SIGMA CHEMICAL CO -- HEMATOXYLIN SOLUTION GILL NO 3, GHS-3, COMPON
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Material Safety Data Sheet
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MSDS Num: CLHCZ
MSDS NAME: HEMATOXYLIN SOLUTION GILL NO 3, GHS-3, COMPONENT OF 91-6
Responsible Party
Name: SIGMA CHEMICAL CO
Box: 14508
City: SAINT LOUIS MO 63178
Info Phone: 314-771-5765 / 800-325-3010
Emergency Phone Number: 314-771-5765
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: SIGMA CHEMICAL CO
Box: 14508
City: SAINT LOUIS MO 63178
Phone: 314-771-5765 / 800-325-3010
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Ingredients
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Name: *** PROPRIETARY ***
-----------------------------
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Health Hazards Data
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LD50 LC50 Mixture: ORAL LD50(RAT):N/P
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE EFFECTS: HARMFUL IF SWALLOWED, INHALED, OR ABSORBED
THROUGH SKIN. VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES &
UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION. MAY CAUSE NERVOUS S YSTEM
DISTURBANCES. PROLONGED EXPOSURE CAN CAUSE: NAUSEA, HEADACHE & VOMITING.
TARGET ORGAN(S): CARDIOVASCULAR SYSTEM, TEETH. CHRONIC EFFECTS: MAY CAUSE
REPRODUCTIVE DISORDERS. TARGET ORGAN(S): LIVER, KIDNEYS, CENTRAL NERVOUS
SYSTEM. ADDITIONAL INFORMATION: WHEN INGESTED EARLY SYMPTOMS MIMIC ALCOHOL
INEBRIATION & ARE FOLLOWED BY NAUSEA, VOMITING, ABDOMINAL PAIN, WEAKNESS,
MUSCLE (SYPTOMS OF OVERE XPOSURE)
Signs And Symptions Of Overexposure: HEALTH HAZARDS ACUTE AND CHRONIC (CON'T):
TENDERNESS, RESPIRATORY FAILURE, CONVULSIONS, CARDIOVASCULAR COLLAPSE,
PULMONARY EDEMA, HYPOCALCEMIC TETANY & SEVERE METABOLIC ACIDOSIS. WITHOUT
TREATEMENT, D EATH MAY OCCUR IN 8 TO 24 HOURS. VICTIMS WHO SURVIVE THE
INITIAL TOXICITY PERIOD USUALLY DEVELOP RENAL FAILURE ALONG WITH BRAIN &
LIVER DAMAGE.
First Aid: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING
AND SHOES. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHI NG GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT
MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
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Handling and Disposal
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Spill Release Procedures: WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER
BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN
CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATE
RIAL PICKUP IS COMPLETE.
Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT
AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
Handling And Storage Precautions: KEEP TIGHTLY CLOSED. STORE IN A COOL DRY
PLACE.
Other Precautions: DO NOT BREATHE VAPOR. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. WASH THOROUGHLY AFTER HANDLING. TOXIC. IRRITANT. REPRODUCTIVE
HAZARD.
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Fire and Explosion Hazard Information
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Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures: WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N). WEAR SELF-CONTAINED BREATHING
APPARATUS & PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
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Control Measures
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Respiratory Protection: WEAR APPROPIATE NIOSH APPROVED RESPIRATOR.
Ventilation: MECHANICAL EXHAUST REQUIRED.
Protective Gloves: CHEMICAL-RESISTANT GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices: DO NOT BREATHE VAPOR. AVOID CONTACT WITH EYES, SKIN
AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: THIS MSDS IS FOR A COMPONENT OF CATALOG#: 91-6.
IRRITANT. REPRODUCTIVE HAZARD. INFORMATION REGARDING THE SPECIFIC CHEMICAL
IDENTITY OF THIS MATERIAL IS BEING WITHHELD AS A TRADE SECRET OF THE MANUFACT
URER.
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Physical/Chemical Properties
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Appearance and Odor: LIQUID. ODOR NOT SPECIFIED BY MANUFACTURER, (FP N).
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Reactivity Data
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Stability Indicator: YES
Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG BASES.
Hazardous Decomposition Products: TOXIC FUMES OF: CARBON MONOXIDE, CARBON
DIOXIDE, SULFUR OXIDES, IODINE, HYDROGEN IODIDE, SODIUM/SODIUM OXIDES;
ALUMINUM OXIDE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: N/P. LABEL PRECAUTIONARY STATEMENTS: TOXIC (USA).
HARMFUL (EU). HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. REPRODUCTIVE HAZARD. TAR GET
ORGANS: LIVER, KIDNEYS. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH
PLENTY OF WATER AND SEEK MEDICAL ADVICE. WEAR SUITABLE PROTECTIVE CLOTHING.
DO NOT BREATHE VAPOR.
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Ecological Information
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Ecological: DATA NOT YET AVAILABLE.
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MSDS Transport Information
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Transport Information: CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
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Regulatory Information
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Sara Title III Information: THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS.
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Other Information
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Other Information: REGULATORY INFORMATION: EUROPEAN INFORMATION: CAUTION:
SUBSTANCE NOT YET FULLY TESTED. HARMFUL. R20/21/22. HARMFUL BY INHALATION, IN
CONTACT WITH SKIN AND IF SWALLOWED. R 36/37/38. IRRITATING TO EYES,
RESPIRATORY SYSTEM & SKIN. S 26. IN CASE OF CONTACT WITH EYES, RINSE
IMMEDIATELY WITH PLENTY OF WATER & SEEK MEDICAL ADVICE. S 36. WEAR
SUITABLE PROTECTIVE CLOTHING. S 23. DO NOT BREATHE VAPOR.
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HAZCOM Label
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MSDS NAME: HEMATOXYLIN SOLUTION GILL NO 3, GHS-3, COMPONENT OF 91-6
Company: SIGMA CHEMICAL CO
PO Box: 14508
City: SAINT LOUIS MO
Zipcode: 63178
Health Emergency Phone: 314-771-5765
Label Required IND: Y
Date Of Label Review: 07/26/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: A
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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