE I/A/W APPROPRIATE U.S. FEDERAL,
STATE, & LOCAL REGS OR W/REGULATIONS OF CANADA & ITS PROVINCES.
PRODUCT, IF UNALTERED BY USE, MAY BE DISPOSED OF BY TREATMENT AT PERMITTED
FACILI TY/AS ADVISED BY YOUR LOCAL HAZARDOUS WASTE REGULATORY AUTHORITY. U.S.
EPA WASTE NUMBER: N/A. DISPOS E OF I/A/W LOCAL, STATE, & FEDERAL REGS (FP
N).
Handling And Storage Precautions: ALL EMPLOYEES SHOULD BE TRAINED TO HANDLE
MATL SAFELY. EMPTY CONTRS MAY CONTAIN RESIDUAL MATL; HANDLE EMPTY CONTRS
W/CARE. STORE IN COOL, DRY LOCATION, AWAY FROM DIRECT SUNLIGHT, SOURCES OF
INTENSE HE AT. STORE AWAY FROM INCOMPATIBLES. STORE IN SECONDARY CONTRS/IN
DIKED AREA AS APPROP.
Other Precautions: STOR & USE AREAS SHOULD BE COVERED W/IMPERVIOUS MATLS.
KEEP CONTR TIGHTLY CLSD WHEN NOT IN USE. INSPECT ALL INCOMING CONTRS BEFORE
STOR TO ENSURE THEY ARE PROPERLY LABELED & NOT DAMAGED. DO NOT STORE IN
GLASS/PERMIT MATL TO BE STORED IN SILICATE-BASED MATL. CONT NEHC FOR MORE
COMPLETE INFO (FP N).
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Fire and Explosion Hazard Information
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Flash Point Text: NOT FLAMMABLE
Extinguishing Media: NOT FLAMMABLE. USE EXTINGUISHING MEDIA APPROPRIATE FOR
SURROUNDING FIRE. USE WATER SPRAY (FOR COOLING), HALON, DRY CHEMICAL, CARBON
DIOXIDE, FOAM, ANY "ABC" CLASS.
Fire Fighting Procedures: WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N). MOVE CONTAINERS FROM FIRE
AREA IF IT CAN BE DONE WITHOUT RISK TO PERSONNEL. IF POSSIBLE, PREVENT RUNOFF
WAT ER FROM ENTERING STORM DRAINS, BODIES OF WATER, OR OTHER
ENVIRONMENTALLY-SENSITIVE AREAS.
Unusual Fire/Explosion Hazard: THIS PROD CAN MODERATELY TO SEVERELY IRRITATE
CONTAMINATED SKIN, & PRESENTS A POTENTIAL CONT HAZ TO FIREFIGHTERS.
DURING A FIRE, IRRITATING & TOXIC GASES (E.G., HYDROGEN FLUORIDE,
POTASSIUM OXIDES, FL UORINE, & BORON COMPOUNDS) MAY BE GENERATED.
EXPLOSION SENSITIVITY TO MECHANICAL IMPACT/STATIC DISCHARGE: NOT SENSITIVE.
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Control Measures
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Respiratory Protection: MAINTAIN AIRBORNE CONTAMINANT CONCENTRATIONS BELOW
GUIDELINES LISTED IN INGREDIENTS SECTION IF APPLICABLE. IF RESPIRATORY
PROTECTION IS NEEDED, USE ONLY PROTECTION AUTHORIZED IN 29 CFR
1910.134/APPLIC ABLE STATE REGULATIONS. USE NIOSH APPROVED SUPPLIED AIR
RESPIRATION PROTECTION IF OXYGEN LEVELS ARE <19.5%/ARE UNKNOWN. CONT NEHC
FOR MORE COMPLETE INFO (FP N).
Ventilation: USE WITH ADEQUATE VENTILATION. EXHAUST DIRECTLY TO OUTSIDE, TAKING
NECESSARY PRECAUTIONS FOR ENVIRONMENTAL PROTECTION.
Protective Gloves: NATURAL RUBBER, NEOPRENE, OR NITRILE RUBBER FOR ROUTINE
INDUSTRIAL USE.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYEWASH & DELUGE SHOWER MTG ANSI DESIGN CRITERIA
(FP N). NO BODY PROTECTION NEEDED FOR NORMAL CIRCUMSTANCES OF USE. USE BODY
PROT APPROPRIATE FOR TASK (E.G., APRON, COVERALLS, CHEMICAL RESISTANT BOOTS).
Work Hygienic Practices: AVOID GETTING ON YOU/IN YOU. WASH THORO AFTER HNDLG.
DO NOT EAT, DRINK, SMOKE/APPLY COSMETICS WHILE HNDLG. AVOID BRTHG
PARTICULATES GENERATED BY PROD. REMOVE CONTAM CLTHG IMMED.
Supplemental Safety and Health: FIRST AID PROC: DRINK MILK, EGG WHITES/LGE QTYS
OF WATER. NEVER INDUCE VOMIT/GIVE FLUIDS IF UNCON, CONVULSING/UNABLE TO
SWALLOW. VICTIMS OF CHEM EXPOS MUST BE TAKEN FOR MED ATTN. RESCUERS SHOULD BE
TA KEN FOR MED ATTN IF NEC. TAKE COPY OF LABEL & MSDS TO HLTH
PROFESSIONAL W/VICTIM. (OTHER INFO)
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Physical/Chemical Properties
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Spec Gravity: 1.5 - 1.7 (H*2O=1)
Solubility in Water: MODERATELY SOLUBLE
Appearance and Odor: WHITE, ODORLESS PASTE.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXTREME TEMPERATURES, MOISTURE, INCOMPATIBLE
MATERIALS.
Materials To Avoid: STRONG OXIDIZERS, STRONG ACIDS, REACTIVE INTERHALOGENS. DUE
TO THE PRESENCE OF FLUORIDE COMPONENTS, AVOID CONTACT WITH SILICATE-BASED
MATERIALS.
Hazardous Decomposition Products: HYDROGEN FLUORIDE, FLUORINE, BORON AND
POTASSIUM COMPOUNDS.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: PRESENTED BELOW ARE HUMAN TOX FOR CONCS >1%.
OTHER DATA FOR ANIMALS ARE AVAIL FOR COMPONENTS. BORIC ACID: SKIN IRRIT
(HUMAN)=15 MG/3 DAYS/INTERMITTENT; MILD. LD (ORAL, HUMAN)=37 MG/KG/BORON AS
BORIC A CID. LD (SKIN, INFANT)=210 MG/KG/BORON AS BORIC ACID. TDLO (ORAL,
CHILD)=500 MG/KG; GI EFTS. LDLO (ORAL, MAN)=429 MG/KG; CARDIOVASCULAR
SYSTEMIC EFTS. LDLO (ORAL, WOMAN)=200 MG/KG. TDLO (ORAL, INFANT) =800 MG/KG/4
WKS/INTERMITTENT. LDLO (ORAL, INFANT)=934 MG/KG. LDLO (SKIN, INFANT)=1200
MG/KG. LDLO (SKIN, CHILD)=4000 MG/KG/4 DAYS. LDLO (SKIN, MAN)=2430 MG/KG.
LDLO (SKIN, CHILD)=1500 MG/KG. CONT NEH C FOR MORE COMPLETE INFO (FP N).
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Ecological Information
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Ecological: ALL WORK PRACTS MUST BE AIMED AT ELIM ENVIRON CONTAM. COMPONENTS OF
THESE FLUXES WILL SLOWLY DECOMPOSE UNDER NORM ENVIRON CNDTNS INTO VARIETY OF
INORG CMPDS. THESE FLUXES CAN BE HARMFUL TO PLANT & ANI MAL LIFE.
SPECIFIC DATA ON TEST ANIMALS ARE AVAIL, BUT ARE NOT PRESENTED IN THIS MSDS.
LGE RELEASES MAY BE HARMFUL/FATAL TO EXPOSED AQUATIC LIFE. BORIC ACID: LC50
(TROUT EGGS)=100 PPM/SOFT; LC50 (TROU T EGGS)=75 PPM/HARD; LC50 (CATFISH
EGGS)=165 PPM/SOFT; LC50 (CATFISH EGGS)=22 PPM/HARD; LC50 (GOLDFISH EGGS)=46
PPM/SOFT; LC50 (GOLDFISH EGGS)=75 PPM/HARD; LC50 (DAPHNIA MAGNA)=133 MG/L/48
HRS.
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MSDS Transport Information
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Transport Information: THIS MATERIAL IS NOT HAZARDOUS (PER 49 CFR 172.101) BY
U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME, HAZARD CLASS # &
DESCRIPTION, UN IDENTIFICATION #, PACKING GROUP, DOT LABEL(S) REQUIRED: N/A.
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK # (1996): N/A. MARINE POLLUTANT:
COMPONENTS OF THESE FLUXES ARE NOT DESIGNATED BY DEPARTMENT OF TRANSPORTATION
TO BE MARINE POLLUTANTS (49 CFR 172.101 , APPENDIX B). TRANSPORT CANADA
TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS CONSIDERED AS
DANGEROUS GOODS. REFER TO ABOVE INFORMATION FOR CANADIAN SHIPMENTS.
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Regulatory Information
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Sara Title III Information: COMPONENTS OF THESE FLUXES ARE NOT SUBJECT TO
REPORTING REQS OF SECTIONS 302, 304, & 313 OF TITLE III OF SUPERFUND
AMENDMENTS & REAUTHORIZATION ACT. U.S. SATA TPQ, U.S. CERCLA RQ: N/A.
OTHER INFO: IF PAIN LASTS LONGER THAN 15 MINS, PROCEED W/CALCIUM GLUCONATE
INJECTIONS. EYES: AFTER 15 MINS WATER FLUSH (IF FLUSH HAS NOT BEEN DONE),
FLUSH EYES W/1% CALCIUM GLUCONATE GEL IN NORM, STERILE SALINE. INH AL:
PROVIDE 10% OXYGEN, FOLLOWED BY INHAL OF MIST CONTAINING 2.5% CALCIUM
GLUCONATE IN SALINE SOLN. WATCH FOR PULM EDEMA. INGEST: GASTRIC LAVAGE W/LIME
WATER/MILK.
Federal Regulatory Information: U.S. REGS: U.S. TSCA INVENTORY STATUS:
COMPONENTS OF THESE FLUXES ARE LISTED ON TSCA INVENTORY. CANADIAN DSL/NDSL
INVENTORY STATUS: COMPONENTS OF THESE FLUXES ARE LISTED ON NDSL/DSL
INVENTORY. CANADIA N ENVIRON PROT ACT (CEPA) PRIORITIES SUBSTANCES LISTS:
COMPONENTS OF THESE FLUXES ARE NOT ON CEPA PRIORITIES SUBSTANCES LISTS, AS
FOLLOWS: POTASSIUM FLUORIDE (AS INORG FLUORIDE) PRIORITY LIST 1, TOX M ATL.
CANADIAN W SYMBOLS: D2B MATLS CAUSING OTHER TOX EFTS. CONT NEHC FOR MORE
COMPLETE INFO (FP N).
State Regulatory Information: COMPONENTS OF THESE FLUXES ARE COVERED UNDER
SPECIFIC STATE REGS, AS FOLLOWS: POTASSIUM FLUORIDES: MISSOURI-EMPLOYER
INFO/TOX SUBSTANCE LIST; NEW JERSEY-RIGHT TO KNOW HAZ SUBSTANCE LIST.
CALIFORNIA SA FE DRINKING WATER & TOX ENFORCEMENT ACT (PROPOSITION 65):
NO COMPONENTS LISTED. PHYSICAL/CHEMICAL PROPERTIES: HOT TO DETECT THESE
SUBSTANCES (WARNING PROPERTIES): THE APPEARANCE MAY ACT AS A DISTINGUI SHING
CHARACTERISTIC OF THESE FLUXES.
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Other Information
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Other Information: CHEM NAME/CLASS: MIXT OF POTASSIUM BORATE & FLUORIDE
CMPDS. PROD USE: METAL-WORKING OPERATIONS. RATING: HLTH=2 (BLUE); FLAMM=0
(RED); REACTIVITY=0 (YELLOW); PROT EQUIP=X. NFPA RATING: HLTH=2; FLA MM=0;
REACTIVITY=0. SUP DAT: RECS TO MD: TREAT SYMPS & ELIM OVEREXP. IN EVENT
OF OVEREXP, ALL PERS PROVIDING TREATMENT MUST BE GLOVED. IF THERE ARE
INDICATIONS THAT VICTIM IS SUFFERING FROM EFTS OF FL UORIDE OVEREXP,
TREATMENT RECS FOR CONTAM ARE AS FOLLOWS: SKIN: AFTER 15 MINS WATER FLUSH (IF
FLUSH HAS NOT YET BEEN DONE), APPLY CALCIUM GLUCONATE GEL (2.5% CONC) UNTIL
PAIN HAS SUBSIDED, BUT NOT LON GER THAN 30 MINS. (SARA REGS)
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HAZCOM Label
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MSDS NAME: STAY-SILV WHITE BRAZING FLUX
Company: J. W. HARRIS CO INC & HARRIS WELCO, DIVISION/J.W. HARRIS CO
Street: 1051 YORK RD
City: KINGS MOUNTAIN NC
Zipcode: 28086
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 12/21/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SYMPS OF INHAL OVEREXP MAY INCL COUGHING,
SNEEZING, & DFCLTY BRTHG. DEPENDING ON DURATION & CONC OF OVEREXP,
SKIN CONT CAN SEV IRRITATE SKIN, & EYE CONT CAN CAN IRRITATE EYES. SEV
INGEST OVEREX P MAY BE FATAL. CHRONIC: RPTD/PRLNG SKINOVEREXP MAY RSLT IN
DERM (RED, DRY, ITCHY SKIN). CHRONIC OVEREXP TO HYDROGEN FLUORIDE (POSS
DECOMP PROD) CAN CAUSE FLUOROSIS (WEAKENING & DEGENERATION OF BONE S
TRUCTURE & POSS HEART, NERVE, & INTESTINAL PROBLEMS). CHRONIC INGEST
OVEREXP MAY CAUSE MOTTLING OF TOOTH ENAMEL & HARDENING/ABNORM DENSITY OF
BONES. TARGET ORGANS: SKIN, EYES, RESP SYS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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