PITT PENN OIL CO -- PITT PENN PREMIUM HEAVY DUTY MILITARY ANTIFRE
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Material Safety Data Sheet
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NIIN: 01-464-9137
MSDS Num: CKZPD
MSDS NAME: PITT PENN PREMIUM HEAVY DUTY MILITARY ANTIFREEZE
Responsible Party
Name: PITT PENN OIL CO
Address: 426 FREEPORT RD
Box: 296
City: CREIGHTON PA 15030-0296
Info Phone: 724-226-2712
Emergency Phone Number: 1-800-255-3924 (CHEM TEL)
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Item Description Information
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Item Manager: S9G
Item Name: ANTIFREEZE
Specification Number: A-A-52624
Type/Grade/Class: TY I, RECYCLED
Unit of Issue: CO
Quantitative Expression: 00000000005GL
UI Container Qty: 1
Type of Container: CONTAINER
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: ORAL RAT LD50: 4.7-8.5 G/KG
Effects of Exposure: EYES: BELIEVED TO CAUSE SLIGHT EYE IRRITATION. SKIN:
BELIEVED TO BE SLIGHTLY IRRITATING UPON PROLONGED CONTACT. RESPIRATORY
SYSTEM: DROWSINESS, NARCOSIS, AND UNCONSCIOUSNESS POSSIBLE UPON EXPOSURE TO
HIGH CONCENTRATIONS IN POORLY VENTILATED CONFINED SPACES. CHRONIC: LIVER AND
KIDNEY DAMAGE IN A 2 YEAR RAT FEEDING STUDY USING 1-2% ETHYLENE GLYCOL. ORAL
ADMINISTRATION OF VERY HIGH DOSES OF ETHYLENE GLYCOL PRODUCED BIRTH DEFECTS
IN LABORATORY ANIMALS. SENSITIZATION PROPERTIES: SKIN: UNKNOWN. RESPIRATORY:
UNKNOWN.
Signs And Symptions Of Overexposure: EYES: IRRITATION. SKIN: IRRITATION.
RESPIRATORY SYSTEM: DROWSINESS, NARCOSIS, AND UNCONSCIOUSNESS. INGESTION:
BASED ON ANIMAL STUDIES: LIVER AND KIDNEY DAMAGE, BIRTH DEFECTS.
Medical Cond Aggravated By Exposure: NOT PROVIDED.
First Aid: EYES: IMMEDIATELY FLUSH WITH LARGE QUANTITIES OF WATER FOR AT LEAST
15 MINUTES AND CALL A PHYSICIAN. SKIN CONTACT: REMOVE EXCESS WITH CLOTH OR
PAPER TOWEL. WASH THOROUGHLY WITH SOAP AND WATER. IF IRRI TATION PERSISTS,
GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. RESTORE AND/OR
SUPPORT BREATHING AS REQUIRED. KEEP VICTIM WARM AND AT REST. SWALLOWED:
IMMEDIATELY CONTACT A PHYSICIAN, POISON CONTROL CENTER OR EMERGENCY
TREATMENT CENTER. DO NOT INDUCE VOMITING! ASPIRATION HAZARD: PRODUCT MAY BE
INHALED INTO LUNGS IF VOMITED.
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Handling and Disposal
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Spill Release Procedures: CONTAIN SPILL IF POSSIBLE. WIPE UP OR ABSORB ON
SUITABLE MATERIAL AND SHOVEL UP. EMERGENCY TELEPHONE NUMBER-CHEM TEL, INC.:
1-800-255-3924.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: UNDER RCRA, IT IS THE RESPONSIBILITY OF THE USER OF
PRODUCTS TO DETERMINE, AT THE TIME OF DISPOSAL, WHETHER PRODUCT MEETS RCRA
CRITERIA FOR HAZARDOUS WASTE. THIS IS BECAUSE PRODUCT USES TRANSFORMATION S,
MIXTURE, PROCESSES, ETC., MAY RENDER THE RESULTING MATERIAL HAZARDOUS.
DISPOSE OF WASTE IN ACCORD ANCE WITH FEDERAL, STATE, AND LOCAL LAWS.
Handling And Storage Precautions: MINIMUM FEASIBLE HANDLING TEMPERATURE SHOULD
BE MAINTAINED. PERIODS OF EXPOSURE TO HIGH TEMPERATURE SHOULD BE MINIMIZED.
WATER CONTAMINATION SHOULD BE AVOIDED.
Other Precautions: HARMFUL OR FATAL IF SWALLOWED. KEEP OUT OF REACH OF
CHILDREN. MAY CAUSE IRRITATION TO EYES. DO NOT DRINK ANTIFREEZE OR SOLUTION.
AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER HANDLING. DO NOT STORE I N
OPEN OR UNLABELED CONTAINERS. ETHYLENE GLYCOL HAS PRODUCED BIRTH DEFECTS IN
RODENTS. DO NOT STORE NEAR FOOD.
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Fire and Explosion Hazard Information
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Flash Point Method: COC
Flash Point: >128.C, 262.4F
Autoignition Temp: >413.C, 775.4F
Lower Limits: 3.2
Upper Limits: 15.3
Extinguishing Media: USE WATER SPRAY, DRY CHEMICAL, FOAM OR CARBON DIOXIDE.
Fire Fighting Procedures: ACCORDING TO THE NATIONAL FIRE PROTECTION ASSOCIATION
GUIDE, USE WATER SPRAY, DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER OR FOAM
MAY CAUSE FROTHING. USE WATER SPRAY TO DISPERSE THE VAPORS AND TO PROV IDE
PROTECTION FOR PERSON ATTEMPTING TO STOP THE LEAK.
Unusual Fire/Explosion Hazard: PRODUCTS EVOLVED WHEN SUBJECTED TO HEAT OR
COMBUSTION: CARBON MONOXIDE AND CARBON DIOXIDE MAY BE FORMED ON BURNING IN
LIMITED AIR SUPPLY.
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Control Measures
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Respiratory Protection: SUPPLIED AIR RESPIRATORY PROTECTION FOR CLEANING LARGE
SPILLS OR UPON ENTRY INTO TANKS, VESSELS, OR OTHER CONFINED SPACES.
Ventilation: NORMAL TO MAINTAIN EXPOSURE BELOW TLV.
Eye Protection: CHEMICAL TYPE GOGGLES OR FACE SHIELD OPTIONAL.
Work Hygienic Practices: EXPOSED EMPLOYEES SHOULD EXERCISE PERSONAL
CLEANLINESS; INCLUDING CLEANSING EXPOSED SKIN SEVERAL TIMES DAILY WITH SOAP
AND WATER, AND LAUNDERING OR DRY CLEANING SOILED WORK CLOTHING AT LEAST
WEEKLY.
Supplemental Safety and Health: PID DATA, RECYCLED 50% RECYCLED CONCENTRATE
ANTIFREEZE: A MINIMUM OF 50% OF THE ETHYLENE GLYCOL USED IN PRODUCING THE
ANTIFREEZE SHALL HAVE BEEN RECYCLED AT A PERMITTED RCRA FACILITY BY MEANS OF
FRACT IONAL DISTILLATION, ION EXCHANGE, OR REVERSE OSMOSIS (FP D).
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Physical/Chemical Properties
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HCC: V5
NRC/State LIC No: NOT RELEVANT
Boiling Point: =166.C, 330.8F
M.P/F.P Text: NOT PROVIDED
Decomp Temp: >412.8C, 775.F
Vapor Pres: 18 MMHG @ 68F/20C
Vapor Density: 2.14(AIR=1
Spec Gravity: 1.125 (H2O=1)
PH: (NEAT) 10-11
Evaporation Rate & Reference: NOT DETERMINED
Solubility in Water: SOLUBLE
Appearance and Odor: PID DATA: REQUIRED COLOR IS GREEN TO BLUE-GREEN LIQUID (FP
D).
Percent Volatiles by Volume: NIL
Corrosion Rate: NOT PROVIDED
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES ABOVE 413C (775F) (PRODUCT CAN
DECOMPOSE).
Materials To Avoid: MATERIAL REACTS VIOLENTY WITH STRONG OXIDIZERS,
Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE MAY BE
FORMED ON BURNING IN LIMITED AIR SUPPLY.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: DO NOT OCCUR.
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Toxicological Information
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Toxicological Information: MEDIAN LETHAL DOSE: (LD50 LC50 X SPECIES): ORAL:
BELIEVED TO BE 4.7-8.5 G/KG (RAT); MODERATELY TOXIC. INHALATION: NOT
DETERMINED. DERMAL: BELIEVED TO BE 1-3 G/KG (RABBIT); SLIGHTLY TOXIC. OTHER:
NOT D ETERMINED. IRRITATION INDEX/ ESTIMATION OF IRRITATION (SPECIES): SKIN:
BELIEVED TO BE 0.5-1.8/ 8.0 (RABBIT); SLIGHTLY IRRITATING. EYES: BELIEVED TO
BE 15-25/ 110 (RABBIT); SLIGHTLY IRRITATING. PERMISS IBLE CONCENTRATIONS IN
AIR: 10 MG/M3 FOR PARTICULATE MIST; 50 PPM (125 MG/ M3) CEILING LIMIT FOR
ETHYLENE GLYCOL (ACGIH 1984-1985).
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: SARA 313: CONTAINS FOLLOWING SUBSTANCE WHICH IS
LISTED IN TITLE I I I: ETHYLENE GLYCOL. SARA HAZARD CATEGORY: AN IMMEDIATE
HEALTH HAZARD. A DELAYED HEALTH HAZARD.
Federal Regulatory Information: ALL COMPONENTS LISTED ON BOTH TSCA (USA) AND
DSL (CANADA) INVENTORY. 1,2-ETHANEDIOL (ETHYLENE GLYCOL), CAS# 107-21-1 IS
HAZARDOUS ACCORDING TO OSHA (1910.1200).
State Regulatory Information: 1,2-ETHANEDIOL (ETHYLENE GLYCOL) HAZARDOUS
ACCORDING TO ONE OR MORE STATE RIGHT-TO-KNOW LIST SPECIFIC.
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Other Information
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Other Information: NONE
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Transportation Information
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Trans ID NO: 156200
MSDS NAME: PITT PENN PREMIUM HEAVY DUTY MILITARY ANTIFREEZE
MSDS Prepared Date: 04/23/2000
Review Date: 03/13/2001
Net Unit Weight: 46.9 LB
Multiple KIT Number: 0
Unit Of Issue: CO
Container QTY: 1
Type Of Container: CONTAINER
Additional Data: TRANSPORTATION DATA PER MANUFACTURER'S MSDS.
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: PITT PENN PREMIUM HEAVY DUTY MILITARY ANTIFREEZE
Company: PITT PENN OIL CO
Street: 426 FREEPORT RD
PO Box: 296
City: CREIGHTON PA
Zipcode: 15030-0296
Health Emergency Phone: 1-800-255-3924 (CHEM TEL)
Label Required IND: Y
Date Of Label Review: 03/13/2001
Status Code: A
Label Date: 03/13/2001
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: EYES: SLIGHT IRRITATION. SKIN: SLIGHTLY IRRITATING.
INHALATION: MAY CAUSE DROWSINESS, NARCOSIS, AND UNCONSCIOUSNESS AT HIGH
CONCENTRATIONS IN POORLY VENTILATED SPACES. INGESTION: ANIMAL STUDIES INDICA
TE LIVER AND KIDNEY DAMAGE AND FOR VERYHIGH DOSES BIRTH DEFECTS IN LABORATORY
ANIMALS. FIRST AID: EYES: FLUSH WELL WITH WATER. GET MEDICAL ATTENTION. SKIN:
REMOVE EXCESS, THEN WASH WITH SOAP AND WATER . IF IRRITATION PERSISTS, GET
MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. RESTORE AND/ OR SUPPORT
BREATHING AS REQUIRED. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL
ATTENTION. DO NOT INDUCE VO MITING.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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