KOLENE CORPORATION -- KOLENE NO. 1
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Material Safety Data Sheet
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NIIN: 01-151-7070
MSDS Num: CKZLN
MSDS NAME: KOLENE NO. 1
Responsible Party
Name: KOLENE CORPORATION
Address: 12890 WESTWOOD AVENUE
City: DETROIT MI 48223
Info Phone: 800-521-4182, 313-273-9220
Emergency Phone Number: 313-273-9220
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: KOLENE CORPORATION
Address: 12890 WESTWOOD AVENUE
City: DETROIT MI 48223
Phone: 800-521-4182, 313-273-9220
Contract Number: SP0411-01-M-E663
Name: KOLENE CORPORATION
Address: 12890 WESTWOOD AVENUE
City: DETROIT MI 48223
Phone: 800-521-4182, 313-273-9220
Contract Number: SP0450-01-M-D497
Name: KOLENE CORPORATION
Address: 12890 WESTWOOD AVENUE
City: DETROIT MI 48223
Phone: 800-521-4182, 313-273-9220
Contract Number: SPO450-01-M-D782
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Item Description Information
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Item Manager: S9G
Item Name: STRIPPING COMPOUND,MOLTEN SALT
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: DR
Quantitative Expression: 00000000500LB
UI Container Qty: 0
Type of Container: DRUM
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: ACUTE ORAL LD50: 140-340 MG/KG (RAT)
Effects of Exposure: ACUTE: EYE CONTACT: DESTRUCTIVE TO EYE TISSUE. CAUSES
SEVERE BURNS THAT MAY RESULT IN DAMAGE TO EYES AND EVEN BLINDNESS. SKIN
CONTACT: DESTRUCTIVE TO TISSUES CONTACTED AND MAY PRODUCE SEVERE BURNS. IN
GESTION: SWALLOWING CAN CAUSE SEVERE BURNS AND DAMAGE TO MUCOUS MEMBRANES OF
MOUTH, THROAT, AND STOMACH. INHALATION: AIRBORNE CONCENTRATIONS OF DUST,
MIST, OR SPRAY CAN CAUSE DAMAGE TO THE UPPER RESPI RATORY TRACT AND POSSIBLE
LUNG DAMAGE. CHRONIC: EFFECT OF LONG TERM LOW LEVEL EXPOSURE NOT DETERMINED.
SAFE HANDLING OF THIS MATERIAL ON A LONG TERM BASIS SHOULD EMPHASIZE
AVOIDANCE OF EXPOSURE.
Explanation Of Carcinogenicity: NONE PROVIDED BY MANUFACTURER.
Signs And Symptions Of Overexposure: EYE CONTACT: EYE TISSUE DESTRUCTION,
SEVERE BURNS TO EYES AND BLINDNESS. SKIN CONTACT: TISSUE DESTRUCTION AND
SEVERE BURNS. INGESTION: SEVERE BURNS AND DAMAGE TO MUSOUS MEMBRANES OF
MOUTH, THROAT, AND STOMACH. INHALATION: DAMAGE TO UPPER RESPIRATORY TRACT,
LUNG DAMAGE.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE OR SKIN CONTACT: PRODUCT CONTAINS CAUSTIC ALKALIS. IMMEDIATELY
FLUSH WITH LARGE AMOUNTS OF WATER (FOR AT LEAST 15 MINUTES WITH EYELIDS OPEN
IN CASE OF EYE EXPOSURE). CALL A PHYSICIAN. REMOVE CONTA MINATED CLOTHING FOR
CLEANING PRIOR TO REUSE. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH
THIS MATERIAL. INHALATION: MOVE PERSON TO FRESH AIR, PROVIDE ARTIFICAL
RESPIRATION AND OXYGEN IF NECE SSARY. SEEK MEDICAL ATTENTION. INGESTION: IF
CONSCIOUS, DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER. NEVER
GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. SEEK MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: IN CASE OF ACCIDENTIAL SPILL OR LEAK,SHOVEL MATERIAL
INTO STEEL CONTAINERS FOR PROPER DISPOSAL. SAFE HANDLING PRACTICES AND
PROTECTIVE EQUIPMENT SHOULD BE USED. AREA OF SPILL SHOULD BE FLUSHED WITH WA
TER TO REMOVE NON-VISIBLE RESIDUES. FOLLOW NORMAL DISPOSAL PRACTICE WITH
RINSE WATER ACCORDING TO FEDERAL, STATE, AND LOCAL REGULATIONS.
Neutralizing Agent: NONE PROVIDED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF WASTE IN ACCORDANCE WITH FEDERAL, STATE, AND
LOCAL REGULATIONS. IF DISCARDED AS SUPPLIED, THIS MATERIAL HAS THE
CHARACTERISTICS OF A CORROSIVE (D002). SPENT SALTS OR OTHER BY-PRODUCTS FROM
THIS MATERIALS USE MAY HAVE OTHER HAZARDOUS CHARACTERISTICS DEPENDENT ON
SPECIFIC PRODUCT USE.
Handling And Storage Precautions: KOLENE NO. 1 SALT SHOULD BE STORED IN COOL,
DRY, SECURE AREA AWAY FROM ACIDS. PARTIALLY FULL DRUMS SHOULD BE RESEALED
TIGHTLY BEFORE STORING TO PREVENT ABSORPTION OF MOISTURE FROM AIR. NEVER ADD
WATER OR OTHER LIQUIDS INTO MOLTEN SALT BATH AS ELEVATED TEMP. MAY CAUSE
VIOLENT GAS AND SALT ERUPTIONS.
Other Precautions: AS RECEIVED KOLENE NO. 1 CONTAINS CAUSTIC COMPOUNDS, WHICH
ARE CORROSIVE TO THE SKIN. ALL PERSONS HANDLING THIS PRODUCT SHOULD BE
CAUTIONED OF ITS HAZARDS. PERSONAL PROTECTION EQUIPMENT SHOULD BE USED AT
ALL TIMES. USE OF THIS PRODUCT REQUIRES HEATING FROM 315C (600F) TO 538C
(1000F) IN (CONTD. SEE "ECOLOGICAL INFO")
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Fire and Explosion Hazard Information
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Flash Point Text: NONFLAMMABLE.
Extinguishing Media: USE WATER, CO2, DRY CHEMICALS TO FIGHT FIRES IN STORAGE
AREAS. DO NOT USE WATER IN VICINITY OF MOLTEN SALT BATH. DIRECT WATER CONTACT
MAY CAUSE VIOLENT EXOTHERMIC REACTION.
Fire Fighting Procedures: MIXTURE IS NONFLAMMABLE. WILL NOT BURN, SINCE IT
CONTAINS AN OXIDIZER, IT CAN SUPPORT COMBUSTION UNDER CERTAIN CIRCUMSTANCES.
DIRECT CONTACT OF THIS PRODUCT WITH WATER MAY CAUSE A VIOLENT EXOTHERMIC
REACTION AND RESULT IN CAUSTIC LIQUID GENERATION. NORTH AMERICAN EMERGENCY
RESPONSE GUIDE NO. 154. (DOT ERG NO. 60.)
Unusual Fire/Explosion Hazard: PRODUCT MAY PRODUCE OXIDES OF NITROGEN AND
CARBON WHEN EXPOSED TO EXTREME HEAT, THEREFORE INHALATION SHOULD BE AVOIDED.
MATERIAL IS NON-EXPLOSIVE IN NORMAL USE AND STORAGE. MIXING OF PRODUCT WITH
STRO NG REDUCING AND ORGANICS COULD PRODUCE VIOLENT REACTIONS. SEE REACTIVITY
DATA.
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Control Measures
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Respiratory Protection: NOT REQUIRED UNDER NORMAL USE. (USE NIOSH APPROVED
RESPIRATOR WHERE DUST, MIST, OR SPRAY MAY BE GENERATED).
Ventilation: NONE PROVIDED BY MFR.
Protective Gloves: GLOVES FOR HANDLING CORROSIVE MATERIAL SHOULD BE WORN.
Eye Protection: FACE SHIELD AND GOGGLES SHOULD BE WORN.
Other Protective Equipment: SAFETY SHOES OR RUBBER BOOTS, CLOTHING FITTED TO
AVOID AREAS OF SKIN EXPOSURE OR RESIDUE RETENTION. SAFETY SHOWERS AND EYEWASH
STATIONS SHOULD BE AVAILABLE IN WORK AREAS.
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Physical/Chemical Properties
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HCC: B1
Boiling Point: =1390.C, 2534.F
Melt/Freeze Pt: =248.9C, 480.F
Spec Gravity: 2 G/CC @ 20C (H2O=1)
PH: H2O SOL: BASIC.
Solubility in Water: COMPLETELY SOLUBLE
Appearance and Odor: LIGHT COLORED, FREE FLOWING GRANULAR SOLID, NO ODOR.
Percent Volatiles by Volume: NOT VOLATILE
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: STABLE UNDER NORMAL CONDITIONS.
Materials To Avoid: AVOID DIRECT CONTACT WITH WATER, ORGANIC MATERIALS,
CONCENTRATED ACIDS, REDUCING AGENTS, MAGNESIUM, TIN, ZINC, ALUMINUM, AND
ALLOYS OF THESE METALS. AVOID UNCONTROLLED OR EXCESSIVE INTRODUCTION OF
ORGANIC MATERIALS.
Hazardous Decomposition Products: UNDER CONDITIONS OF EXTREME HEAT [GREATER
THAN 704 DEG C (1300 DEG F)] THIS PRODUCT MAY MAY PRODUCE NITROGEN OXIDES.
Conditions To Avoid Polymerization: NONE PROVIDED BY MFR.
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Toxicological Information
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Toxicological Information: PRODUCT CONTAINS ALKALI HDROXIDES AND ALKALI
NITRATES. THE EXACT CHEMICAL RANGE OF COMPOUNDS IN THIS PRODUCT IS CLASSIFIED
AS A TRADE SECRET. HOWEVER, THE PHYSICAL DATA, FIRE AND EXPLOSION DATA, HEALT
H HAZARD INFORMATION, REACTIVITY, SPILL PROCEDURES, INDUSTRIAL HYGIENE
MEASURES AND OTHER PRECAUTIONS REPRESENT A COMPOSITE OF ALL RELATED CHEMICAL
HAZARDS. ACUTE ORAL, RAT LD50: 140-340 MG/KG; ACUTE DERMAL, RABBIT LD50:
1.35 G/KG. PERMISSIBLE EXPOSURE LIMITS: 2 MG/M3-8 HOUR (TIME WEIGHTED
AVERAGE).
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Ecological Information
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Ecological: (CONTD. FROM "OTHER PRECAUTIONS") SPECIALIZED EQUIPMENT. AS WITH
ANY HIGH TEMPERATURE PROCESS, PROPER TRAINING, SAFETY EQUIPMENT, AND
PRECAUTIONS ARE MANDATORY. OPERATING PERSONNEL SHOULD BE PROVIDED WITH FACE
SHIELDS AND HEAT RESISTANT GLOVES, NOT RUBBER OR PLASTIC COATED. SEALED
CONTAINERS, FABRICATED ASSEMBLIES, OR OTHER ITEMS WHICH CONTAIN CONFINED AIR
OR LIQUIDS SHOULD NOT BE IMMERSED IN THE MOLTEN SALT BECAUSE OF POSSIBLE
EXPLOSION HAZARDS RESULTING FROM INTERNAL PRESSURE BUILDUP.
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MSDS Transport Information
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Transport Information: DOT CLASSIFICATION: PROPER SHIPPING NAME: CORROSIVE
SOLIDS. N.O.S. (SODIUM HYDROXIDE),CLASS: 8, UN 1759, PG I I.
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Regulatory Information
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Sara Title III Information: PRODUCT IS A PROPRIETY PRODUCT CONTAINING NITRATE
COMPOUNDS. ONLY NITRATES PRESENT IN AQUEOUS SOLUTIONS ARE REPORTABLE.
REPORTABLE PERSENTAGE IN RINSE WATERS WILL VARY DEPENDING ON SPECIFIC
APPLICATIO NS AND OPERATING CONDITIONS. THIS PRODUCT ALSO CONTAINS DRY ALKALI
HYDROXIDES AT 59% (MAX). WHICH MAY REQUIRE REPORTING UNDER SECTIONS OF THIS
REGULATION.
Federal Regulatory Information: CERCLA INFORMATION: THE REPORTABLE QUANTITY
(RQ) FOR RELEASES OF THIS MIXED PRODUCT UNDER THE ABOVE ACT IS 1695 LBS.
BASED ON THE WEIGHT PERCENT OF THE HAZARDOUS COMPONENT PRESENT. RCRA
INFORMATION: IF DISCARDED AS SUPPLIED, THIS MATERIAL HAS THE
CHARACTERISTICS OF A CORROSIVE (D002). SPENT SALTS OR OTHER BY-PRODUCTS FROM
THIS MATERIALS USE MAY HAVE OTHER HAZARDOUS CHARACTERISTICS DEPENDENT ON S
PECIFIC PRODUCT USE.
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Other Information
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Other Information: EQUIPMENT AND OPERATIONS: ONLY EQUIPMENT SPECIFICALLY
ENGINEERED FOR MOLTEN SALTS SHOULD BE CONSIDERED FOR CONTAINING AND OPERATING
THIS PRODUCT. NORMAL OPERATING TEMPERATURES RANGE FROM 371C (700F) T O 538C
(1000F). REQUIRED TREATMENT TIMES VARY FROM A FEW SECONDS TO SEVERAL MINUTES,
DEPENDING ON THE SCALE SEVERITY.
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Transportation Information
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Trans ID NO: 156155
MSDS NAME: KOLENE NO. 1
MSDS Prepared Date: 08/30/2000
Review Date: 03/07/2001
Tech Entry NOS Shipping Nm: (SODIUM HYDROXIDE)
Net Unit Weight: 500 LBS
Multiple KIT Number: 0
Unit Of Issue: DR
Container QTY: 0
Type Of Container: DRUM
Additional Data: TRANSPORTATION DATA PER MANUFACTURER'S MSDS.
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Detail DOT Information
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DOT PSN Code: DWZ
Symbols: G
DOT Proper Shipping Name: CORROSIVE SOLIDS, N.O.S.
Hazard Class: 8
UN ID Num: UN1759
DOT Packaging Group: II
Label: CORROSIVE
Packaging Exception: 154
Non Bulk Pack: 212
Bulk Pack: 240
Max Qty Pass: 15 KG
Max Qty Cargo: 50 KG
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: ESJ
IMO Proper Shipping Name: CORROSIVE SOLID, N.O.S. o
IMDG Page Number: 8151
UN Number: 1759
UN Hazard Class: 8
IMO Packaging Group: I/II/III
Subsidiary Risk Label: -
EMS Number: 8-15
MED First Aid Guide NUM: 760
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Detail IATA Information
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IATA PSN Code: HMF
IATA UN ID Num: 1759
IATA Proper Shipping Name: CORROSIVE SOLID, N.O.S. *
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: II
Packing Note Passenger: 814
Max Quant Pass: 15KG
Max Quant Cargo: 50KG
Packaging Note Cargo: 816
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Detail AFI Information
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AFI PSN Code: HMF
AFI Symbols: *
AFI Proper Shipping Name: CORROSIVE SOLID, N.O.S.
AFI Hazard Class: 8
AFI UN ID NUM: UN1759
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A12.4
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HAZCOM Label
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MSDS NAME: KOLENE NO. 1
Company: KOLENE CORPORATION
Street: 12890 WESTWOOD AVENUE
City: DETROIT MI
Zipcode: 48223
Health Emergency Phone: 313-273-9220
Label Required IND: Y
Date Of Label Review: 03/07/2001
Status Code: A
Label Date: 03/07/2001
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: NO
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYE CONTACT: DESTRUCTIVE TO EYE TISSUE. CAUSES
SEVERE BURNS THAT MAY RESULT IN DAMAGE TO EYES AND EVEN BLINDNESS. SKIN
CONTACT: DESTRUCTIVE TO TISSUES CONTACTED AND MAY PRODUCE SEVERE BURNS. IN
GESTION: SWALLOWING CAN CAUSE SEVERE BURNS AND DAMAGE TO MUCOUS MEMBRANES OF
MOUTH, THROAT, AND STOMACH. INHALATION: AIRBORNE CONCENTRATIONS OF DUST,
MIST, OR SPRAY CAN CAUSE DAMAGE TO THE UPPER RESPI RATORY TRACT AND POSSIBLE
LUNG DAMAGE. CHRONIC: EFFECT OF LONG TERM LOW LEVEL EXPOSURE NOT DETERMINED.
SAFE HANDLING OF THIS MATERIAL ON A LONG TERM BASIS SHOULD EMPHASIZE
AVOIDANCE OF EXPOSURE.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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