LOS ANGELES CHEMICAL CO -- SODIUM FLUORIDE
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Material Safety Data Sheet
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NIIN: 00-059-9069
MSDS Num: BLHFQ
MSDS NAME: SODIUM FLUORIDE
Responsible Party
Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE STREET
Box: 1987
City: SOUTH GATE CA 90280-2534
Info Phone: 213-773-7923/FL 904-241-1200
Emergency Phone Number: 213-664-2121/800-424-9300
Preparer's Name: J. M. COATES
Review Ind: Y
Published: Y
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Preparer Co. when other than Responsible Party Co.
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Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE ST
Box: 1987
City: SOUTH GATE CA 90280
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Contractor Summary
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Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE ST
Box: 1987
City: SOUTH GATE CA 90280
Phone: 213-562-9500
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Item Description Information
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Item Manager: S9G
Item Name: SODIUM FLUORIDE,TECHNICAL
Specification Number: 06768-AWWA B-701
Type/Grade/Class: NONE
Unit of Issue: BG
Quantitative Expression: 00000000100LB
UI Container Qty: 0
Type of Container: UN 5M2 BAG
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Ingredients
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Cas: 7681-49-4
RTECS #: WB0350000
Name: SODIUM FLUORIDE (CERCLA)
% Wt: 97.70
Other REC Limits: NONE SPECIFIED
OSHA PEL: 2.5 PPM (F)
ACGIH TLV: 2.5 MG (F/)M3; 9596
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: LD50 (ORAL RAT) IS 180 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INHALATION OF DUST OR MIST MAY CAUSE SEVERE MUCOUS
MEMBRANE IRRITATION & BURNS. EFFECTS MAY NOT BE IMMEDIATELY APPARENT,
ESPECIALLY WITH DILUTE SOLUTIONS. CHRONIC:CAUSES SEVERE SKIN IRRITATION &
BURNS. INGESTION/INHALATION MAY BE HARMFUL & POSSIBLY FATAL. MAY BE
ABSORBED THROUGH SKIN & CAUSE FLUOROSIS.
Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR
GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Signs And Symptions Of Overexposure: MUCOUS MEMBRANE IRRITATION/BURNS, SEVERE
SKIN IRRITATION/BURNS, MAY PRODUCE SIGNS OF FLUOROSIS SUCH AS WEIGHT LOSS,
BRITTLENESS OF BONES, ANEMIA, WEAKNESS AND STIFFNESS OF JOINTS. INTERNAL
BLEEDING MA Y DEVELOP.
Medical Cond Aggravated By Exposure: ANY SKIN, RESPIRATORY OR MUCOUS MEMBRANE
CONDITION
First Aid: GET MEDICAL CARE.INHALATION:REMOVE TO FRESH AIR.GIVE CPR IF
NEEDED.KEEP PERSON WARM AND AT REST.EYES:IMMEDIATELY FLUSH WITH WATER FOR 15
MINUTES HOLDING EYELIDS OPEN.CONTACT AN EYE SPECIALIST IMMEDIAT ELY.SKIN:WASH
WITH SOAP/MILD DETERGENT & WATER.INGESTION:DO NOT INDUCE VOMITING.IF
CONSCIOUS,DRINK SEVERAL GLASSES OF WATER OR MILK.NOTE TO PHYSICIAN:EXPOSED
PERSON SHOULD BE OBSERVED FOR 48-72 HOURS.
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Handling and Disposal
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Spill Release Procedures: WEAR NIOSH APPROVED PROTECTIVE CLOTHING AND BREATHING
APPARATUS. ISOLATE SPILL AREA. CAREFULLY SHOVEL MATERIAL AND PLACE IN CLEAN
DRY CONTAINER AND COVER. AVOID RAISING DUST.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL SHOULD BE SUBJECT TO ALL APPLICABLE FEDERAL,
STATE AND LOCAL LAWS AND REGULATIONS.
Handling And Storage Precautions: STORAGE-STORE IN A COOL DRY PLACE,AWAY FROM
ACIDS.USE ONLY WITH ADEQUATE VENTILATION,DUST MASK/SELF-CONTAINED BREATHING
APPARATUS.
Other Precautions: DO NOT RAISE DUST. KEEP CONTAINER CLOSED. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. AVOID BREATHING DUST OR MIST. PROTECTIVE CLOTHING
SHOULD ALWAYS BE WORN. IN FIRE, IT WILL DECOMPOSE, RELEASING HIG HLY TOXIC
HYDROGEN FLUORIDE GAS.
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Fire and Explosion Hazard Information
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Flash Point Text: NOT COMBUSTIBLE
Extinguishing Media: USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures: ALTHOUGH THIS CHEMICAL IS NON-FLAMMABLE, WHEN HEATED
TO TEMPERATURES SUCH AS A FIRE, IT WILL RELEASE HYDROGEN FLUORIDE GAS.
Unusual Fire/Explosion Hazard: FIREFIGHTERS SHOULD AVOID ALL BODILY CONTACT.
WEAR FULL PROTECTIVE CLOTHING AND SCBA.
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Control Measures
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Respiratory Protection: IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN
EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR AN AIR-SUPPLIED
RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29 CFR 1910.134.
Ventilation: USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN
EXPOSURE BELOW TLV(S).
Protective Gloves: IMPERVIOUS GLOVES-PVC, NEOPRENE.
Eye Protection: CHEMICAL SPLASH GOGGLES, FACESHIELD.
Other Protective Equipment: EYE WASH STATION,SAFETY SHOWER, IMPERVIOUS CLOTHING
(COVERALL, BOOTS, ETC.)
Work Hygienic Practices: WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING,
OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health: MSDS PRESENTED BY CAGE 75656 FOR CONTRACT
NUMBER SP0400-97-T8934.
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Physical/Chemical Properties
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HCC: T4
B.P. Text: 3099F,1704C
M.P/F.P Text: 1796F,980C
Decomp Text: UNKNOWN
Vapor Pres: <0.01@200C
Spec Gravity: 2.726
Viscosity: UNKNOWN
Solubility in Water: MODERATE
Appearance and Odor: WHITE, CRYSTALLINE POWDER; NO ODOR.
Corrosion Rate: UNKNOWN
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: EXTREME TEMPERATURES SUCH AS FIRE. AVOID CONTACT
WITH INCOMPATIBLE MATERIALS.
Materials To Avoid: STRONG ACIDS.
Hazardous Decomposition Products: NITROGEN OXIDES, HYDROFLUORIC ACIDS AND
FLUORINE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 45227
MSDS NAME: SODIUM FLUORIDE
MSDS Prepared Date: 03/01/1996
Review Date: 04/17/1997
Net Unit Weight: 100.0 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: BG
Container QTY: 0
Type Of Container: UN 5M2 BAG
Additional Data: PSN IS PER MFR MSDS. REPORTABLE QUANTITY IS 1000 LBS PER MSDS.
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Detail DOT Information
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DOT PSN Code: NFI
DOT Proper Shipping Name: SODIUM FLUORIDE
Hazard Class: 6.1
UN ID Num: UN1690
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Special Provision: T8
Packaging Exception: 153
Non Bulk Pack: 213
Bulk Pack: 240
Max Qty Pass: 100 KG
Max Qty Cargo: 200 KG
Vessel Stow Req: A
Water/Ship/Other Req: 26
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Detail IMO Information
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IMO PSN Code: NRR
IMO Proper Shipping Name: SODIUM FLUORIDE, SOLID
IMDG Page Number: 6258
UN Number: 1690
UN Hazard Class: 6.1
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 6.1-04
MED First Aid Guide NUM: 750
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Detail IATA Information
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IATA PSN Code: WQB
IATA UN ID Num: 1690
IATA Proper Shipping Name: SODIUM FLUORIDE
IATA UN Class: 6.1
IATA Label: TOXIC
UN Packing Group: III
Packing Note Passenger: 619
Max Quant Pass: 100KG
Max Quant Cargo: 200KG
Packaging Note Cargo: 619
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Detail AFI Information
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AFI PSN Code: WQB
AFI Proper Shipping Name: SODIUM FLUORIDE
AFI Hazard Class: 6.1
AFI UN ID NUM: UN1690
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A10.6
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HAZCOM Label
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MSDS NAME: SODIUM FLUORIDE
Company: LOS ANGELES CHEMICAL CO
Street: 4545 ARDINE ST
PO Box: 1987
City: SOUTH GATE CA
Zipcode: 90280
Health Emergency Phone: 213-664-2121/800-424-9300
Label Required IND: Y
Date Of Label Review: 04/17/1997
Status Code: C
Label Date: 04/17/1997
Year Procured: 1997
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INHALATION OF DUST OR MIST MAY CAUSE SEVERE
MUCOUS MEMBRANE IRRITATION & BURNS.CHRONIC:CAUSES SEVERE SKIN IRRITATION
& BURNS.INGESTION/INHALATION MAY BE HARMFUL & POSSIBLY FATAL.MAY BE
ABSORBED THROUGH SKIN & CAUSE FLUOROSIS. FIRST AID:GET MEDICAL
CARE.INHALATION:REMOVE TO FRESH AIR.GIVE CPR IF NEEDED.KEEP PERSON WARM &
AT REST.EYES:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES,LIFT LIDS.CONTA CT
AN EYE SPECIALIST.SKIN:WASH WITH SOAP/MILD DETERGENT & WATER.INGESTION:DO
NOT INDUCE VOMITING.IF CONSCIOUS,DRINK SEVERAL GLASSES OF WATER OR MILK.NOTE
TO PHYSICIAN:EXPOSED PERSON SHOULD BE OBSERVED FOR 48-72 HOURS.TARGET
ORGANS:LUNGS,SKIN,EYES.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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