calcium carbonate treated with stearic acid. (no mfr cas# provided. amorphous fumed silica. (observe particulate limits. osha pel: twa 15 methyltrimethoxysilane. (dow corning guide: twa 50 ppm. also see methyl
DOW CORNING CORPORATION -- DOW CORNING 795 SILICONE BUILDING SEALANT, GR
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CLHBW
MSDS NAME: DOW CORNING 795 SILICONE BUILDING SEALANT, GRAY
Responsible Party
Name: DOW CORNING CORPORATION
Address: SOUTH SAGINAW ROAD
City: MIDLAND MI 48686
Info Phone: 517-496-6000/517-496-5900
Emergency Phone Number: 517-496-5900
Resp. Party Other MSDS No.: 1595725
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: DOW CORNING CORP
Address: 2200 W SALZBURG RD
City: AUBURN MI 48611
Phone: 517-496-4388
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Ingredients
=======================================================
Name: CALCIUM CARBONATE TREATED WITH STEARIC ACID. (NO MFR CAS# PROVIDED.
OBSERVE CALCIUM CARBONATE LIMITS. OSHA PEL: TWA 15 MG/M3 RESPIRABLE FRACTION.
)
% low Wt: 40.
% high Wt: 70.
OSHA PEL: SEE TOXICOLOGICAL
ACGIH TLV: TWA 10 MG/M3
-----------------------------
Cas: 112945-52-5
RTECS #: VV7310000
Name: AMORPHOUS FUMED SILICA. (OBSERVE PARTICULATE LIMITS. OSHA PEL: TWA 15
MG/M3 TOTAL DUST, 5 MG/M3 RESPIRABLE FRACTION. ACGIH TLV: TWA 10 MG/M3
INHALABLE PARTICULATE, 3 MG/M3 RESPIRABLE PARTICULATE.)
% low Wt: 3.
% high Wt: 7.
OSHA PEL: SEE TOXICOLOGICAL
ACGIH TLV: SEE TOXICOLOGICAL
------------------------------
Cas: 1185-55-3
RTECS #: VV4650000
Name: METHYLTRIMETHOXYSILANE. (DOW CORNING GUIDE: TWA 50 PPM. ALSO SEE METHYL
ALCOHOL COMMENTS IN TOXICOLOGICAL)
% low Wt: 1.
% high Wt: 5.
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE EFFECTS. EYE: DIRECT CONTACT MAY CAUSE MILD
IRRITATION. SKIN: NO SIGNIFICANT IRRITATION EXPECTED FROM A SINGLE SHORT-TERM
EXPOSURE. INHALATION: VAPOR OVEREXPOSURE MAY CAUSE DROWSINESS. INGESTION :
LOW INGESTION HAZARD IN NORMAL USE. PROLONGED/ REPEATED EXPOSURE EFFECTS:
SKIN: MAY CAUSE IRRITATION. INHALATION: NO KNOWN APPLICABLE INFORMATION.
INGESTION: REPEATED INGESTION OR SWALLOWING LARGE A MOUNTS MAY INJURE
INTERNALLY. COMMENT: THE ABOVE LISTED POTENTIAL EFFECTS OF OVEREXPOSURE ARE
BASED ON ACTUAL DATA, RESULTS OF STUDIES PERFORMED UPON SIMILAR COMPOSITIONS,
COMPONENT DATA AND/OR EXPERT REVIEW OF THE PRODUCT.
Signs And Symptions Of Overexposure: NO KNOWN APPLICABLE INFORMATION.
Medical Cond Aggravated By Exposure: NO KNOWN APPLICABLE INFORMATION.
First Aid: EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. SKIN: FLUSH WITH
COPIOUS AMOUNTS OF WATER. CONTACT A PHYSICIAN (FP N). INHALATION: REMOVE TO
FRESH AIR. GET MEDICAL ATTENTION IF ILL EFFECTS PERSIST. INGESTION: GET
MEDICAL ATTENTION. COMMENTS: TREAT ACCORDING TO PERSON'S CONDITION AND
SPECIFICS OF EXPOSURE.
=======================================================
Handling and Disposal
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Spill Release Procedures: OBSERVE ALL PERSONAL PROTECTION EQUIPMENT
RECOMMENDATIONS. WIPE UP OR SCRAPE UP & CONTAIN FOR SALVAGE OR DISPOSAL.
CLEAN AREA AS APPROPRIATE SINCE SOME SILICONE MATERIALS EVEN IN SMALL
QUANTITIES, MA Y PRESENT A SLIP HAZARD. FINAL CLEANING MAY REQUIRE USE OF
STEAM, SOLVENTS OR DETERGENTS. LOCAL, STATE & FEDERAL LAWS &
REGULATIONS MAY APPLY TO RELEASE & DISPOSAL OF THIS MATERIAL AS WELL
(SUPP SFTY)
Waste Disposal Methods: WHEN THE MATERIAL IS DISCARDED AS RECEIVED, IT IS NOT
CLASSIFIED AS A HAZARDOUS WASTE. FEDERAL HAZARDOUS WASTE CODE: NA.
CHARACTERISTIC WASTE: IGNITABLE: NA. CORROSIVE: NA. REACTIVE: NA. TCLP: NA.
STA TE/LOCAL LAWS MAY IMPOSE ADDITIONAL REGULATORY REQUIREMENTS REGARDING
DISPOSAL. CALL DOW CORNING COR PORATE ENVIRONMENTAL MGMT IF NEEDED
(517)496-6315.
Handling And Storage Precautions: USE WITH ADEQUATE VENTILATION. PRODUCT
EVOLVES METHYL ALCOHOL WHEN EXPOSED TO WATER OR HUMID AIR. PROVIDE
VENTILATION DURING USE TO CONTROL EXPOSURE WITHIN EXPOSURE GUIDELINES OR USE
AIR-SUPPLIED OR SELF-CONTAINED BREATHING APPARATUS. AVOID BREATHING VAPOR.
KEEP CONTAINER CLOSED. (OTHER PREC)
Other Precautions: HANDLING/STORAGE (CONT'D): AVOID EYE CONTACT. DO NOT TAKE
INTERNALLY. KEEP CONTAINER CLOSED AND STORE AWAY FROM WATER OR MOISTURE.
PRODUCT EVOLVES METHYL ALCOHOL WHEN EXPOSED TO WATER OR HUMID AIR. P ROVIDE
VENTILATION DURING USE TO CONTROL EXPOSURE WITHIN GUIDELINES OR USE
AIR-SUPPIED OR SELF-CONTA INED (OTHER INFO)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Autoignition Temp Text: N/D
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: ON LARGE FIRES USE DRY CHEMICAL, FOAM OR WATER SPRAY. ON
SMALL FIRES USE CARBON DIOXIDE (CO*2), WATER SPRAY, DRY CHEMICAL. WATER CAN
BE USED TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures: A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS
AND FULL PROTECTIVE EQIUPMENT SHOULD BE WORN IN FIGHTING LARGE FIRES
INVOLVING CHEMICALS (FP N). DETERMINE THE NEED TO EVACUATE OR ISOLATE THE
AREA ACCORDING TO YOUR LOCAL EMERGENCY PLAN. USE WATER SPRAY TO KEEP FIRE
EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard: NONE. THERMAL BREAKDOWN OF THE PRODUCT DURING
FIRE OR VERY HIGH HEAT CONDITIONS MAY EVOLVE THE FOLLOWING HAZARDOUS
DECOMPOSITION PRODUCTS: CARBON OXIDES AND TRACES OF INCOMPLETELY BURNED
CARBON COMPOU NDS. SILICON DIOXIDE. NITROGEN OXIDES. QUARTZ. METAL OXIDES.
FORMALDEHYDE. NFPA: HEALTH-1, FLAMMABILITY-1, REACTIVITY-0.
=======================================================
Control Measures
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Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIRATE FOR EXPOSURE OF
CONCERN (FP N). USE RESPIRATORY PROTECTION UNLESS ADEQUATE LOCAL EXHAUST
VENTILATION IS PROVIDED OR AIR SAMPLING DATA SHOW EXPOSURES ARE WITHIN
RECOMMENDED EXPOSURE GUIDELINES. INDUSTRIAL HYGIENE PERSONNEL CAN ASSIST IN
JUDGING THE ADEQUACY OF EXISTING ENGINEERING CONTROLS.
Ventilation: LOCAL EXHAUST: RECOMMENDED. GENERAL VENTILATION: RECOMMENDED.
Protective Gloves: IMPERVIOUS GLOVES (FP N). NO SPECIAL PROTECTION NEEDED
(MFR).
Eye Protection: ANSI APPROVED SAFETY GLASSES (FP N).
Other Protective Equipment: EYEWASH MEETING ANSI DESIGN CRITERIA (FP N).
Work Hygienic Practices: WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE.
Supplemental Safety and Health: SPILL/RELEASE PROC {CONT'D): AS THOSE MATERIALS
AND ITEMS EMPLOYED IN THE CLEANUP OF RELEASES. CALL DOW CORNING CORPORATION
(517) 496-5900 IF ADDITIONAL INFORMATION IS REQUIRED. PPE FOR SPILLS: EYE: U
SE FULL FACE RESPIRATOR. SKIN: WASHING AT MEALTIME AND END OF SHIFT IS
ADEQUATE. INHALATION/SUITABLE (OTHER INFORMATION)
=======================================================
Physical/Chemical Properties
=======================================================
M.P/F.P Text: NOT DETERMINED.
Spec Gravity: 1.52 @ 25C.
Solubility in Water: NOT DETERMINED.
Appearance and Odor: GRAY PASTE. SLIGHT ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE.
Materials To Avoid: OXIDIZING MATERIAL CAN CAUSE A REACTION. WATER, MOISTURE,
OR HUMID AIR CAN CAUSE HAZARDOUS VAPORS TO FORM.
Hazardous Decomposition Products: FIRE OR VERY HIGH HEAT CONDITIONS MAY EVOLVE
THE FOLLOWING PRODUCTS: CARBON OXIDES & TRACES OF INCOMPLETELY BURNED CARBON
COMPOUNDS. SILICON DIOXIDE. NITROGEN OXIDES. QUARTZ. METAL OXIDES.
FORMALDEHYDE.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ACUTE TOXICOLOGY DATA: COMPLETE INFORMATION IS NOT
YET AVAILABLE. COMPONENT TOXICOLOGY INFORMATION: NO KNOWN APPLICABLE
INFORMATION. SPECIAL HAZARD INFORMATION ON COMPONENTS: NO KNOWN APPLICABLE
INFOR MATION. INGREDIENTS (CON'T): COMMENTS: METHYL ALCOHOL FORMS ON CONTACT
WITH WATER OR HUMID AIR. PROVIDE ADEQUATE VENTILATION TO CONTROL EXPOSURES
WITHIN GUIDELINES OF OSHA PEL: TWA 200 PPM AND ACGIH TLV=SKIN: TWA 200 PPM,
STEL 250 PPM. THE EFFECTS OF OVEREXPOSURE LISTED IN THE HEALTH HAZARDS
SECTION INCLUDE HEALTH EFFECTS RELATED TO CONVERSION OF METHOXYSILANES TO
METHYL ALCOHOL UPON EXPOSURE TO MOIST OR HUMID AIR.
=======================================================
Ecological Information
=======================================================
Ecological: ENVIRONMENTAL FATE AND DISTRIBUTION: AIR: THIS PRODUCT IS A SOLID
CONSISTING OF A HIGH MOLECULAR WEIGHT SILICONE POLYMER AND OTHER SOLID
MATERIALS. UNLESS MILLED TO PRODUCE A DUST OR PARTICLES, IT IS UNLIKELY TO
GIVE RISE TO ATMOSPHERIC CONTAMINATION. WATER: THIS PRODUCT IS A SOLID WHICH
IS COMPLETELY INSOLUBLE IN WATER. AS THE SPECIFIC GRAVITY IS >1, IT WILL
SINK TO THE BOTTON OF THE WATER COURSE . TERRESTRIAL ENVIRONMENT: THIS
PRODUCT WILL ENTER THE TERRESTRIAL ENVIRONMENT IF, AS A COMPONENT OF
MUNICIPAL OR INDUSTRIAL SOLID WASTE THE PRODUCT IS LANDFILLED. IT IS UNLIKELY
THAT FURTHER SIGNIFIC ANT TRANSFORMATION OF THE (TRANSPORT)
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
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Sara Title III Information: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: NONE.
SECTION 304 CERCLA HAZARDOUS SUBSTANCES: NONE. SECTION 312 HAZARD CLASS:
ACUTE: YES. CHRONIC: NO. FIRE: NO. PRESSURE: NO. REACTIVE: NO. SECTION 313 T
OXIC CHEMICALS: NONE PRESENT OR NONE PRESENT IN REGULATED QUANTITIES.
TRANSPORT (CON'T): DOES NOT CONTAIN SIGNIFICANT CONCENTRATIONS OF WATER
SOLUBLE CONSTITUENTS THAT MAY BE LEACHED FROM PRODUCT. IT IS NOT LIKELY TO
PRESENT A DANGER TO TERRESTRIAL ORGANISMS. BIOCONCENTRATION: PRODUCT IS A
SOLID WHICH IS NOT SOLUBLE IN WATER & IF INGESTED WILL NOT BE ABSORBED.
ACCUMULATION IN BODY IS THEREFORE NO T POSSIBLE. DEGRADATION: (FED REGS)
Federal Regulatory Information: TSCA STATUS: ALL CHEMICAL SUBSTANCES IN THIS
MATERIAL ARE INCLUDED ON OR EXEMPTED FROM LISTING ON THE TSCA INVENTORY OF
CHEMICAL SUBSTANCES. CONTENTS OF THIS MSDS COMPLY WITH OSHA HAZARD
COMMUNICATION STANDARD 29CFR 1910.1200. SARA (CON'T): HIGH MOLECULAR
WEIGHT POLYMER WHICH IS AMENABLE TO RECYCLING. PRODUCT IS NOT BIODEGRADABLE.
PRODUCT IS REMOVED >80% DURING THE SEWAGE TREATMENT PROCESS. CON TACT NEHC
FOR FURTHER INFORMATION.
State Regulatory Information: CALIFORNIA: WARNING: THIS PRODUCT CONTAINS THE
FOLLOWING CHEMICAL(S) LISTED BY THE STATE OF CALIFORNIA UNDER THE SAFE
DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65) AS BEING
KNOWN T O CAUSE CANCER: NONE KNOWN. WARNING: THIS PRODUCT CONTAINS THE
FOLLOWING CHEMICAL(S) LISTED BY THE STATE OF CALIFORNIA UNDER THE SAFE
DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65) AS BEING
KNOWN TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: NONE KNOWN.
MASSACHUSETTS: NO INGR EDIENT REGULATED BY MA RIGHT-TO-KNOW LAW PRESENT.
PENNSYLVANIA: CALCIUM CARBONATE TREATED WITH STEARIC ACID. (OTHER INFO)
=======================================================
Other Information
=======================================================
Other Information: GENERIC DESCRIPTION: SILICONE ELASTOMER. OTHER PREC
(CONT'D): BREATHING APPARATUS. THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE
HANDLING. USE AT ELEVATED TEMPERATURE OR AEROSOL/SPRAY APPLICATIONS MAY RE
QUIRE ADDED PRECAUTIONS. SUPPLEMENTAL SAFTEY (CONT'D): RESPIRATOR: USE
SELF-CONTAINED BREATHING APPARTUS (SCBA) OR OTHER SUPPLIED-AIR RESPIRATOR.
STATE REG (CONT'D): DIMETHYL SILOXANE, HYDROXY-TERMIN ATED.
POLYDIMETHYLSILOXANE. AMORPHOUS FUMED SILICA. NEW JERSEY: CALCIUM CARBONATE
TREATED WITH STEARIC ACID. DIMETHYL SILOXANE, HYDROXY-TERMINATED.
POLYDIMETHYLSILOXANE. AMORPHOUS FUMED SILICA. METHY LTRIMETHOXYSILANE.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: DOW CORNING 795 SILICONE BUILDING SEALANT, GRAY
Company: DOW CORNING CORP
Street: 2200 W SALZBURG RD
City: AUBURN MI
Zipcode: 48611
Health Emergency Phone: 517-496-5900
Label Required IND: Y
Date Of Label Review: 07/23/2001
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: Slight
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.