HURON INDUSTRIES INC -- ISOPROPANOL, ANHYDROUS 99%
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Material Safety Data Sheet
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MSDS Num: CKVWV
MSDS NAME: ISOPROPANOL, ANHYDROUS 99%
Responsible Party
Name: HURON INDUSTRIES INC
Box: 610104
City: PORT HURON MI 48061
Info Phone: 810-984-4213; 602-929-4400
Emergency Phone Number: 800-255-3924
Preparer's Name: DEBRA SULLIVAN
Review Ind: Y
Published: Y
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Contractor Summary
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Name: HURON INDUSTRIES INC
Address: 2301 16TH ST
Box: 610104
City: PORT HURON MI 48061-0104
Phone: 810-984-4213
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Ingredients
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Cas: 67-63-0
RTECS #: NT8050000
Name: ISOPROPYL ALCOHOL
Percent by Wt: 100.
OSHA PEL: 980 MG/M3;400 PPM
ACGIH TLV: 983 MG/M3;400 PPM
ACGIH STEL: 1230 MG/M3;500 PPM
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Health Hazards Data
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Effects of Exposure: IN DEVELOPMENTAL TOXICITY STUDIES CONDUCTED BY THE
CHEMICAL MANUFACTURERS ASSOCIATION, UNEXPECTED ACUTE TOXICITY WAS FOUND WHEN
ISOPROPANOL WAS ADMINISTERED TO PREGNANT RABBITS BY GAVAGE. THERE WERE N O
UNEXPECTED TOXIC EFFECTS IN PRERGNANT RATS EXPOSED IN THE 3AMC STUDY. IN RATS
THERE WERE SOME RELATIVELY MILD DEVELOPMENTAL EFFECTS AT MATERNALLY TOXIC
LEVELS. THERE WAS NO EVIDENCE OF TOXICITY IN T HE RABBITS AT ANY EXPOSURE
LEVEL. FINDINGS FROM MULTI GENERATION REPRODUCTION STUDY INDICATE THAT
INFANT/IMMATURE RATS ARE MORE SENSITIVE THAN THEIR PARENTS TO THE ACUTE ORAL
TOXICITY INDUCED BY HIGH (1000 MG/KG/DAY) DOSES OF ISOPROPANOL.
Explanation Of Carcinogenicity: CARCINOGEN IARC PROGRAM: N/A. CARCINOGEN NTP
PROGRAM: N/A.
Signs And Symptions Of Overexposure: EYE CONTACT: IRRITATING, AND WILL INJURE
THE TISSUE IF NOT REMOVED PLROMPTLY. SKIN CONTACT: FREQUENT OR PROLONGED
CONTACT MAY ITTITATE AND CAUSE DERMATIUTIS. LOW ORDER OF TOXICITY.
INHALATION: HIGH VA POR CONCENTRATIONS ARE IRRITATING TO THE EYES AND THE
RESPIRATORY TRACT. MAY CAUSE HEADACHES AND DIZZINESS ARE ANESTHETIC AND MAY
HAVE OTHER CENTRAL NERVOUS SYSTEM EFFECTS. NEGLIBLE HAZARD AT AMBIENT
TEMPERATURE (-18 TO 38C, 0-100F). INGESTION: MINIMAL TOXICITY SMALL AMOUNTS
OF THE LIQUID ASPIRATED INTO THE RESPIRATORY SYSTEM DURING INGESTION, OR FROM
VOMITING, MAY CAUSE BRONCHOPNEUMONIA OR PULMON ARY EDEMA.
First Aid: EYE-IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST
15 MINUTES. GET PROMPT MEDICAL ATTENTION. SKIN-IMMEDIATELY FLUSH WITH LARGE
AMOUNTS OF WATER, USE SOAP IF AVAILABLE REMOVE CONTAMINA TED CLOTHING,
INCLUDING SHOES, AFTER FLUSHING HAS BEGUN. INHALATION-USING PROPER
RESPIRATORY PROTECTION, IMMEDIATELY REMOVE THE AFFECTED VICTIM FROM EXPOSURE.
ADMINISTER ARTIFICIAL RESPIRATION IF BREA THING IS STOPPED. KEEP AT REST.
CALL FOR PROMPT MEDICAL ATTENTION. INGESTION-IF PATIENT IS CONSCIOUS AND HAS
A GAG REFLEX. GIVE 2 GLASSES OF WATER, INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION WITHOUT DE LAY.
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Handling and Disposal
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Spill Release Procedures: LAND SPILL: ELIMINATE SOURCES OF IGNITION, PREVENT
ADDITIONAL DISCHARGE OF MATERIAL, IF POSSIBLE TO DO WITHOUT HAZARD. FOR SMALL
SPILLS IMPLEMENT CLEANUP PROCEDURES; FOR LARGE SPILLS IMPLEMENT CLEANUP
PROCEDURES AND, IF IN PUBLIC AREA, KEEP PUBLIC AWAY AND ADVISE AUTHORITIES.
ALSO, IF THIS PRODUCT IS SUBJECT TO CERCLA REPORTING, NOTIFY THE NATIONAL
RESPONSE CENTER.
Other Precautions: FIRE/EXPLOSION-APORS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG GROUND OR MAY BE MOVED BY VENTILATION & IGNITED BY PILOT LIGHTS,
OTHER FLAMES, SPARKS, HEATER, SMOKING, ELECTRIC MOTORS, STATIC DISCHARGE, OR
OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING POINT,
MATERIAL MAY PRODUCE FL OATING FIRE HAZARD.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =11.7C, 53.F
Autoignition Temp: >327.8C, 622.F
Lower Limits: 2.0
Upper Limits: 12.7
Extinguishing Media: APPLY ALCOHOL-TYPE OF ALL-PURPOSE FOAM BY MANUFACTUER'S
RECOMMENDED TECHNIQUES FOR LARGE FIRES. USE CARBON DIOXIDE OR DRY CHEMICAL
MEDIA FOR SMALL FIRES.
Fire Fighting Procedures: USE WATER SPRAY TO COOL FIRE EXPOSED SURFACE/PROTECT
PERSONNEL. SHUT OFF "FUEL" TO FIRE. IF LEAK/SPILL HAS NOT IGNITED, USE WATER
SPRAY TO DISPERSE VAPORS OR ALLOW FIRE TO BURN UNDER CONTROLLED CONDIT
IONS/EXTINGUISH WITH ALCOHOL TYPE FOAM & DRY CHEMICAL. TRY TO COVER
LIQUID SPILL WITH FOAM. USE SCBA/PROTECTIVE CLOTHES.
Unusual Fire/Explosion Hazard: NEVER USE WELDING OR CUTTING TORCH ON OR NEAR
DRUM (EVEN EMPTY) BECAUSE PRODUCT CAN IGNITE EXPLOSIVELY. ALL 5 GALLON PAILS
& LARGER METAL CONTAINERS INCLUDING TANK CARS & TANK TRUCKS SHOULD BE
GROUNDE D &/OR BONDED WHEN MATERIAL IS TRANFERRED.
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Control Measures
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Respiratory Protection: FOR OPEN SYSTEMS WHERE CONTACT IS LIKELY, WORK PRACTICE
OR OTHER MEANS OF EXPOSURE REDUCTION ARE NOT ADEQUATE, NIOSH/MSHA APPROVED
RESPIRATORS MAY BE NECESSARY TO PREVENT OVEREXPOSURE BY INHALATION.
Ventilation: GENERAL (MECHANICAL) ROOM VENTILATION IS EXPECTED TO BE
SATISFACTORY. SPECIAL, LOCAL VENTILATION IS NEEDED WHERE VAPORS ESCAPE TO
WORKPLACE AIR.
Protective Gloves: CHEMICAL RESISTANT GLOVES.
Eye Protection: CHEMICAL GOGGLES, SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment: FOR OPEN SYSTEMS, WHERE CONTACT IS LIKELY, WEAR
LONG SLEEVES. TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR IMPERVIOUS
CLOTHING AND BOOTS.
Supplemental Safety and Health: SPILL-VAPOR/DUST CAN BE HARMFUL/FATAL. WARN
OCCUPANTS OF DOWNWIND AREAS. PREVENT LIQUID FROM ENTERING SEWER, WATERCOURSE,
OR LOW AREA. CONTAIN SPILLED LIQUID WITH SAND/EARTH. DO NOT USE COMBUSTIBLE
MA TERIAL (SAWDUST). REMOVE BY PUMPING (EXPLOSION PROOF/HAND PUMP) OR WITH A
SUITABLE ABSORBENT. CONSULT DISPOSAL EXPERT.
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Physical/Chemical Properties
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HCC: F2
Boiling Point: =82.3C, 180.1F
Melt/Freeze Pt: =52.9C, 127.3F
Vapor Pres: 33 MMHG
Vapor Density: 2.07
Spec Gravity: 0.7861 AT 20/20C
Viscosity: 3@68F
Evaporation Rate & Reference: 238
Solubility in Water: COMPLETE AT 20C
Appearance and Odor: TRANSPARENT COLORLESS LIQUID, CHARACTERISTIC.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE KNOWN.
Materials To Avoid: ALDEHYDES, STRONG OXIDIZING AGENTS, HALOGENS, STRONG
INORGANIC ACIDS, HALOGEN COMPOUNDS.
Hazardous Decomposition Products: BURNING CAN PRODUCE THE FOLLOWING COMBUSTION:
CARBON MONOXIDE AND/OR CARBON DIOXIDE, CARBON MONOXIDE IS HIGHLY TOXIC IF
INHALED; CARBON DIOXIDE IN SUFFICENT CONCENTRATIONS CAN ACT AS AN ASPHYXIANT.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: OSHA REGULATIONS 29CFR1910.1000 REQUIRES THE
FOLLOWING PERMISSIBLE EXPOSURE LIMITS: A TWA OD 400 PPM (980 MG/M3) AND A
STEL OF 500 PPM (1225 MG/M3) FOR ISOPROPYL ALCOHOL. THE ACGIH RECOMMENDS THE
FOLL OWING THRESHOLD LIMIT VALUES: A TWA OF 400 PPM (983 MG/M3), AND A STEL
OF 500 PPM (1230 MG/M3) FOR ISOPROPYL ALCOHOL.
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Ecological Information
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Ecological: WATER SPILL: ELIMINATE SOURCES OF IGNITION. VAPOR/DUST CAN BE
HARMFUL/FATAL. WARN OCCUPANTS AND SHIPPING IN DOWNWINDS AREAS. CONSULT AN
EXPERT ON DISPOSAL OR RECOVERED MATERIAL AND ENSURE CONFORMITY T O LOCAL
DISPSOAL REGULATIONS.
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MSDS Transport Information
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Transport Information: ISOPROPANOL, 3, UN1219, PG II. FLAMMABLE LIQUID.
EMERGENCY RESPONSE: 800-255-3924.
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Regulatory Information
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Sara Title III Information: SARA TITLE III: UNDER THE PROVISIONS OF TITLE III,
SECTION 311/312 OF THE SUPERFUND AMENDMENT AND REAUTHORIZATION ACT, THIS
PRODUCT IS CLASSIFIED INTO THE FOLLOWING HAZARD CATEGORIES: IMMEDIATE HEALTH
, DELAYED HEALTH, FIRE.
Federal Regulatory Information: THIS PRODUCT IS HAZARDOUS AS DEFINED IN 29 CFR
1910.1000. OSHA HAZARD: FLAMMABLE PEL: TLV, EYE IRRITANT. TSCA: THIS PRODUCT
IS LISTED ON THE TSCA INVENTORY AT CAS REGISTRY NUMBER 67-63-0.
CERCLA: IF T HIS PRODUCT IS ACCIDENTALLY SPILLED, IT IS NOT SUBJECT TO ANY
REPORTING UNDER THE REQUIREMENTS OF THE COMPREHENSIVE ENVIRONMENTAL RESPONSE,
COMPENSATION AND LIABILITY ACT (CERCLA). WE RECOMMEND YOU CO NTACT LOCAL
AUTHORITIES TO DETERMINE IF THERE MAY BE OTHER LOCAL REPORTING REQUIREMENTS.
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Other Information
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Other Information: GENERAL HAZARD-FLAMMABLE LIQUID, CAN RELEASE VAPORS THAT
FORM FLAMMABLE MIXTURES AT TEMPERATURES AT OR ABOVE THE FLASHPOINT. "EMPTY"
CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID &/OR VAPOR) & CAN BE DANG
EROUS. DO NOT PRESSURIZE, CUT, WLED, BRAZE, OLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES
OF IGNITION; THEY MAY EXPLODE & CAUSE INJURY OR DEATH. EMPTY DRUMS
SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & PROMPTLY RETURNED TO A
DRUM RECONDITIONER, OR PROPERLY DISPOSED OF.
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Transportation Information
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Trans ID NO: 155311
MSDS NAME: ISOPROPANOL, ANHYDROUS 99%
MSDS Prepared Date: 05/05/1999
Review Date: 11/09/2000
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CY
Type Of Container: CYLINDER
Additional Data: ESTIMATED RATINGS: HEALTH-2, FLAMMIBILITY-3, REACTIVITY-0,
PERSONAL PROTECTION-H. ESTIMATED NFP A RATINGS: HEALTH-1, FLAMMIBILITY-3,
REACTIVITY-0.
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Detail DOT Information
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DOT PSN Code: HWY
DOT Proper Shipping Name: ISOPROPANOL OR ISOPROPYL ALCOHOL
Hazard Class: 3
UN ID Num: UN1219
DOT Packaging Group: II
Label: FLAMMABLE LIQUID
Special Provision: T1
Packaging Exception: 150
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
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Detail IMO Information
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IMO PSN Code: ITA
IMO Proper Shipping Name: ISOPROPANOL
IMDG Page Number: 3244
UN Number: 1219
UN Hazard Class: 3.2
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 3-06
MED First Aid Guide NUM: 305
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Detail IATA Information
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IATA PSN Code: ONH
IATA UN ID Num: 1219
IATA Proper Shipping Name: ISOPROPANOL
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
UN Packing Group: II
Packing Note Passenger: 305
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 307
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Detail AFI Information
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AFI PSN Code: ONH
AFI Proper Shipping Name: ISOPROPANOL
AFI Hazard Class: 3
AFI UN ID NUM: UN1219
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A7.3
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HAZCOM Label
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MSDS NAME: ISOPROPANOL, ANHYDROUS 99%
Company: HURON INDUSTRIES INC
Street: 2301 16TH ST
PO Box: 610104
City: PORT HURON MI
Zipcode: 48061-0104
Health Emergency Phone: 800-255-3924
Label Required IND: Y
Date Of Label Review: 11/09/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: IN DEVELOPMENTAL TOXICITY STUDIES CONDUCTED BY THE
CHEMICAL MANUFACTURERS ASSOCIATION, UNEXPECTED ACUTE TOXICITY WAS FOUND WHEN
ISOPROPANOL WAS ADMINISTERED TO PREGNANT RABBITS BY GAVAGE. THERE WERE N O
UNEXPECTED TOXIC EFFECTS IN PRERGNANTRATS EXPOSED IN THE 3AMC STUDY. IN RATS
THERE WERE SOME RELATIVELY MILD DEVELOPMENTAL EFFECTS AT MATERNALLY TOXIC
LEVELS. THERE WAS NO EVIDENCE OF TOXICITY IN TH E RABBITS AT ANY EXPOSURE
LEVEL. FINDINGS FROM MULTI GENERATION REPRODUCTION STUDY INDICATE THAT
INFANT/IMMATURE RATS ARE MORE SENSITIVE THAN THEIR PARENTS TO THE ACUTE ORAL
TOXICITY INDUCED BY HIGH ( 1000 MG/KG/DAY) DOSES OF ISOPROPANOL.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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