ITW PHILADELPHIA RESINS -- ANNAPOLIS ADHESIVE HARDENER, 6020H
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Material Safety Data Sheet
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MSDS Num: CKVST
MSDS NAME: ANNAPOLIS ADHESIVE HARDENER, 6020H
Responsible Party
Name: ITW PHILADELPHIA RESINS
Address: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA 18936
Info Phone: 215-855-8450
Emergency Phone Number: 215-855-8450
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: ITW PHILADELPHIA RESINS CORPORATION
Address: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA 18936
Phone: 215-855-8450
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: NO DATA AVAILABLE.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES ARE LISTED AS A ROUTE OF EXPOSURE. WARNING! SEVERE
EYE IRRITANT. MAY CAUSE SKIN IRRITATION. OVEREXPOSURE MAY CAUSE RESPIRATORY
TRACT, MUCOUS MEMBRANE IRRITATION. CAN CAUSE CNS EFFECTS (EVIDENCED BY
DIZZINESS, HEADACHE, NAUSEA AND VOMITING).
Signs And Symptions Of Overexposure: ACUTE: SKIN: MILDLY IRRITATING TO THE
SKIN. EYES: AN EYE IRRITANT. CORNEAL DAMAGE MAY OCCUR. INHALATION: MAY CAUSE
MILD IRRITATION TO THE NOSE, THROAT AND RESPIRATORY TRACT AND MAY RESULT IN
CENTRAL N ERVOUS SYSTEM DEPRESSION. INGESTION: IRRITATING TO THE
GASTROINTESTINAL TRACT, CAUSING ABDOMINAL PAIN AND VOMITING, SOMETIMES
BLOODY. INGESTION MAY CAUSE CNS DEPRESSION, LOW BLOOD PRESSURE, RAPID HEAR T
BEAT AND LIVER DAMAGE. CHRONIC: INHALATION: MAY CAUSE LIVER, KIDNEY OR BRAIN
DAMAGE.
Medical Cond Aggravated By Exposure: EXISTING EYE, SKIN AND RESPIRATORY
DISORDERS.
First Aid: EYES: FLUSH EYES WITH CLEAN WATER FOR AT LEAST 15 MINUTES WHILE
GENTLY HOLDING EYELIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN:
IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND EXCESS CONTAMINANT. FLU SH SKIN
WITH WATER. WASH THOROUGHLY WITH SOAP AND WARM WATER. CONSULT A PHYSICIAN IF
IRRITATION DEVELOPS. INHALATION: REMOVE PATIENT TO FRESH AIR. ADMINISTER
OXYGEN IF BREATHING IS DIFFICULT. GET MEDI CAL ATTENTION IF SYMPTOMS PERSIST.
INGESTION: DO NOT INDUCE VOMITING. GIVE A LARGE QUANTITY OF MILK OR WATER. DO
NOT GIVE FLUIDS TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: AVOID PERSONAL CONTACT. ELIMINATE IGNITION SOURCES.
VENTILATE AREA. DIKE, CONTAIN AND ABSORB WITH CLAY, SAND OR OTHER SUITABLE
MATERIAL. WEAR APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. FOR LARGE
SPILLS, PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT
SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIAL AND DISPOSE OF PROPERLY. FLUSH
AREA WITH WATER TO REMOVE TRACE (SUPP DATA)
Waste Disposal Methods: IF THIS PRODUCT BECOMES A WASTE, IT WOULD BE A
HAZARDOUS WASTE BY RCRA CRITERIA (40CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: HANDLING: DO NOT BREATH VAPOR OR MIST. DO NOT
GET INTO EYES, ON SKIN OR CLOTHING. WASH THOROUGHLY AFTER HANDLING. CLOSE
CONTAINER AFTER EACH USE. GROUND CONTAINER WHEN POURING. KEEP AWAY FROM HEAT,
FL AME OR SPARKS. USE NON-SPARKING TOOLS. STORAGE: KEEP IN A COOL PLACE,
(OTHER PREC)
Other Precautions: HANDLING/STORAGE: WITHOUT DIRECT EXPOSURE TO SUNLIGHT. KEEP
CONTAINER TIGHTLY CLOSED AND OTHERWISE IN ACCORDANCE WITH NFPA REGULATIONS.
MAINTAIN AIR SPACE IN STORAGE CONTAINERS. FLAMMABLE. AVOID SKIN AND EYE
CONTACT. AVOID BREATING VAPOR. USE WITH ADEQUATE VENTILATION.
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Fire and Explosion Hazard Information
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Flash Point: >37.8C, 100.F
Flash Point Text: METHOD:ESTIMATE.
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, ALCOHOL FOAM.
Fire Fighting Procedures: CLEAR AREA OF UNPROTECTED PERSONNEL. DO NOT ENTER
CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER
COATS, GLOVES AND RUBBER BOOTS) AND A POSITIVE PRESSURE NIOSH APPROVED S
ELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER
SPRAY.
Unusual Fire/Explosion Hazard: FLAMMABLE SUBSTANCE. CONTAINERS EXPOSED TO
INTENSE HEAT FROM FIRES COULD RUPTURE FROM VAPOR PRESSURE BUILDUP. HAZARDOUS
PRODUCTS OF COMBUSTION: CARBON MONOXIDE, CARBON DIOXIDE, AND OTHER UNKNOWN
ORGAN IC COMPOUNDS.
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Control Measures
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Respiratory Protection: NONE REQUIRED IF AIR CONCENTRATIONS ARE BELOW
PERMISSIBLE LEVELS. OTHERWISE, A NIOSH APPROVED AIR PURIFYING RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE MAY BE PERMISSIBLE. USE A NIOSH APPROVED POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLLED
RELEASE, OR UNKNOWN EXPOSURE LEVELS.
Ventilation: USE VENTILATION THAT IS ADEQUATE TO KEEP EMPLOYEE EXPOSURE TO
AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: WEAR ANSI APPROVED CHEMICAL SPLASH GOGGLES AND FACE SHIELD (FP
N) (SUPP DATA)
Other Protective Equipment: WEAR IMPERVIOUS BUTYL RUBBER CLOTHING TO PREVENT
ANY CONTAMINATION. HAVE EMERGENCY EYE WASH AND SAFETY SHOWER MEETING ANSI
DESIGN CRITERIA PRESENT.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: EYE PROT: WHEN EYE & FACE CONTACT IS
POSSIBLE. OBSERVE LABEL PRECAUTIONS. SPILL/RELEASE: RESIDUE. SMALL SPILLS:
TAKE UP W/ABSORBENT MATERIAL & PLACE IN APPROPRIATE CONTAINERS FOR
DISPOSAL. PREVENT SP ILL FROM ENTERING DRAINAGE/SEWER SYSTEM, WATERWAYS &
SURFACE WATERS. USE BONDING/GROUNDING LINES & NON-SPARKING TOOLS.
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Physical/Chemical Properties
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B.P. Text: N/D
M.P/F.P Text: N/D
Vapor Pres: N/D @ 68F.
Vapor Density: N/D
Spec Gravity: 1.07
PH: N/D
VOC Grams/Liter: 211
Evaporation Rate & Reference: N/D (BUTYL ACETATE=1).
Solubility in Water: MODERATE.
Appearance and Odor: BLACK PASTE WITH SOLVENT ODOR.
Percent Volatiles by Volume: N/D
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THIS MATERIAL IS CHEMICALLY STABLE. AVOID HEAT,
OPEN FLAMES, TEMPERATURES ABOVE 120F AND IGNITION SOURCES.
Materials To Avoid: DO NOT USE UNCURED MATERIAL WITH ALUMIUM EQUIPMENT AT
TEMPERATURES ABOVE 120F. AVOID CONTACT WITH STRONG OXIDIZING AGENTS, ACIDS,
CHLORINE, ACETALDEHYDE, ETHYLENE OXIDE.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE AND UNKNOWN
PRODUCTS OF DECOMPOSITION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE KNOWN.
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Toxicological Information
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Toxicological Information: ACUTE ORAL EFFECTS: LD50 (RAT): NO DATA AVAILABLE.
ACUTE DERMAL EFFECTS: LD50 (RABBIT): NO DATA AVAILABLE. ACUTE INHALATION
EFFECTS: LC50 (RAT): NO DATA AVAILABLE. EYE IRRITATION: NO DATA AVAILABLE. S
UBCHRONIC EFFECTS: NO DATA AVAILABLE. CARCINOGENICITY, TERATOGENICITY, &
MUTAGENICITY: NO DATA AVAILABLE. OTHER CHRONIC EFFECTS: NO DATA AVAILABLE.
TOXICOLOGICAL INFORMATION ON HAZARDOUS CHEMICAL CONS TITUENTS OF THIS
PRODUCT: BUTYL ALCOHOL: ORAL LD50 (RAT) 790 MG/MK. DERMAL LD50 (RABBIT): 3400
MG/KG. INHALATION LC50 4 HR (RAT): 8000 PPM. POLYAMINE ADDUCT: ORAL LD50
(RAT): N/D. DERMAL LD50 (RABBIT) : N/D. INHALATION LC50 4HR (RAT): N/D.
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Ecological Information
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Ecological: NO DATA AVAILABLE FOR ECOTOXICITY, MOBILITY AND PERSISTANCE,
ENVIRONMENTAL FATE.
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MSDS Transport Information
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Transport Information: PROPER SHIPPING NAME: BUTANOLS SOLUTION. HAZARD CLASS:
3. UN NUMBER: 1120. PACKING GROUP: III. EMERGENCY RESPONSE GUIDE NUMBER: 129.
IMDG PAGE NUMBER: 3313.
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Regulatory Information
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Sara Title III Information: FOR PURPOSES OF SARA SECTION 312 HAZARDOUS
MATERIALS INVENTORY REPORTING, THE FOLLOWING HAZARD CLASSES APPLY TO THIS
MATERIAL: IMMEDIATE HEALTH HAZARD. DELAYED HEALTH HAZARD. FIRE HAZARD. BUTYL
ALCOHO L IS ON SARA SECTION 313 LIST OF TOXIC CHEMICALS, FOR WHICH RELEASE
REPORTING MAY BE REQUIRED. FOR SPECIFIC REQUIREMENTS, CONSULT THE APPROPRIATE
REGULATIONS. CONSULT THE APPROPRIATE REGULATIONS FOR E MERGENCY PLANNING AND
RELEASE REPORTING REQUIREMENTS FOR SUBSTANCES ON THE SARA SECTION 301
EXTREMELY HAZARDOUS SUBSTANCE LIST: NONE.
Federal Regulatory Information: TSCA: ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. THE FOLLOWING RCRA
CODE(S) APPLIES TO THIS MATERIAL IF IT BECOMES WASTE: D001. REGULATORY STATUS
OF HAZARDOUS CHEMICAL CONSTITUENTS OF THISPRODUCT: BUTYL ALCOHOL: EXTREMELY
HAZARDOUS: NO. TOXIC CHEMICAL: YES. CERCLA RQ (LBS): NONE. TSCA 12B EXPORT
NOTIFICATION: NOT REQUIRED. POLYAMINE ADDUCT: EXTRE MELY HAZARDOUS: NO. TOXIC
CHEMICAL: NO. CERCLA RQ (LBS): NONE. TSCA 12B EXPORT NOTIFICATION: NOT REQ
UIRED. CANADIAN REGULATOINS: W HAZARD CLASS(ES): B3. D28.
State Regulatory Information: N/P.
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Other Information
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Other Information: ; HEALTH-2. FLAMMABILITY-2. REACTIVITY-0. CANCER-SUSPECT
CONSTITUENTS: NONE. NFPA: NOT PROVIDED. CHEMICAL FAMILY: POLYAMINE ADDUCT.
GENERAL USE: THE HEALTH HAZARD DATA OF THIS MSDS PERTAINS TO TH E HARDENER
ONLY. WHEN FULLY CURED, THE MIXED PRODUCT IS NON-HAZARDOUS. HNDLG/STOR:
WITHOUT DIRECT EXPOSURE TO SUNLIGHT. KEEP CONTAINER TIGHTLY CLOSED AND
OTHERWISE IN ACCORDANCE WITH NFPA REGULATIONS . MAINTAIN AIR SPACE IN STORAGE
CONTAINERS.
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HAZCOM Label
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MSDS NAME: ANNAPOLIS ADHESIVE HARDENER, 6020H
Company: ITW PHILADELPHIA RESINS CORPORATION
Street: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA
Zipcode: 18936
Health Emergency Phone: 215-855-8450
Label Required IND: Y
Date Of Label Review: 11/03/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: FLAMMABLE. WARNING! SEVERE EYE IRRITANT. MAY CAUSE SKIN
IRRITATION. OVEREXPOSURE MAY CAUSE RESPIRATORY TRACT, MUCOUS MEMBRANE
IRRITATION. CAN CAUSE CNS EFFECTS (EVIDENCED BY DIZZINESS, HEADACHE, NAUSE A
AND VOMITING). ACUTE: SKIN: MILDLY IRRITATING TOTHE SKIN. EYES: CORNEAL
DAMAGE MAY OCCUR. INHALATION: MAY CAUSE MILD IRRITATION TO THE NOSE, THROAT
& RESP TRACT & MAY RESULT IN CNS DEPRESSION. INGES T: IRRIT TO THE GI
TRACT, CAUSING ABDOMINAL PAIN & VOMITING, SOMETIMES BLOODY. INGEST
MAYCAUSE CNS DEPRESSION, LOW BLOOD PRESSURE, RAPID HEART BEAT & LIVER
DAMAGE. ITARGET ORGANS: LIVER, KIDNEY OR BR AIN.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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