EAGLE-PICHER INDUSTRIES INC -- CAREFREE OR HE RECHARGEABLE BATTERY
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Material Safety Data Sheet
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MSDS Num: CKZKQ
MSDS NAME: CAREFREE OR HE RECHARGEABLE BATTERY
Article: Y
Responsible Party
Name: EAGLE-PICHER INDUSTRIES INC
Address: 14212 BETHEL ROAD
Box: 130
City: SENECA MO 64865
Info Phone: 417-776-2256
Emergency Phone Number: 417-776-2256
Chemtrec IND/Phone: (800)424-9300
Published: Y
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Contractor Summary
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Name: EAGLE-PICHER INDUSTRIES INC
Address: 14212 BETHEL ROAD
Box: 130
City: SENECA MO 64865
Phone: 417-776-2256
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Regulated Components
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Regulated Component Name: LEAD
CAS: 7439-92-1
Percent Text: 50%
Regulated Component Name: LEAD OXIDE
CAS: 1317-36-8
Regulated Component Name: LEAD OXIDE
CAS: 1314-41-6
Regulated Component Name: SULFURIC ACID, 38%
CAS: 7664-93-9
Percent Text: 18%
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SEVERE BURNS AND EYE DAMAGE FROM SULFURIC ACID
ELECTROLYTE. ILLNESS FROM SULFUR OXIDE FUMES. CONTAINS LEAD WHICH IS KNOWN TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
Signs And Symptions Of Overexposure: IRRITATION AND ACID BURNS. PUNGENT ODOR
AND RESPIRATORY IRRITATION.
First Aid: FOR SULFUR OXIDE FUMES, DISCONNECT BATTERIES, EVACUATE AND
VENTILATE. EXTERNAL: FLUSH AREAS CONTAMINATED BY SULFURIC ACID ELECTROLYTE
WITH WATER. INTERNAL: DRINK LARGE QUANTITIES OF WATER OR MILK, FOL LOWED BY
MILK OF MAGNESIA, BEATTEN EGGS, OR VEGETABLE OIL.
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Handling and Disposal
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Spill Release Procedures: AVOID CONTACT WITH SULFURIC ACID ELECTROLYTE FROM
BATTERY. FLUSH WITH WATER. NEUTRALIZE WITH SOLUTION OF BAKING SODA IN WATER.
Neutralizing Agent: USE SOLUTION OF BAKING SODA IN WATER.
Waste Disposal Methods: UNLAWFUL TO DISPOSE IN LANDFILL. DO NOT INCINERATE,
PUNCTURE, DISASSEMBLE OR MUTILATE. DISPOSE WITH AUTOMOTIVE BATTERY SCRAP IN
ACCORDANCE WITH LOCAL AND FEDERAL REGULATIONS.
Handling And Storage Precautions: BATTERIES WITH RELEASED ELECTROLYTE SHALL BE
SEALED IN POLYETHYLENE BAGS. KEEP BATTERIES AWAY FROM CHILDREN.AVOID CONTACT
WITH SULFURIC ACID ELECTROLYTE FROM BATTERY. FLUSH WITH WATERNEUTRALIZE WITH
S OLUTION OF BAKING SODA IN WATER.
Other Precautions: DO NOT CRACK BATTERY CASES. DO NOT OVERCHARGE. DO NOT SHORT
CIRCUIT BATTERY TERMINALS. KEEP LIGHTED CIGARETTES, SPARKS, AND FLAMES AWAY
FROM CHARGING BATTERIES.
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Fire and Explosion Hazard Information
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Extinguishing Media: WATER, FOAM, DRY.
Fire Fighting Procedures: FLASH POINT (METHOD USED) DIRECT FLAME TO BATTERY
CASE. FLAMMABLE LIMITS: UL-94HB 94V-O ON FR UNITS.
Unusual Fire/Explosion Hazard: KEEP LIGHTED CIGARETTES, SPARKS, FLAMES AWAY.
EXPLOSION CAN RESULT FROM IMPROPER CHARGING AND IGNITION OF CHARGING GASES.
EXPLOSION CAN RESULT IF CHARGED IN GAS TIGHT ENCLOSURES.
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Control Measures
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Ventilation: NATURAL CONVECTION VENTILATION.
Protective Gloves: RUBBER GLOVES IF CASE IS CRACKED BATTERY CASE.
Eye Protection: RECOMMENDED.
Supplemental Safety and Health: THIS PRODUCT IS AN ARTICLE UNDER OSHA.
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Physical/Chemical Properties
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HCC: Z4
Spec Gravity: 1.28
Evaporation Rate & Reference: N/A (BUAC=1)
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: SEVERE OVERCHARGING AND OVERHEATING.
Materials To Avoid: SOLVENTS MAY DISSOLVE BATTERY CASE MATERIAL.
Hazardous Decomposition Products: SEVER OVERCHARGING AND OVERHEATING MAY CAUSE
SULFUR OXIDE FUMES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: THIS PRODUCT IS AN ARTICLE UNDER OSHA.
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Ecological Information
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MSDS Transport Information
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Transport Information: GROUND SHIPMENTS: NOT REGULATED PER 49 CFR 173.159 (D).
AIR SHIPMENTS: NOT REGULATED PER IATA, SPECIAL PROVISIONS 4.4, A67. OCEAN
SHIPMENTS: NOT REGULATED. THIS PRODUCT IS AN ARTICLE UNDER OSHA.
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Regulatory Information
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Other Information
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Other Information: THIS PRODUCT IS AN ARTICLE UNDER OSHA.
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Transportation Information
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Trans ID NO: 156144
MSDS NAME: CAREFREE OR HE RECHARGEABLE BATTERY
MSDS Prepared Date: 04/01/1999
Review Date: 03/06/2001
Multiple KIT Number: 0
Unit Of Issue: CY
Type Of Container: CYLINDER
Additional Data: PRODUCT IS AN ARTICLE UNDER OSHA. GROUND SHIPMENTS: NOT
REGULATED PER 49 CFR 173.159 (D). AIR SHIPME NTS: NOT REGULATED PER IATA,
SPECIAL PROVISION 4.4, A67. OCEAN SHIPMENTS: NOT REGULATED PER IMDG CODE-PAGE
8121. PACKAGING AND MARKINGS MUST BE IAW REGULATIONS.
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Detail DOT Information
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DOT PSN Code: XXX
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Detail IMO Information
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IMO PSN Code: XXX
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Detail IATA Information
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IATA PSN Code: XXX
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Detail AFI Information
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AFI PSN Code: DAB
AFI Proper Shipping Name: BATTERIES, WET, NON-SPILLABLE
AFI PSN Modifier: , ELECTRIC STORAGE
AFI Hazard Class: 8
AFI UN ID NUM: UN2800
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A12.5
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HAZCOM Label
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MSDS NAME: CAREFREE OR HE RECHARGEABLE BATTERY
Company: EAGLE-PICHER INDUSTRIES INC
Street: 14212 BETHEL ROAD
PO Box: 130
City: SENECA MO
Zipcode: 64865
Health Emergency Phone: 417-776-2256
Label Required IND: Y
Date Of Label Review: 03/06/2001
Status Code: A
Label Date: 03/06/2001
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: BATTERY IS AN ARTICLE UNDER OSHA. UNDER NORMAL USE IS
NON-HAZARDOUS. UNDER UNUSUAL CONDITIONS PERSON'S MAY BE EXPOSED TO TOXIC
LEAD, CORROSIVE SULFURIC ACID, EXPLOSIVE HYDROGEN. BURNS AND EYE DAMAGE
FROM SULFURIC ACID. FIRST AID: EYES: FLUSH WITH WATER. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND WATER.
GET MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. GET MEDICAL ATTENTION.
INGESTION: LEAD COMPOUNDS: GET MEDICAL ATTENTION. SULFURIC ACID: DO NOT
INDUCE VOMITING. GIVE WATER OR MILK FOLLOWED BY MILK OF MAGNESIA, BEATEN
EGGS, OR VEGETABLE OIL. GET MED ICAL ATTENTION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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