SIGMA COATINGS USA BV -- SIGMA EP MULTIGUARD HARDENER, 7461B
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Material Safety Data Sheet
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MSDS Num: CKZCK
MSDS NAME: SIGMA EP MULTIGUARD HARDENER, 7461B
Responsible Party
Name: SIGMA COATINGS USA BV
Address: 1401 DESTREHAN AVE
City: HARVEY LA 70058-2436
Info Phone: 504-347-4321
Emergency Phone Number: 504-347-4321
Preparer's Name: JAY FOLSE
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: SIGMA COATINGS USA BV
Address: 1401 DESTREHAN AVE
City: HARVEY LA 70058-2436
Phone: 504-347-4321
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: ORAL, RAT LD50: 1,030 MG/KG(ISOPHORONE)
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: THIS PRODUCT MAY CAUSE SKIN IRRITATION AND
DRYING/DEFATTING OR CRACKING AND DERMATITIS ON REPEATED OR PROLONGED EXPOSURE
TO THE SKIN. EYE CONTACT MAY RESULT IN LOSS OF VISION WITH SEVERE BURNS.
BASED ON THE PRESENCE OF TRIS-2,4,6-(DIMETHYLAMINOMETHYL) PHENOL, CONTACT
WITH THE EYES MAY CAUSE TRANSIENT CORNEAL DAMAGE, CONJUNCTIVAL IRRITATION AND
BURNS IF NOT PROMPTLY REMOVED. THIS PRODUCT, IF INGEST ED, MAY CAUSE
IRRITATION TO THE MEMBRANES OF THE MOUTH, THROAT AND GI TRACT WHICH THE
MATERIAL CONTACTS. BASED ON THE PRESENCE OF TRIS-2,4,6-(DIMETHYLAMINOMETHYL)
PHENOL THIS PRODUCT MAY CAUSE DRYING AND (SIGNS AND SYMPTOMS OF
OVEREXPOSURE)
Explanation Of Carcinogenicity: ETHYL BENZENE: IARC GROUP 2B, VOLUME 77, PAGE
277, 2000.
Signs And Symptions Of Overexposure: HEALTH HAZARDS ACUTE AND CHRONIC (CONT):
DEMATITIS ON REPEATED OR PROLONGED EXPOSURE TO THE SKIN. BASED ON THE
PRESENCE OF TRIS-2,4,6-(DIMETHYLAMINOMETHYL) PHENOL THIS PRODUCT IS CORROSIVE
TO THE EYE, SKIN, NOSE AND THROAT. THIS PRODUCT MAY CAUSE IRRITATION TO THE
UPPER RESPIRATORY TRACT. ANIMAL STUDIES HAVE SHOWN SOLVENTS TO CAUSE
FETOTOXIC EFFECTS AT OR NEAR MATERNALLY TOXIC LEVELS. THIS PRODUCT CAN BE
ABSORBED THROUGH THE SKIN CAUSING ORGAN DAMAGE. BASED ON THE PRESENCE OF
ISOPHORONE DIAMINE THIS PRODUCT MAY CAUSE SKIN IRRITATION. MAY CAUSE ALLERGIC
REACTION. EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND (OTHER
INFORMATION)
Medical Cond Aggravated By Exposure: ASTHMA, CHRONIC RESPIRATORY DISEASES, SKIN
DISORDERS AND ALLERGIES, EYE DISEASES. SKIN DISORDERS AND ALLERGIES:
DISORDERS OF THE SKIN, LUNGS, KIDNEYS, AUDITORY SYSTEM AND HEART DISORDERS.
First Aid: EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES. SEEK PHYSICIAN
IMMEDIATELY. SKIN CONTACT: FLUSH WITH COPIOUS AMOUNTS OF WATER. REMOVE
CONTAMINATED CLOTHING PROMPTLY. CONTACT A PHYSICIAN IMMEDIATELY. INH ALATION:
REMOVE EXPOSED INDIVIDUAL TO FRESH AIR. RESTORE BREATHING IF REQUIRED.
CONTACT A PHYSICIAN IMMEDIATELY. INGESTION: RINSE MOUTH IMMEDIATELY. GIVE
EXPOSED INDIVIDUAL 6 TO 8 OUNCES OF LIQUID. (N EVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON.) DO NOT INDUCE VOMITING UNLESS ADVISED BY A PHYSICIAN.
CONTACT A PHYSICIAN IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: STAY UPWIND AND AWAY FROM SPILL UNLESS WEARING
APPROPRIATE PROTECTIVE EQUIPMENT. STOP AND/OR CONTAIN DISCHARGE IF IT MAY BE
DONE SAFELY. KEEP ALL SOURCES OF IGNITION AWAY. VENTILATE AREA OF SPILL. USE
NON-SPARKING TOOLS FOR CLEANUP. COVER WITH INERT MATERIAL TO REDUCE FUMES.
KEEP OUT OF DRAINS, SEWERS, OR WATERWAYS. CONTACT FIRE AUTHORITIES. NOTIFY
LOCAL HEALTH AND POLLUTION (NEUTRALIZING AGENT)
Neutralizing Agent: N/P. SPILL RELEASE PROCEDURES (CONT): CONTROL
AGENCIES. CALL SPILL RESPONSE TEAMS IF LARGE SPILL.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE
AND LOCAL REGULATIONS (FP N).
Handling And Storage Precautions: AVOID CONTACT WITH EYES. WEAR GOGGLES IF
THERE IS A LIKELIHOOD OF CONTACT WITH EYES. USE VENTILATION AS REQUIRED TO
CONTROL VAPOR CONCENTRATION. AVOID PROLONGED OR REPEATED BREATHING OF VAPORS.
IF EXP OSURE EXCEEDS TLV, USE A NIOSH-APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE.
Other Precautions: AVOID INHALATION OF VAPORS AND CONTACT WITH PRODUCT. IF
CONTACT MADE, REMOVE CONTAMINATED CLOTHING, FLUSH AFFECTED SKIN AREA WITH
WATER. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINC E
EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLIDS),
ALL PRECAUTIONS IN MSDS MUST BE OBSERVED.
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Fire and Explosion Hazard Information
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Flash Point: =15.C, 59.F
Lower Limits: 1.00
Extinguishing Media: CO2, DRY CHEMICAL, FOAM, ALCOHOL FOAM, OR WATER FOG. WATER
SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO
PRVNT PRESSURE BUILDUP & AUTOIGNITION OR EXPLOSION
Fire Fighting Procedures: IF WATER USED, FOG NOZZLES ARE PREFERED. THIS LIQUID
AND VAPOR IS DANGEROUS FIRE HAZARD AND MODERATE EXPLOSION HAZARD WHEN EXPOSED
TO HEAT/FLAME. HEAVIER THAN AIR VAPORS CAN FLOW ALONG SURFACES TO DIS TANT
IGNITION SOURCES AND FLASH BACK. USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM
HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAME. CLOSED CONTAINER MAY EXPLODE
WHEN EXPOSED TO EXTREME HEAT. USE SPECIAL PRECAUTIONS TO APPLY TO HOT
SURFACES . DO NOT USE WELDING OR CUTTING TORCH ON OR NEAR CONTAINER (EVEN
EMPTY) BECAUSE LIQUID PRODUCT MAY IGNITE EXPLOSIVELY.
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Control Measures
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Respiratory Protection: IF EXPOSURE EXCEEDS TLV, USE A NIOSH APPROVED
RESPIRATOR TO PREVENT OVEREXPOSURE. IN OUTDOOR OR OPEN AREAS USE NIOSH
APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID AIRBORN PARTICLES OF
OVERSPRA Y DURING SPRAY APPLICATION. IN RESTRICTED VENTILATION AREAS USE
NIOSH APPROVED CHEMICAL-MECHANICAL FILTERS DESIGNED TO REMOVE A COMBINATION
(OTHER INFORMATION)
Ventilation: USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS
Protective Gloves: RESISTANT GLOVES SUCH AS NATURAL RUBBER, NEOPRENE, BUNA N OR
NITRILE.
Eye Protection: WEAR ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL FACESHIELD
(FP N).
Other Protective Equipment: GLOVES REQUIRED FOR PROLONGED OR REPEATED CONTACT.
AN APRON SHOULD BE WORN TO AVOID SKIN CONTACT. EYEWASH AND DELUGE SHOWER
MEETING ANSI DESIGN CRITERIA (FP N).
Work Hygienic Practices: AVOID CONTACT WITH EYES. AVOID PROLONGED OR REPEATED
BREATHING OF VAPORS. WASH HANDS THOROUGHLY BEFORE EATING AND USING WASHROOM.
Supplemental Safety and Health: NOTICE - REPORTS HAVE ASSOCIATED REPEATED AND
PROLONGED OCCUPATIONAL OVER EXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHA LING THE CONTENTS MAY BE HARMFUL OR FATAL.
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Physical/Chemical Properties
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Boiling Point: <107.8C, 226.F
B.P. Text: BOILING RANGE 226 TO 477F
Vapor Pres: 16.000
Vapor Density: 3.720
Spec Gravity: 1.0080 (8.3898 LB/GAL)
Evaporation Rate & Reference: 1.6400 (ETHER = 1)
Appearance and Odor: APPEARANCE: N/A. ODOR: N/A.
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Reactivity Data
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Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, ALKALI
METALS AND HALOGENS.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: ISOPHORONE DIAMINE: LD50: 1030 MG/KG (ORAL/RAT),
LC50: NOT AVAILABLE. NONYPHENOL: LD50: 1.62 G/KG (ORAL/RAT), LC50: OVER 2
MG/ LITER. PROPRIETARY AMINE ADDUCT: LD50: NOT ESTABLISHED, LC50: NOT ESTAB
LISHED. TRIS-2,4,6-(DIMETHYLAMINOMETHYL) PHENOL: LD50: 2169 MG/KG
(ORAL/RAT), LC50: NOT ESTABLISHED. XYLENE: LD50: 4300 MG/KG (ORAL/RAT), 2
ML/KG (DERMAL/RABBIT); LC50: TC (LOW) = 200 PPM (HUMAN TOX IC EFFECTS).
ETHYL BENZENE: LD50: 3500 MG/KG (ORAL/RAT), LC50: TC (LOW) = 100 PPM/4 HOURS
(HUMAN). METHYL ISOBUTYL KETONE: LD50: 2.08 G/KG (ORAL/RAT), LC50: 4000 PPM
- 4 HOURS/RAT. (ECOLOGICAL INFOR MATION)
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Ecological Information
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Ecological: N/P. TOXICOLOGICAL INFORMATION (CONT): ISOBUTYL ALCOHOL:
LD50: 2.46 MG/KG (ORAL/RAT), LC50: NOT AVAILABLE. BENZYL ALCOHOL: LD50: 1230
MG/KG (ORAL/RAT), LC50: 1000 PPM. PHYSICAL / CH EMICAL PROPERTIES
(CONT): XYLENE: LEL 1.00. ETHYL BENZENE: LEL1.00. METHYL ISOBUTYL KETONE:
LEL 1.40. ISOBUTYL ALCOHOL: 1.70. BENZYL ALCOHOL: LEL1.30. ODOR THRESHOLD:
N/A. COEFFICIENT OF WATER / OIL DISTRIBUTION: N/A. SENSITIVITY TO
EXPLOSION BY IMPACT: N/A. SENSITIVITY TO EXPLOSION BY STATIC ELECTRICITY:
N/A.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: SARA 313 INFORMATION: THIS PRODUCT CONTAINS THE
FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
TITLE I I I OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND
40 CFR PART 372: XYLENE, CASN: 1330-20-7, PCT BY WT: 12.9660. ETHYL BENZENE,
CASN: 100-41-4, PCT BY WT: 2.8960. METHYL ISOBUTYL KETONE, CASN: 108-10-1,
PCT BY WT: 5.5000.
Federal Regulatory Information: THIS SUBSTANCE IS CLASSIFIED AS A HAZARDOUS AUR
POLLUTANT. BASED ON THE PRESENCE OF COMPONENTS (METHYL ISOBUTYL KETONE,
ISOBUTYL ALCOHOL) YOU MAY BE REQUIRED UNDER THE COMPREHENSIVE ENVIRONMENTAL
RES PONSE, COMPENSATION, AND LIABILITY ACT OF 1980 (CERCLA) TO NOTIFY THE
NATIONAL RESPONSE CENTER OF RELEASES OF QUANTITIES OF THESE CHEMICALS EQUAL
TO OR GREATER THAN THE REPORTABLE QUANTITIES (RQ'S) LI STED IN 40 CFR 302.4.
REFER TO 40 CFR 302.4 FOR DETAILS ON REPORTING REQUIREMENTS.
State Regulatory Information: CALIFORNIA PROPOSITION 65: REQUIRES MANUFACTURERS
TO WARN USERS OF THE PRESENCE OF CHEMICALS WICH MAY CAUSE A "SIGNIFICANT
RISK". BASED UPON THE POSSIBILITY OF THE PRESENCE OF MINUTE AMOUNTS OF CONTAM
INANTS IN ANY PAINT, SIGMA COATINGS GIVES THE FOLLOWING WARNINGS: WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER. WARNING: THIS PRODUCT CONTAINS A CHEMICA L KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
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Other Information
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Other Information: USE: PROTECTIVE COATING. SIGNS AND SYMPTOMS OF
OVEREXPOSURE (CONT): RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE,
NAUSEA, HEADACHE, POSSIBLE UNCONSCIOUSNESS, AND EVEN ASPHYXIATION. ROU TE OF
ENTRY: SKIN CONTACT, SKIN ABSORPTION, EYE CONTACT, INHALATION.
RESPIRATORY PROTECTION (CONT): OF PARTICULATE AND GAS AND VAPOR. IN CONFINED
AREAS USE NIOSH APPROVEDAIR LINE RESPIRATORS O R HOODS. RESPIRATORY
PROTECTION MAY ALSO BE NECESSARY IN ANY LATER MANUFACTURING OPERATIONS IN
WHICH THE PRODUCT MAY BECOME AIRBORNE IN THE FORM OF VAPOR OR DUST.
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HAZCOM Label
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MSDS NAME: SIGMA EP MULTIGUARD HARDENER, 7461B
Company: SIGMA COATINGS USA BV
Street: 1401 DESTREHAN AVE
City: HARVEY LA
Zipcode: 70058-2436
Health Emergency Phone: 504-347-4321
Label Required IND: Y
Date Of Label Review: 02/27/2001
Status Code: A
Label Date: 12/15/2000
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE! ACUTE: EYES: PRODUCT IS CORROSIVE TO EYES.
CONTACT MAY RESULT IN LOSS OF VISION WITH SEVERE BURNS. SKIN: PRODUCT IS
CORROSIVE TO ALL TISSUES; CAN BE ABSORBED THROUGH SKIN CAUSING ORGAN DAMA GE;
MAY CAUSE ALLERGIC REACTION. INHALATION: MAY CAUSE NASAL AND RESPIRATORY
IRRITATION, DIZZINESS, UNCONSCIOUSNESS, ASPHYXIATION. INGESTION: MAY CAUSE
MEMBRANE IRRITATION OF THE MOUTH, THROAT, AND GI TRACT. CHRONIC: MAY CAUSE
DERMATITIS, BURNS TO EYES AND SKIN , CORNEAL DAMAGE,ORGAN DAMAGE, ALLERGIC
REACTIONS, LOSS OF VISION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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