acetic acid, vinyl ester; (residual vinyl acetate monomer). formaldehyde volatile organic compound: 5.2 g/liter, 10 g/liter of material, less supp data: any work in a bulk storage tank.
H B FULLER CO -- X-3801 WATER BASED ADHESIVE
=======================================================
Material Safety Data Sheet
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MSDS Num: BTPWN
MSDS NAME: X-3801 WATER BASED ADHESIVE
Responsible Party
Name: H B FULLER CO
Address: 1200 WOLTERS BLVD
City: VADNAIS HEIGHTS MN 55110
Info Phone: 612-481-3300;612-481-3300
Emergency Phone Number: 612-481-3300
Published: Y
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Contractor Summary
=======================================================
Name: H B FULLER CO
Address: 1200 WOLTERS BLVD
City: VADNAIS HEIGHTS MN 55110
Phone: 612-481-3300
Name: H.B. FULLER COMPANY
Address: 3500 LEXINGTON AVENUE N.
City: ST. PAUL MN 55126-8076
Phone: 612-236-5300/ -5309 FAX
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Ingredients
=======================================================
Cas: 108-05-4
RTECS #: AK0875000
Name: ACETIC ACID, VINYL ESTER; (RESIDUAL VINYL ACETATE MONOMER).
LD50:(ORAL,RAT)2920 MG/KG. VP: 92@20C
% Wt: <0.5
OSHA PEL: 10 PPM;20 STEL
ACGIH TLV: 10 PPM;20 STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 50-00-0
RTECS #: LP8925000
Name: FORMALDEHYDE
% Wt: <0.0855
OSHA PEL: 0.75 PPM;2 PPM STEL
ACGIH TLV: 0.3 PPM, C
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: 5.2 G/LITER, 10 G/LITER OF MATERIAL, LESS
WATER AND EXEMPT SOLVENTS.
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPP DATA: ANY WORK IN A BULK STORAGE TANK.
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
=======================================================
Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENT
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYES: CONT W/LIQ MAY CAUSE IRRIT. SKIN:PRLNGD/RPTD
CONT W/LIQ PROD MAY CAUSE IRRIT. INHAL: EXPOS TO VAPS IN POORLY VENTD AREAS
MAY CAUSE IRRIT OF NOSE, THROAT & RESP TRACT. INGEST: NOT AN ANTIC RTE
OF EXPOS. SM AMTS ARE NOT ANTIC TOBE HARMFUL. CHRONIC: OVEREXP TO VINYL
ACETATE IS NOT EXPECTED (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOTE: CONTAINS LESS THAN REPORTABLE QUANTITIES
OF FORMALDEHYDE WHICH IS A KNOWN HUMAN CARCINOGEN (FP N).
Signs And Symptions Of Overexposure: HLTH HAZ: TO OCCUR DURING NORM HNDLG &
USE OF PROD. VINYL ACETATE HAS BEEN SHOWN TO CAUSE IRRIT & CANCER IN
INHAL STUDIES W/LAB ANIMALS. TEST LEVELS OF 600 PPM CAUSED AN INCR IN TUMORS
IN RESP TRACT O F TEST ANIMALS. NO TUMORS WERE OBSERVEDIN ANIMALS EXPOSED @
50 PPM/LOWER. THERE IS NOT EVIDENCE THAT VINYL (SUPP DATA)
Medical Cond Aggravated By Exposure: NO KNOWN EFTS ON OTHER ILLNESSES.
First Aid: EYE: FLUSH IMMED WITH WATER FOR AT LEAST 15 MINUTES. CONSULT A
PHYSICIAN IF IRRITATION PERSISTS. SKIN: WASH AFFECTED AREA WITH SOAP AND
WATER. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHAL: REMOVE TO FRESH
AIR. INGEST: IF PERSON CAN SWALLOW, GIVE 1 GLASS OF WATER/MILK. DO NOT INDUCE
VOMITING. GET IMMED MED ATTN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON
PERSON.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: DIKE IF NECESSARY, CONTAIN SPILL WITH INERT ABSORBENT
AND TRANSFER TO CONTAINERS FOR DISPOSAL. KEEP SPILLED PRODUCT OUT OF SEWERS,
WATERSHEDS OR WATER SYSTEMS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: TO THE BEST OF MFR KNOWLEDGE, THIS PROD DOES NOT MEET
DEFINITIOLN OF HAZ WASTE UNDER U.S. EPA HAZ WASTE REGS 40 CFR 261. SOLIDIFY
& DISPOSE OF IN AN APPRVD LANDFILL. CONSULT STATE, LOCAL OR PROVINICIA L
AUTHORITIES FOR MORE RESTRICTIVE REQUIREMENTS.
Handling And Storage Precautions: AVOID TEMPERATURE EXTREMES IN STORAGE.
CONSULT TECHNICAL DATA SHEET FOR SPECIFIC STORAGE INSTRUCTIONS.
Other Precautions: IN STOR, MONOMER VAPS WILL MIGRATE FROM EMULSION &
ESTABLISH AN EQUILIBRIUM BETWEEN HEADSPACE IN STOR CONTR & LIQ EMULSION.
LEVELS IN EXCESS OF ACCEPTABLE EXPOS CAN ACCUMULATE IN NON-VENTD HEADSPACES
ABOVE EMULSION. ALL PROC (SUPP DATA)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NON-FLAMMABLE
Extinguishing Media: NON-FLAMM IN LIQ ST; USE WATER SPRAY, FOAM, DRY CHEMICAL
OR CARBON DIOXIDE ON DRIED PRODUCT.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: THERE IS THE POSSIBILITY OF PRESSURE BUILDUP IN
CLOSED CONTAINERS WHEN HEATED. WATER SPRAY MAY BE USED TO COOL CONTAINERS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NOT NORMALLY REQUIRED. USE NIOSH/MSHA APPROVED
RESPIRATOR IF CONDITIONS WARRANT.
Ventilation: GENERAL DILUTION VENTILATION.
Protective Gloves: RUBBER GLOVES.
Eye Protection: CHEMICAL SAFETY GOGGLES.
Other Protective Equipment: EYE WASHES AVAIL WHERE EYE CONTACT CAN OCCUR.
Work Hygienic Practices: LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: EFTS OF OVEREXP:ACETATE HAS CAUSED CANCER IN
HUMANS. PROD CNTNS TRACE AMTS (<0.1%) OF FORMALDEHYDE. OVEREXP TO
FORMALDEHYDE SHOULD NOT OCCUR W/NORM HNDLG & USE. OTHER PREC: APPROP FOR
A CONFINED SPACE ENTRY SHOULD BE COMPLETED PRIOR TO PERFORMING
=======================================================
Physical/Chemical Properties
=======================================================
HCC: C3
B.P. Text: >200F,>93C
Spec Gravity: 1.05
PH: 5
Appearance and Odor: OFF-WHITE LIQUID, MILD, SWEET ODOR
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: INCOMPLETE COMBUSTION CAN YIELD LOW MOLECULAR
WEIGHT HYDROCARBONS, CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
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Ecological Information
=======================================================
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MSDS Transport Information
=======================================================
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Regulatory Information
=======================================================
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Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: X-3801 WATER BASED ADHESIVE
Company: H B FULLER CO
Street: 1200 WOLTERS BLVD
City: VADNAIS HEIGHTS MN
Zipcode: 55110
Health Emergency Phone: 612-481-3300
Label Required IND: Y
Date Of Label Review: 12/07/1993
Status Code: C
Label Date: 12/07/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYE IRRITATION. SKIN IRRITATION. MAY IRRITATE
NOSE, THROAT AND RESPRIATORY TRACT. CHRONIC: CONTAINS VINYL ACETATE WHICH HAS
BEEN SHOWN TO CAUSE CANCER IN INHALATION STUDIES WITH LABORATORY ANIM ALS.
THERE IS NO EVIDENCE THAT VINYL ACETATE HAS CAUSED CANCER IN HUMANS. THIS
PRODUCT CONTAINS FORMALDEHYDE WHICH IS KNOWN TO THE STATE OF CALIFRNIA TO
CAUSE CANCER OR REPRODUCTIVE DAMAGE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.