EASTMAN KODAK COMPANY -- 839 6210,KODAK PRE-BLEACH II,SINGLE-USE (SEE
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Material Safety Data Sheet
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NIIN: 01-301-8779
MSDS Num: CKWBD
MSDS NAME: 839 6210,KODAK PRE-BLEACH II,SINGLE-USE (SEE SUPPL DATA)
Kit Part: Y
Responsible Party
Name: EASTMAN KODAK COMPANY
Address: 343 STATE STREET
City: ROCHESTER NY 14650
Info Phone: 716-722-5151/(800) 242-2424
Emergency Phone Number: 716 722-5151
Preparer's Name: NOT PROVIDED
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address: 343 STATE ST
City: ROCHESTER NY 14650-1115
Phone: 716-722-5151/(800) 242-2424
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Item Description Information
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Item Manager: S9I
Item Name: CHEMICAL KIT,PHOTOGRAPHIC COLOR PROCESSING
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: KT
UI Container Qty: 1
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EFFECTS OF EXPOSURE: GENERAL: CONTAINS: METHANOL.
INGESTION MAY CAUSE VISUAL DISTURBANCES OR BLINDNESS. INHALATION: LOW HAZARD
FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULF
ITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO
THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY
EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITAT ION. SKIN: CAUSES
IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF SWALLOWED.
Explanation Of Carcinogenicity: CARCINOGENICITY CLASSIFICATION (COMPONENTS
PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
(IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
(ACGIH): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL
SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE
Signs And Symptions Of Overexposure: INHALATION: IN CONTACT WITH STRONG ACIDS
OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS
IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE
INDIVIDUA LS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION.
SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. INGESTION: MAY
CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF SWALLOWED.
Medical Cond Aggravated By Exposure: SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING,
CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA.
First Aid: INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY
FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTEN TION.
SKIN: IMMEDIATELY REMOVECONTAMINATED CLOTHING AND SHOES AND WASH WITH SOAP
AND PLENTY OF WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH
CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR THORO UGHLY CLEAN CONTAMINATED
SHOES. INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATEL Y.
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Handling and Disposal
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Spill Release Procedures: FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE
IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE
RESIDUAL CONTAMINATION.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO
NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS E VEN
AFTER CONTAINER IS EMPTIED.
Handling And Storage Precautions: KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION). KEEP FROM CONTACT WITH
OXIDIZING MATERIALS.
Other Precautions: AVOID BREATHING VAPOR AT CONCENTRATIONS GREATER THAN THE
EXPOSURE LIMITS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Extinguishing Media: WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL, ALCOHOL
FOAM
Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard: NONE
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Control Measures
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Respiratory Protection: IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, WEAR AN APPROVED FULL-FACE
POSITIVE-PRESSURE AIR-SUPPLIED RESPIRATOR. IF FORMALDEHYDE IS EMITTED AT L
EVELS REQUIRING RESPIRATORY PROTECTION, WEAR FULL FACEPIECE WITH CARTRIDGES
APPROVED BY NIOSH. OBSERVE OSHA STANDARD 29CFR 1910.134 AND 29CFR 1910.1048.
Ventilation: GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
Protective Gloves: WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE
FOR RISK OF EXPOSURE
Eye Protection: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment: EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices: NOT PROVIDED
Supplemental Safety and Health: USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS. CONTINUED FROM PRODUCT ID: CHEMISTRY KIT PROCESS
E-6.
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Physical/Chemical Properties
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HCC: C1
NRC/State LIC No: NOT RELEVANT
Boiling Point: >100.C, 212.F
M.P/F.P Text: NOT PROVIDED
Decomp Text: NOT PROVIDED
Vapor Pres: (68F):24 MBAR (18 MM HG)
Vapor Density: 0.6
Spec Gravity: 1.21
PH: 6.0
Viscosity: NOT PROVIDED
Evaporation Rate & Reference: NOT PROVIDED
Solubility in Water: COMPLETE
Appearance and Odor: COLORLESS, ODORLESS, LIQUID.
Percent Volatiles by Volume: 80-85 WT
Corrosion Rate: NOT PROVIDED
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NOT PROVIDED
Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES.
Hazardous Decomposition Products: FORMALDEHYDE. OXIDES OF SULFUR, CARBON
MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
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Toxicological Information
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Toxicological Information: EFFECTS OF EXPOSURE: GENERAL: CONTAINS: METHANOL.
INGESTION MAY CAUSE VISUAL DISTURBANCES OR BLINDNESS. INHALATION: LOW HAZARD
FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULF
ITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE
RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY
EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATI ON. SKIN: CAUSES
IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF SWALLOWED.
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Ecological Information
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Ecological: IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A LOW BIOCHEMICAL
OXYGEN DEMAND AND LITTLE POTENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS
SYSTEMS, A LOW POTENTIAL TO AFFECT AQUATIC ORGANISMS, A LOW POTENTIAL TO
AFFECT SECONDARY WASTE TREATMENT MICROBIAL METABOLISM, A LOW POTENTIAL TO
AFFECT THE GERMINATION AND/OR EARLY GROWTH OF SOME PLANTS, A LOW POTENTIAL
TO BIOCONCENTRATE. AFTER DILUTION WITH A LARGE AMOUNT OF WATER, FOLLOWED BY
SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE
ENVIRONMENTAL EFFECTS.
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MSDS Transport Information
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Transport Information: FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT
CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400
BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY .
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Regulatory Information
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Sara Title III Information: CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS
OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: METHANOL
Federal Regulatory Information: NOT PROVIDED
State Regulatory Information: MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
ADVERSE REPRODUCTIVE EFFECTS: NONE
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Other Information
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Other Information: CONTAINS: 1-THIOGLYCEROL (000096-27-5); METHANOL
(000067-56-1); STABILIZING AGENT (PROPRIETARY); POTASSIUM SULFITE
(010117-38-1). WARNING! HARMFUL IF ABSORBED THROUGH SKIN OR SWALLOWED. CAUSES
SKIN AN D EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. CONTACT WITH ACID
LIBERATES HARMFUL GAS. CONTACT WITH BASE LIBERATES HARMFUL GAS.
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Transportation Information
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Trans ID NO: 155362
MSDS NAME: 839 6210,KODAK PRE-BLEACH II,SINGLE-USE (SEE SUPPL DATA)
MSDS Prepared Date: 12/21/1998
Review Date: 11/15/2000
Multiple KIT Number: 0
Kit Part IND: Y
Unit Of Issue: KT
Container QTY: 1
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: 839 6210,KODAK PRE-BLEACH II,SINGLE-USE (SEE SUPPL DATA)
Company: EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Street: 343 STATE ST
City: ROCHESTER NY
Zipcode: 14650-1115
Health Emergency Phone: 716 722-5151
Label Required IND: Y
Date Of Label Review: 11/15/2000
Status Code: A
MFG Label NO: NOT PROVIDED
Label Date: 12/21/1998
Origination
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: NO
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: N/P. WARNING! HARMFUL IF ABSORBED
THROUGH SKIN OR SWALLOWED. CAUSES SKIN AND EYE IRRITATION. MAY CAUSE ALLERGIC
SKIN REACTION. FIRST AID: IF SWALLOWED, INDUCE VOMITING IMMEDIATELY AS DI
RECTED BY MEDICAL PERSONNEL. NEVER GIVEANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. IN CASE OF EYE
CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. IN CASE OF SKIN CONTACT, IMMEDIATELY WASH WITH SOAP AND PLENTY OF
WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF
SYMPTOMS OCCUR. KEEP OUT OF REA CH OF CHILDREN.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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