LIQUID CARBONIC CORP -- CARBON DIOXIDE,REFRIGERATED LIQUID
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Material Safety Data Sheet
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NIIN: 01-078-3669
MSDS Num: BKNWJ
MSDS NAME: CARBON DIOXIDE,REFRIGERATED LIQUID
Responsible Party
Name: LIQUID CARBONIC CORP
Address: 910 JORIE BLVD.
City: OAK BROOK IL 60521-2218
Info Phone: 708-572-7500
Emergency Phone Number: 504-673-8831 800-424-9300(CHEMTREC)
Preparer's Name: UNKNOWN
Review Ind: Y
Published: Y
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Preparer Co. when other than Responsible Party Co.
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Name: LIQUID CARBONIC CORP
Address: 135 S LA SALLE STREET
City: CHICAGO IL 60603-4101
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Contractor Summary
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Name: DUTCH VALLEY SUPPLY CO
Address: 970 PROGRESS CTR AVE
City: LAWRENCEVILLE GA 30043
Phone: (404-513-0612)
Name: HILLER SYSTEMS INC
Address: 833 PRINCIPAL LN
City: CHESAPEAKE VA 23320
Phone: 757-549-9123
Name: KIDDE FENWAL INC
Address: 400 MAIN ST
City: ASHLAND MA 01721-2150
Phone: 508-881-2000
Name: LIQUID CARBONIC CORP
Address: 135 S LA SALLE STREET
City: CHICAGO IL 60603-4101
Phone: 312-855-2500
Name: SUMMIT ASSOCIATES
Address: 10910-H SOUTHLAKE COURT
City: RICHMOND VA 23236-3914
Phone: 804-794-1434
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Item Description Information
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Item Manager: S9I
Item Name: CYLINDER,CARBON DIOXIDE
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: EA
UI Container Qty: 1
Type of Container: CYLINDER
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Ingredients
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Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE
% Wt: <99.5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 5000 PPM
ACGIH TLV: 5000PPM/30000STEL;95
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Health Hazards Data
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LD50 LC50 Mixture: TLV IS 5000 MOLAR PPM (TWA)
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHAL:CARBON DIOXIDE IS AN ASPHYXIANT(POWERFUL CEREBRAL
VASODILATOR WHICH,AT HIGH CONCENTRATIONS,CAN CAUSE DEATH DUE TO CIRCULATORY
INSUFFICIENCY).SKIN/EYES:MAY CAUSE "FREEZE" BURNS.INGEST:NOT AN EXPE CTED
ROUTE OF EXPOSURE.
Explanation Of Carcinogenicity: NONE OF THE INGREDIENTS IN THIS PRODUCT IS
LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN.
Signs And Symptions Of Overexposure: INHAL:2-3%-ASPHYXIA.3-5%-INCREASED
RESPIRATION,HEADACHE.>15%-HEADACHE,NAUSEA,VOMITING,UNCONSCIOUSNESS.
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH MAY BE AT INCREASED
RISK FROM EXPOSURE.
First Aid: EYES/SKIN(FROSTBITE):REMOVE CONTAMINATED CLOTHING;FLUSH WITH
LUKEWARM WATER.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL
RESPIRATION IF NEEDED.INGEST:NOT AN EXPECTED ROUTE OF EXPOSURE.
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Handling and Disposal
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Spill Release Procedures: REMOVE PERSONNEL. VENTILATE AREA. WEAR SELF-
CONTAINED BREATHING APPA
Waste Disposal Methods: CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. MANUFACTURER
RECOMMENDS VENTING SLOWLY TO ATMOSPHERE WITH ADEQUATE VENTILATIONS. DISPOSE
OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE CARBON DIOXIDE CYLINDERS UPRIGHT IN A
COOL, DRY LOCATION, AWAY FROM CHEMICALS WITH SAFETY CAP INSTALLED.
Other Precautions: NEVER WORK ON A PRESSURIZED SYSTEM. IF THERE IS A LEAK,
CLOSE THE CYLINDER VALVE, BLOW DOWN SYSTEM BY VENTING TO A SAFE PLACE, THEN
REPAIR LEAK.
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Extinguishing Media: SUBJECT MATERIAL IS AN EXTINGUISHING AGENT.
Fire Fighting Procedures: WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL
FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH
WATER FOG.
Unusual Fire/Explosion Hazard: DO NOT SPRAY WATER DIRECTLY ON RELIEF
VALVES.COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION
PRODUCTS AND VAPORS.
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Control Measures
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Respiratory Protection: WEAR SELF-CONTAINED BREATHING APPARATUS WHEN
CONCENTRATIONS ARE ABOVE PEL.
Ventilation: MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST VENTILATION TO KEEP
EXPOSURE LEVELS BELOW PEL.
Protective Gloves: LEATHER GLOVES FOR HANDLING CYLINDERS.
Eye Protection: SAFETY GLASSES OF FULL FACE SHIELD.
Other Protective Equipment: SELF-CONTAINED BREATHING APPARATUS. SAFETY SHOES.
DO NOT WEAR CONTACT LENSES.
Work Hygienic Practices: KEEP SAFETY VALVES IN GOOD WORKING CONDITIONS. KEEP
DEBRIS AND UNNECESSARY EQUIPMENT AWAY FROM CO2 EQUIPMENT.
Supplemental Safety and Health: SUBLIMATION TEMPERATURE IS 109.3F.THE LIQUID
CONVERTS TO SNOW WHEN DISCHARGED FROM CYLINDER AT LESS THAN 68PSIG.
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Physical/Chemical Properties
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HCC: G3
B.P. Text: SUBLIMES
M.P/F.P Text: SUBLIMES
Decomp Text: UNKNOWN
Vapor Pres: 44260
Vapor Density: 1.65
Spec Gravity: 1.014 @2F
Solubility in Water: SOLUBLE
Appearance and Odor: GAS/LIQUID/PARTICLES(SNOW);COLORLESS;SLIGHT PUNGENT ODOR.
Percent Volatiles by Volume: 100
Corrosion Rate: UNKNOWN
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: ALKALINE MATERIALS(FORMS CARBONATES AND BICARBONATES).
REACTIVE METALS(EG,NA,K,MG),CAN EXPLODE.
Hazardous Decomposition Products: CARBON MONOXIDE(AT HIGH TEMPERATURES).
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 105593
MSDS NAME: CARBON DIOXIDE,REFRIGERATED LIQUID
MSDS Prepared Date: 04/01/1994
Review Date: 05/13/1997
Net Unit Weight: 100 LBS.
AF MMAC Code: NR
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: EA
Container QTY: 1
Type Of Container: CYLINDER
Additional Data: NONE
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Detail DOT Information
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DOT PSN Code: CUX
DOT Proper Shipping Name: CARBON DIOXIDE
Hazard Class: 2.2
UN ID Num: UN1013
Label: NONFLAMMABLE GAS
Packaging Exception: 306
Non Bulk Pack: 302,304
Bulk Pack: 302,314,315
Max Qty Pass: 75 KG
Max Qty Cargo: 150 KG
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: DOH
IMO Proper Shipping Name: CARBON DIOXIDE
IMDG Page Number: 2111
UN Number: 1013
UN Hazard Class: 2(2.2)
IMO Packaging Group: -
Subsidiary Risk Label: -
EMS Number: 2-09
MED First Aid Guide NUM: 615
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Detail IATA Information
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IATA PSN Code: FHH
IATA UN ID Num: 1013
IATA Proper Shipping Name: CARBON DIOXIDE +
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
Packing Note Passenger: 200
Max Quant Pass: 75KG
Max Quant Cargo: 150KG
Packaging Note Cargo: 200
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Detail AFI Information
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AFI PSN Code: FHH
AFI Proper Shipping Name: CARBON DIOXIDE
AFI Hazard Class: 2.2
AFI UN ID NUM: UN1013
Special Provisions: P5
Back Pack Reference: A6.3,A6.5,A6.6
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HAZCOM Label
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MSDS NAME: CARBON DIOXIDE,REFRIGERATED LIQUID
Company: LIQUID CARBONIC CORP
Street: 135 S LA SALLE STREET
City: CHICAGO IL
Zipcode: 60603-4101
Health Emergency Phone: 504-673-8831 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 05/13/1997
Status Code: C
MFG Label NO: UNKNOWN
Label Date: 05/13/1997
Year Procured: 1996
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: INHAL:CARBON DIOXIDE IS AN ASPHYXIANT(POWERFUL CEREBRAL
VASODILATOR WHICH,AT HIGH CONCENTRATIONS,CAN CAUSE DEATH DUE TO CIRCULATORY
INSUFFICIENCY).SKIN/EYES:MAY CAUSE "FREEZE" BURNS.INGEST:NOT AN EXPE CTED
ROUTE OF EXPOSURE. STORE CARBON DIOXIDE CYLINDERS UPRIGHT IN A COOL, DRY
LOCATION, AWAY FROM CHEMICALS WITH SAFETY CAP INSTALLED. FIRST AID:
EYES/SKIN(FROSTBITE):REMOVE CONTAMINATED CLOTHING;FLUS H WITH LUKEWARM
WATER.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF
NEEDED.INGEST:NOT AN EXPECTED ROUTE OF EXPOSURE.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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