ITW PHILADELPHIA RESINS -- PHILLYCLAD 1775/620TS HARDENER, 3461H
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Material Safety Data Sheet
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MSDS Num: CLPPQ
MSDS NAME: PHILLYCLAD 1775/620TS HARDENER, 3461H
Kit Part: Y
Responsible Party
Name: ITW PHILADELPHIA RESINS
Address: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA 18936
Info Phone: 215-855-8450
Emergency Phone Number: 800-424-9300
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ITW PHILADELPHIA RESINS
Address: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA 18936
Phone: 215-855-8450
Contract Number: N00406-00-P-5525
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Ingredients
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Name: *** PROPRIETARY ***
-----------------------------
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Health Hazards Data
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Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: EMERGENCY OVERVIEW: WARNING! SEVERE EYE, SKIN &
RESPIRATORY TRACT IRRITANT (EVIDENCED BY RASH, BURNING SENSATION, SORE
THROAT, NAUSEA, SHORTNESS OF BREATH). TOXIC BY SKIN ABSORPTION. MAY CAUSE
SKIN SE NSITIZATION. AVOID BREATHING VAPORS. USE WITH ADEQUATE VENTILATION.
DO NOT TAKE INTERNALLY. WASH THOROUGHLY AFTER HANDLING. DO NOT EXPOSE TO HEAT
OR FLAMES. POTENTIAL HEALTH EFFECTS: PRIMARY ROUTES OF EXPOSURE: SKIN
CONTACT, SKIN ABSORPTION. ACUTE OVEREXPOSURE: SKIN: SEVERE IRRITANT. EYES:
SEVERE IRRITANT. INHALATION: IRRITATION OF NOSE & THROAT; NAUSEA &
VOMITING IN SEVERE CASES. INGESTION: MAY CAUSE (SIGNS/SYMPTOMS OF
OVEREXPOSURE)
Explanation Of Carcinogenicity: CRYSTALLINE SILICA: IARC GROUP 1, VOLUME 68,
PAGE 41, 1997; NTP 9TH ANNUAL REPORT KNOWN TO BE HUMAN CARCINOGENS LIST (FP
N). CANCER-SUSPECT CONSTITUENT(S): CRYSTALLINE SILICA (SEE HANDLING AND
STORAGE ).
Signs And Symptions Of Overexposure: ACUTE/CHRONIC (CON'T): IRRITATION OF MOUTH
& THROAT & GASTROINTESTINAL TRACT. CHRONNIC OVEREXPOSURE: REPEATED
SKIN CONTACT CAN CAUSE SENSITIZATION WITH ITCHING, RASHES OR SWELLING OF
SKIN. PROLONGED O R SEVERRE OVEREXPOSURE TO DMP VAPOR CAN CAUSE DELAYED LUNG
DAMAGE & CHEMICAL PNEUMONIA. REPEATED EXPOSURES TO HIGH VAPOR
CONCENTRATIONS OF TEPA MAY CAUSE INJURY TO LIVER, KIDNEY & RESPIRATORY
TRACT. T EPA HAS CAUSED ALLERGIC. OTHER: REPEATED &/OR PROLONGED
EXPOSURE TO LOW CONCENTRATIONS OF VAPOR MAY CAUSE: SORE THROAT, EYE
IRRITATION, NAUSEA, FAINTNESS, HEADACHE, WHICH ARE TRANSIENT. REPEATED
&/OR PROLONGED EXPOSURES (MEDICAL CONDITION)
Medical Cond Aggravated By Exposure: EYE DISEASE, SKIN DISORDERS AND ALLERGIES.
OVEREXPOSURE (CON'T): MAY RESULT IN: ADVERSE SKIN EFFECTS (DEFATTING, RASH,
IRRITATION OR CORROSION), ADVERSE EYE EFFECTS (CONJUNCTIVITIS OR CORNIEAL
DAMAGE).
First Aid: EYES: IMMEDIATELY FLUSH WITH CLEAN WATER FOR AT LEAST 15 MINUTES
WHILE GENTLY HOLDING EYELIDS OPEN. GET MEDICAL HELP AS SOON AS POSSIBLE.
SKIN: IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND SHOES; WASH WELL WITH
SOAP AND WARM WATER. SEE A DOCTOR IF IRRITATION DEVELOPES. INHALATION: REMOVE
PATIENT TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. SEE A
DOCTOR IF SYMPTOMS PERSIST. INGEST ION: DO NOT INDUCE VOMITING. DILUTE WITH
LOTS OF MILK OR WATER AND GET IMMEDIATE MEDICAL HELP.
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Handling and Disposal
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Spill Release Procedures: SPILL CONTROL: AVOID PERSONAL CONTACT. ELIMINATE
IGNITION SOURCES. VENTILATE AREA. CONTAINMENT: DIKE, CONTAIN AND ABSORB WITH
CLAY, SAND, OR OTHER SUITABLE MATERIAL. CLEANUP: FOR LARGE SPILLS, PUMP TO
STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY,
SAND, OR OTHER SUITABLE MATERIAL; DISPOSE OF PROPERLY. FLUSH AREA WITH WATER
TO REMOVE TRACE RESIDUE. (NEUTRALIZING AGENT).
Neutralizing Agent: N/P.SPILL(CONT):SPECIAL PROCEDURES: PREVENT SPILL FROM
ENTERING DRAINAGE/SEWER SYSTEMS WATERWAYS/SURFACE WATERS.
Waste Disposal Methods: WASTE MANAGEMENT RECOMMENDATIONS: IF THIS MATERIAL
BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR
261). DISPOSE OF ACCORDING TO APPLICABLE FEDERAL, STATE, AND LOCAL REGULA
TIONS.
Handling And Storage Precautions: AVOID CONTACT WITH SKIN, EYES, OR CLOTHING.
WASH THOROUGHLY WITH SOAP & WATER AFTER USING & PARTICULARLY BEFORE
EATING, DRINKING, SMOKING, APPLYING COSMETICS, OR USING TOILET FACILITIES.
LAUNDER CONTA MINATED CLOTHING & PROTECTIVE GEAR BEFORE REUSE. DISCARD
CONTAMINATED LEATHER (OTHER PRECAUTIONS)
Other Precautions: HANDLING/STORAGE (CON'T): ARTICLES. HANDLE MIXED RESIN &
HARDENER IN ACCORDANCE WITH POTENTIAL HAZARD OF CURING AGENT USED. PROVIDE
APPROPRIATE VENTILATION/RESPIRATORY PROTECTION AGAINST DECOMPOSITION
PRODUCTS DURING WELDING/FLAME CUTTING OPERATIONS & TO PROTECT AGAINST
DUSTS WHICH INCLUDES (OTHER I NFORMATION)
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Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point: >93.3C, 200.F
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: WATER, CARBON DIOXIDE AND DRY CHEMICAL.
Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS AND SUFFICIENT PROTECTIVE GEAR TO PREVENT
ALL SKIN AND EYE CONTACT WITH THIS MATERIAL(FP N).
Unusual Fire/Explosion Hazard: NONE. HAZARDOUS PRODUCTS OF COMBUSTION: ACRID
AND TOXIC FUMES WITH ORGANIC AMINES, AMMONIA, OXIDES OF CARBON AND NITROGEN.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE NEEDED IN NORMAL USE WITH PROPER VENTILATION. IN
POORLY VENTILATED AREAS OR WHEN CREATING A DUST OR MIST, USE NIOSH-APPROVED
ORGANIC VAPOR RESPIRATOR.
Ventilation: GENERAL MECHANICAL VENTILATION IS ADEQUATE FOR OCCASIONAL USE. FOR
PROLONGED OR REPEATED USE, LOCAL EXHAUST IS RECOMMENDED.
Protective Gloves: CHEMICAL-RESISTANT RUBBER (FOR EXAMPLE, NEOPRENE, BUTYL
RUBBER, OR NITRILE).
Eye Protection: ANSI APPROVED SAFETY GLASSES WITH SIDESHIELDS OR CHEMICAL
GOGGLES (FP N).
Other Protective Equipment: EYEWASH STATION AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). OTHER PROTECTIVE GEAR AS NEEDED TO PREVENT SKIN
CONTACT.
Work Hygienic Practices: N/P.
Supplemental Safety and Health: PHYSICAL/CHEMICAL DATA (CON'T): VOC
(GRAMS/LITER): 0. PERCENT SOLIDS BY WEIGHT: 100. CHEMICAL FAMILY: POLYAMINES
AND MODIFIED POLYAMINES. RATINGS: HEALTH-3, FLAMMABILITY-1, REACTIVITY-1.
THIS MSD S PERTAINS TO HARDENER ONLY; PROPERLY MIXED, CURED EPOXIES ARE NOT
HAZARDOUS.
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Physical/Chemical Properties
=======================================================
Boiling Point: >232.2C, 450.F
M.P/F.P Text: N/D
Vapor Pres: <0.01 AT 68F
Vapor Density: (AIR=1):>1
Spec Gravity: 0.95
PH: ALKALINE 0
Solubility in Water: N/D
Appearance and Odor: AMBER LIQUID WITH MILD AMMONIA-LIKE ODOR.
Percent Volatiles by Volume: 0
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT OR OPEN FLAME. THIS PRODUCT IS
CHEMICALLY STABLE.
Materials To Avoid: STRONG OXIDDIZERS, ACIDS, AND CHLORINATED ORGANIC
COMPOUNDS.
Hazardous Decomposition Products: ACRID AND TOXIC FUMES WITH ORGANIC AMINES,
AMMONIA, OXIDES OF CARBON AND NITROGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: HEAT IS RELEASED WHEN THIS PRODUCT IS MIXED
WITH EPOXY RESINS; USE CARE WHEN MIXING LARGE QUANTITIES.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ACUTE ORAL EFFECTS: LD50 (RAT): NO DATA AVAILABLE.
ACUTE INHALATION EFFECTS: LC50 (RAT): NO DATA. SUBCHRONIC EFFECTS: NO DATA.
ACUTE DERMAL EFFECTS: LD50 (RABBIT): NO DATA AVAILABLE. TETA HAS BEEN FOU ND
TO BE TOXIC BY SKIN ABSORPTION (ANSI Z129.1 1988). TETA IS A SEVERE IRRITANT
TO SKIN OF A RABBIT. EYE IRRITATION: TETA AND DMP ARE SEVERE IRRITANTS TO
EYES OF A RABBIT. CHRONIC EFFECTS: NO DATA. CA RCINOGENICITY, TERATOGENICITY,
& MUTAGENICITY: TETA HAS TESTED POSITIVE IN SCREENING TESTS FOR
MUTAGENICITY. TETA WAS FOUND FETOTOXIC AND TERATOGENIC WHEN FED TO RATS AT
0.83% & 1.67% OF DIET. WHEN AP PLIED DERMALLY TO (ECOLOGICAL INFO)
=======================================================
Ecological Information
=======================================================
Ecological: ECOTOXICITY: NO DATA. MOBILITY AND PERSISTENCE: NO DATA.
ENVIRONMENTAL FATE: NO DATA. TOXICOLOGICAL INFO (CON'T): THE SKIN OF PREGNANT
GUINEA PIGS, THERE WAS A 90% ABORTION RATE OR DEATH OF FETUS WITH
DEVELPMENTAL ANOMOLIES. TEPA HAS EXHIBITED EVIDENCE FOR WEAK MUTAGENIC
ACTIVITY IN VITRO TEST SYSTEMS. LD50 (ORAL,RAT): TRIETHYLENETETRAMINE 2460
MG/KG; TETRAETHYLENEPENTAMINE 205 MG/KG; 2,4,6-TRIS(D
IMETHYLAMINOMETHYL)PHENOL 1200 MG/KG; AMIDOAMINE N/D. LD50 (DERMAL, RABBIT):
TRIETHYLENETETRAMINE 805 MG/KG; TETRAETHYLENEPENTAMINE 660 MG/KG;
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL 1350 MG/KG; AMIDOA MINE N/D.
(TRANSPORT)
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MSDS Transport Information
=======================================================
Transport Information: PROPER SHIPPING NAME: NON-REGULATED. TECHNICAL NAME:
N/P. HAZARD CLASS: N/A. UN NUMBER: N/A. PACKING GROUP: N/A. IMDG PAGE NO.:
N/A. EMERGENCY RESPONSE GUIDE NO.: N/A. OTHER: N/P. ECOLOGICAL INFORMAT ION
(CON'T): LC50 (INHALATION, RAT 4 HOURS): TRIETHYLENETETRAMINE N/D;
TETRAETHYLENEPENTAMINE N/D; 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL > 0.5
MG/L; AMIDOAMINE N/D.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: CLASSIFICATION OF THIS MATERIAL FOR SARA SECTION
312 HAZARDOUS MATERIALS INVENTORY REPORTING: IMMEDIATE HEALTH HAZARD: DELAYED
HEALTH HAZARD.
Federal Regulatory Information: TSCA: ALL INGREDIENTS OF PRODUCT ARE LISTED, OR
EXEMPT FROM LISTING ON TSCA INVENTORY. THE FOLLOWING RCRA CODE(S) APPLIES TO
MATERIAL IF IT BECOMES WASTE: NONE. REGULATORY STATUS OF HAZARDOUS CHEMICAL
CONSTITUENTS OF THIS PRODUCT: TRIETHYLENETETRAMINE, TETRAETHYLENEPENTAMINE,
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL, AMIDOAMINE: EXTREMELY HAZARDOUS:NO.
TOXIC CHEMICAL: NO. CERCLA (RQ (LBS): NO. TSCA 1 2B EXPORT NOTIFICATION: NOT
REQUIRED. CANADIAN REGULATIONS: W HAZARD CLASS(ES): D2B. ALL COMPONE NTS OF
PRODUCT ARE ON DOMESTIC SUBSTANCES LIST.
State Regulatory Information: N/P.
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Other Information
=======================================================
Other Information: AMIDOAMINE IS A SUBSTANCE WHOSE IDENTITY IS A TRADE SECRET
OF SUPPLIER AND UNKNOWN. OTHER PRECAUTIONS (CON'T): CRYSTALLINE SILICA,
DURING SANDLING/GRINDING OF CURED PRODUCT. A TLV OF 0.1 MG/M3 SHOULD BE
OBSERVED FOR CRYSTALLINE SILICA. STORE IN A COOL, DRY AREA AWAY FROM HIGH
TEMPERATURES & FLAMES.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PHILLYCLAD 1775/620TS HARDENER, 3461H
Company: ITW PHILADELPHIA RESINS
Street: 130 COMMERCE DR.
City: MONTGOMERYVILLE PA
Zipcode: 18936
Health Emergency Phone: 800-424-9300
Label Required IND: Y
Date Of Label Review: 10/30/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: EMERGENCY OVERVIEW: WARNING! ACUTE: SEVERE EYE, SKIN
AND RESPIRATORY TRACT IRRITANT (EVIDENCED BY RASH, BURNING SENSATION, SORE
THROAT, NAUSEA, SHORTNESS OF BREATH). TOXIC BY SKIN ABSORPTION. CHRONIC: CAN
CAUSE SKIN SENSITIZATION. VAPORS CAN CAUSE DELAYED LUNG DAMAGE, CHEMICAL
PNEUMONITIS, ALLERGIC REACTIONS AND INJURY TO LIVER, KIDNEY AND RESPIRATORY
TRACT. REPEATED/PROLONGED EXPOSURE MAY CAUSE T RANSIENT SORE THROAT, EYE
IRRITATION, NAUSEA, FAINTNESS, HEADACHE. MAY ALSO RESULT IN ADVERSE SKIN
EFFECTS (DEFATTING, RASH, IRRITATION, CORROSION), & ADVERSE EYE EFFECTS
(CONJUNCTIVITIS, CORNEAL DAMA GE).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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PHILLYCLAD 1775/620TS HARDENER, 3461H
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INTERNAL STANDARD MIXTURE, STM-341N
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3114-55-4
3855-82-1
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MAGENTA TONER CARTRIDGE, 12A1451
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