LILLY INDUSTRIES INC -- 60001 BLACK 67-11, 36711
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Material Safety Data Sheet
=======================================================
MSDS Num: BVZTL
MSDS NAME: 60001 BLACK 67-11, 36711
Responsible Party
Name: LILLY INDUSTRIES INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Info Phone: 310-352-3087
Emergency Phone Number: 800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LILLY IND INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Phone: 310-352-3087
Name: LILLY INDUSTRIES INC
Address: 210 E ALONDRA BLVD
City: GARDENA CA 90248
Phone: 213-321-0710
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Ingredients
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Name: POLYESTER RESIN UNSATURATED
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)
% Wt: 10-20
OSHA PEL: 2 MG/M3 RDUST
ACGIH TLV: 2 MG/M3 RDUST
------------------------------
Cas: 100-42-5
RTECS #: WL3675000
Name: STYRENE, MONOMER (SARA III). VP: 4.50.
% Wt: 42.69
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM;100PPM STEL,S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Name: POLYESTER RESIN UNSATURATED
% Wt: 30-40
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE - QUARTZ
% Wt: TRACE
OSHA PEL: 10 MG/M3 RDUST
ACGIH TLV: 0.1 MG/M3 RDUST
------------------------------
Cas: 7440-38-2
RTECS #: CG0525000
Name: ARSENIC (SARA III)
% Wt: TRACE
OSHA PEL: N/K (FP N)
ACGIH TLV: 0.01 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 7439-92-1
RTECS #: OF7525000
Name: LEAD (SARA III)
% Wt: TRACE
OSHA PEL: N/K (FP N)
ACGIH TLV: 0.15 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Name: SUPP DATA: MAY BE HVR/AIR & MAY TRAVEL ALONG GROUND BEFORE
IGNIT/FLASHING BACK TO VAP SOURCE. CLSD CNTNRS MAY BE
-----------------------------
Name: ING 8:COOLED BY WATER SPRAY.WATER/FOAM SPRAYED INTO CNTNR OF HOT BURNING
LIQ MAY CAUSE VIOLENT ERUPTION.IF WATER
-----------------------------
Name: ING 9: IS USED, FOG NOZZ ARE PREF. CONT W/FREE RADICAL FORMERS SUCH AS
PEROXIDES MAY RSLT IN SPONT EXOTHERMIC
-----------------------------
Name: ING 10: POLYM. EXPOS TO HEAT BUILDS UP PRESS IN CLSD CNTNRS. PROD
CONTAINS EXTREMELY FLAMM SOLVS WHOSE VAPS MAY
-----------------------------
Name: ING 11: FORM EXPLOSIVE MIXTURES WITH AIR.
-----------------------------
Name: RESP PROT:MIST,& FUME FILTERS.WHERE EXPOS POTNTL UNDER USE CNDTNS
NECESSITATES HIGHER LEV OF PROT,USE NIOSH/MSHA
-----------------------------
Name: ING 13: APPROVED POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR.
-----------------------------
Name: VENT: OR LOC EXHST VENT IN VOL & PATTERN TO KEEP TLV OF MOST HAZ ING
BELOW ACCEPTABLE LIMIT, & TO REMOVE DECOMP
-----------------------------
Name: ING 15: PRODUCTS DURING WELDING OR FLAMECUTTING ON SURFACES COATED WITH
THIS PRODUCT.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:SKIN: MAY CAUSE IRRIT/BLISTERING. EYE: MAY CAUSE MOD
IRRIT, TEARING, BURNING/REDNESS. INHAL: OVEREXP MAY CAUSE RESP IRRIT/NAUS,
EVEN UNCON/DEATH. CHRONIC: RPTS HAVE ASSOC RPTD & PRLNGD OVEREXP T O
SOLVS W/BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC &
INHAL CONTENTS MAY BE HARMFUL/FATAL.(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: STYRENE: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG
345, 1987: GROUP 2B. ANIMAL: NERVOUS SYSTEM.
Signs And Symptions Of Overexposure: HLTH HAZ: AVOID BRTHG VAPS/SPRAY MIST.
LONG TERM EXPOS MAY CAUSE PULM FIBROSIS LEADING TO PERM LUNG DMG. NOTE: LEAD
APPEARS ON NAVY LISTING OF OCCUP CHEM REPROD HAZS. SEEK CONSULTATION FROM
APPROPRIAT E HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION
AND SAFE HANDLING AND EXPOSURE INFORMATION (FP N).
Medical Cond Aggravated By Exposure: CONJUNCTIVITIS OF EYE, DERMATITIS, ASTHMA,
PREEXISTING RESPIRATORY DISEASES. PREEXISTING LUNG DISEASE, BY EXPOSURE TO
DUST.
First Aid: EYES: FLUSH WITH LUKE WARM WATER FOR AT LEAST 15 MINUTES AND OBTAIN
PROMPT MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. IF IRRITATION
OCCURS, GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMI TING. OBTAIN
EMER MEDICAL HELP. VOMITING MAY LEAD TO CHEMICAL PNEUMONITIS, WHICH CAN BE
FATAL. INHALATION: REMOVE TO FRESH AIR.
=======================================================
Handling and Disposal
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Spill Release Procedures: DO NOT USE WELDING/CUTTING TORCHES ON/NEAR CNTNRS.
FOLLOW LBL WARNINGS. REMOVE SOURCES OF IGNIT.PVNT FLOW INTO SEWERS/WATERWAYS.
CLEAN UP W/AN INERT ABSORB USING NON-SPARKING TOOLS.THOSE INVOLVED IN C
LEANUP OF SPILLS SHOULD USE RESP PROT FOR (SUPDAT)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: FOLLOW APPLICABLE REGULATIONS ON DISPOSAL OF WASTE.
RESIDUES ARE HAZARDOUS DUE TO THEIR IGNITABILITY. DISPOSE OF IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS (FP N).
Handling And Storage Precautions: KEEP PRODUCT CONTAINERS COOL, DRY, AND AWAY
FROM SOURCES OF IGNITION. USE AND STORE THIS PRODUCT WITH ADEQUATE VENT. DO
NOT SMOKE IN STORAGE AREAS.
Other Precautions: KEEP CONTAINERS CLOSED WHEN NOT IN USE. KEEP FROM CONTACT
WITH OXIDIZING MATERIALS. DO NOT TAKE INTERNALLY. FOR INDUSTRIAL USE ONLY.
KEEP AWAY FROM FOOD PRODUCTS. WASH THOROUGHLY AFTER HANDLING.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 88F,31.1C
Lower Limits: 1.1%
Upper Limits: 6.1%
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, OR FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP
N). PVNT HUMAN EXPOS TO FIRE, SMOKE, FUMES OR PRODS OF COMBUST. EVACUATE
NONESSENTIAL PERSONNEL FROM FIRE AREA.
Unusual Fire/Explosion Hazard: WATER SPRAY MAY BE INEFT. WATER MAY BE USED TO
COOL CLSD CNTNRS TO PVNT PRESS BUILD UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS
TO EXTREME HEAT. IF WATER IS (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF EXPOS EXCEEDS TLV, USE NIOSH/MSHA APPRVD SUPP-AIR
RESP OPER IN POS PRESS MODE. IF USE CNDTNS GEN AIRBORNE DUST, MATL SHOULD BE
HNDLD IN AN OPEN/WELL VENT AREA.WHEN ADEQ VENT IS NOT AVAIL,USE NIOSH/ MSHA
APPRVD ORG VAP RESP W/DUST,
Ventilation: LOC VENT SHOULD BE SUFF.USE VENT AS REQD TO CNTRL VAP CONCS.AVOID
PRLNGD/RPTD BRTHG OF VAPS.PROVIDE GEN DILUTION
Protective Gloves: NEOPRENE OR RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKER GOGGLES (FP N).
Other Protective Equipment: EMERG EYE WASH AND DELUGE SHOWER WHICH MEETS ANSI
DESIGN CRITERIA (FP N). PROTECTIVE CLOTHING SHOULD BE WORN.
Work Hygienic Practices: FOLLOW PRUDENT HYGIENIC PRACTICES.
Supplemental Safety and Health: MATLS TO AVOID: RADICAL FORMERS (PEROXIDES,
HYDRAZIDES, ALKALI METALS, STRONG LEWIS ACIDS). SPILL PROC: AIRBORNE DUST.
VACUUM/SCOOP UP SPILLED MATL FOR RECOVERY/DISP. AVOID DUSTING CNDTNS &
USE GOOD V ENT.WETTING SPILL W/WATER SPRAY MAY HELP TO KEEP AIRBORNE DUST
LEVS DOWN. EXPLO HAZ:USED, FOG NOZZ ARE PREF.VAPS
=======================================================
Physical/Chemical Properties
=======================================================
HCC: F4
B.P. Text: 293F,145C
Vapor Pres: 4.50 @ 68F
Vapor Density: HVR/AIR
Spec Gravity: 1.16 (FP N)
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: LIQUID.
Percent Volatiles by Volume: 55.15
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: SPARKS, OPEN FLAMES, HOT SURFACES, AND ALL
SOURCES OF HEAT AND IGNITION. HEAT ABOVE 150F.
Materials To Avoid: STRONG MINERAL ACIDS & OXIDIZING AGENTS. STRONG ACIDS,
ALKALIES, OXIDIZERS, AMINES, POLYM ACCELERATORS. FREE (SUPDAT)
Hazardous Decomposition Products: MAY PRDCE HAZ FUMES WHEN HEATED TO DECOMP.
FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE, & OXIDES OF NITROGEN.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: CATALYST OR HEAT.
=======================================================
Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
=======================================================
MSDS NAME: 60001 BLACK 67-11, 36711
Assigned IND: Y
Company: LILLY INDUSTRIES INC
Street: 210 E ALONDRA BLVD
City: GARDENA CA
Zipcode: 90248
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 11/11/1994
Status Code: C
Label Date: 11/11/1994
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: Slight
Hazard And Precautions: FLAMMABLE CLASS 1C. ACUTE: SKIN: MAY CAUSE IRRITATION
OR BLISTERING. EYE: MAY CAUSE MODERATE IRRITATION, TEARING, BURNING OR
REDNESS. INHALATION: OVEREXPOSURE MAY CAUSE RESPIRATORY IRRITATION OR NAUSE
A, EVEN UNCONSCIOUSNESS OR DEATH. CHRONIC: CANCER HAZARD. CONTAINS STYRENE
WHICH IS LISTED AS AN ANIMAL NERVOUS SYSTEM CARCINOGEN (FP N). REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING CONTENTS MAY BE HARMFUL OR FATAL. CONTAINS LEAD WHICH APPEARS ON
NAVY OCCUPATIONAL CHEMICA L REPRODUCTIVE HAZARDS LIST (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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