LAROCHE CHEMICALS INC -- CAUSTIC SODA 50%
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Material Safety Data Sheet
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NIIN: 01-051-3050
MSDS Num: BWMQZ
MSDS NAME: CAUSTIC SODA 50%
Responsible Party
Name: LAROCHE CHEMICALS INC
Address: 1134 JEFFERSON HWY
Box: 5500
City: GRAMERCY LA 70052
Info Phone: 800-528-4963
Emergency Phone Number: 504-869-2365/800-424-9300(CHEMTREC)
Preparer's Name: NOT KNOWN
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LAROCHE CHEMICALS INC
Address: AIRLINE HWY
Box: 1031
City: BATON ROUGE LA 70821
Phone: 504-356-8467
Name: LAROCHE CHEMICALS INC
Address: 1134 JEFFERSON HWY
Box: 5500
City: GRAMERCY LA 70052
Phone: 800-528-4963
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Item Description Information
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Item Manager: S9G
Item Name: SODIUM HYDROXIDE SOLUTION
Unit of Issue: DR
Quantitative Expression: 00000000055GL
UI Container Qty: 0
Type of Container: DRUM
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Ingredients
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Cas: 1310-73-2
RTECS #: WB4900000
Name: SODIUM HYDROXIDE (CERCLA)
% Wt: 49.5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 2 MG/M3
ACGIH TLV: C 2 MG/M3; 9495
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: LD50 (ORAL RAT) IS 500 MG/KG (10%)
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS.
ACUTE- INHALE:MIST MAY CAUSE DAMAGE TO RESPIRATORY TRACT & SEVERE
IRRITATION. EYE:CORROSIVE. MAY CAUSE INJURY & LOSS OF VISION.
SKIN:CORROSIVE. CAUSE S BURNS. ORAL:MODERATELY TOXIC. MAY CAUSE VOMITING,
COLLAPSE. CHRONIC- UNKNOWN.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: SEVERE EYE IRRITATION, SEVERE SKIN BURNS,
SEVERE GASTROINTESTINAL IRRITATION OR ULCERATION, SEVERE BURNS OF MOUTH AND
THROAT, SEVERE UPPER RESPIRATORY TRACT IRRITATION, IMPAIRED VISION, EVEN
BLINDNESS
Medical Cond Aggravated By Exposure: PERSONS WITH PRE-EXISTING SKIN DISORDERS
OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO
THE EFFECTS OF THE SUBSTANCE.
First Aid: GET IMMEDIATE MEDICAL HELP FOR ALL CASES OF EXPOSURE.
EYES/SKIN:FLUSH WITH WATER FOR 30 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE
TO FRESH AIR. PROVIDE CPR/OXYGEN IF NECESSARY. ORAL:DO NOT INDUCE VOM ITING.
IF CONSCIOUS, DRINK LARGE AMOUNTOF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON.
=======================================================
Handling and Disposal
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Spill Release Procedures: VENTILATE AREA. WEAR RUBBER OVERCLOTHING AND GLOVES.
REMOVE IGNITION SOURCES (H2). CONTAIN SPILL IF POSSIBLE. PICK UP BULK OF
LIQUID. TRANSFER INTO PLASTIC LINED STEEL CONTAINERS. DILUTE RESIDUAL MATE
RIAL WITH WATER AND NEUTRALIZE WITH WEAKACID.
Neutralizing Agent: ACETIC ACID
Waste Disposal Methods: DISPOSE OF IN COMPLIANCE WITH ALL CURRENT LOCAL, STATE
AND FEDERAL REGULATIONS. SMALL QUANTITIES MAY BE DILUTED AND NEUTRALIZED WITH
ACID. NEUTRALIZED SOLUTION MAY BE FLUSHED DOWN DRAIN IF PERMITTED. CALL NRC
AT 800-424-8802 IF NEEDED.
Handling And Storage Precautions: STORE AWAY FROM INCOMPATIBLE MATERIALS. KEEP
CONTAINERS SEALED. ADD CAUSTIC SODA LIQUID 50% TO WATER WITH ADEQUATE
AGITATION TO PREVENT BOILING.
Other Precautions: DO NOT GET IN EYES OR ON SKIN. DO NOT GENERATE MISTS. DO NOT
BREATHE MISTS. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. FOR
INDUSTRIAL USE ONLY. WASH THOROUGHLY AFTER HANDLING. DO NOT STORE IN
ALUMINUM, TIN, LEAD/ZINC CONTAINERS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONE
Extinguishing Media: WATER, CARBON DIOXIDE OR FOAM. A LARGE AMOUNT OF HEAT WILL
BE LIBERATED WHEN CAUSTIC LIQUID IS DILUTED WITH WATER.
Fire Fighting Procedures: WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE
POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard: MAY REACT WITH METALS GENERATING HYDROGEN GAS
WHICH WILL BURN OR EXPLODE IF IGNITED. MAY CAUSE FIRE ON CONTACT WITH
COMBUSTIBLES.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IN MISTY ATMOSPHERES, USE A NIOSH APPROVED RESPIRATOR
FOR MIST OR SELF-CONTAINED BREATHING APPARATUS.
Ventilation: GOOD GENERAL VENTILATION IS SUFFICIENT FOR MOST CONDITIONS (10
ROOM VOLUMES PER HOUR). LOCAL EXHAUST MAY BE NECESSARY.
Protective Gloves: RUBBER
Eye Protection: CHEMICAL SAFETY GOGGLES WITH SIDE SHIELD
Other Protective Equipment: RUBBER APRON, RUBBER BOOTS, EYE WASH AND SAFETY
SHOWER
Work Hygienic Practices: WASH THOROUGHLY BEFORE EATING, DRINKING OR SMOKING.
Supplemental Safety and Health: NOTE TO PHYSICIAN: CORROSIVE. MAY CAUSE
STRICTURE. IF LAVAGE IS PERFORMED, SUGGEST ENDOTRACHEAL AND/OR ESOPHAGOSCOPIC
CONTROL. IF BURN IS PRESENT, TREAT AS ANY THERMAL BURN, AFTER
DECONTAMINATION. EYE IRRIGATION MAY BE NECESSARY FOR AN EXTENDED PERIOD OF
TIME.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: B1
NRC/State LIC No: NOT RELEVANT
Boiling Point: =142.2C, 288.F
Vapor Pres: NONE
Vapor Density: NONE
Spec Gravity: 1.5
PH: >13
Evaporation Rate & Reference: NONE (CCL4=1)
Solubility in Water: COMPLETE
Appearance and Odor: COLORLESS LIQUID WITH NO DORO
Percent Volatiles by Volume: 0
Corrosion Rate: UNKNOWN
=======================================================
Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: CONTACT WITH METALS, WATER
Materials To Avoid: WATER, ACIDS, ALUMINUM, TIN, ZINC, BRONZE, BRASS, LEAD
Hazardous Decomposition Products: WHEN HEATED TO DECOMPOSITION, IT EMITS SODIUM
OXIDE (NA2O).
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 103221
MSDS NAME: CAUSTIC SODA 50%
MSDS Prepared Date: 09/01/1992
Review Date: 03/01/1995
Net Unit Weight: 687.0 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 0
Type Of Container: DRUM
Additional Data: 50% SOLUTION OF SODIUM HYDROXIDE.
=======================================================
Detail DOT Information
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DOT PSN Code: NGY
DOT Proper Shipping Name: SODIUM HYDROXIDE SOLUTION
Hazard Class: 8
UN ID Num: UN1824
DOT Packaging Group: II
Label: CORROSIVE
Special Provision: B2,N34,T8
Packaging Exception: 154
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 1 L
Max Qty Cargo: 30 L
Vessel Stow Req: A
=======================================================
Detail IMO Information
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IMO PSN Code: NTB
IMO Proper Shipping Name: SODIUM HYDROXIDE, SOLUTION
IMDG Page Number: 8226
UN Number: 1824
UN Hazard Class: 8
IMO Packaging Group: II/III
Subsidiary Risk Label: -
EMS Number: 8-06
MED First Aid Guide NUM: 705
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: WST
IATA UN ID Num: 1824
IATA Proper Shipping Name: SODIUM HYDROXIDE SOLUTION
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: II
Packing Note Passenger: 809
Max Quant Pass: 1L
Max Quant Cargo: 30L
Packaging Note Cargo: 813
Exceptions: A3
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: WST
AFI Proper Shipping Name: SODIUM HYDROXIDE, SOLUTION
AFI Hazard Class: 8
AFI UN ID NUM: UN1824
AFI Packing Group: II
Special Provisions: P5, N34
Back Pack Reference: A12.3
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: CAUSTIC SODA 50%
Company: LAROCHE CHEMICALS INC
Street: 1134 JEFFERSON HWY
PO Box: 5500
City: GRAMERCY LA
Zipcode: 70052
Health Emergency Phone: 504-869-2365/800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 03/01/1995
Status Code: C
MFG Label NO: NOT RELEVANT
Label Date: 03/01/1995
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Moderate
Hazard And Precautions: TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS.
ACUTE- CORROSIVE. INHALE:MIST MAY DAMAGE RESPIRATORY TRACT. EYE:MAY CAUSE
INJURY & LOSS OF VISION. SKIN:CAUSES BURNS. ORAL:MODERATELY TOXIC.
CHRONIC- UNKNOWN. STORE AWAY FROM INCOMPATIBLES. PICK UP SPILL. TRANSFER
INTO PLASTIC LINED STEEL CONTAINERS. FIRST AID- GET IMMEDIATE MEDICAL HELP
FOR ALL CASES OF EXPOSURE. EYES/SKIN:FLUSH WITH WATER FOR 30 MINUTES. HOLD
EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IFNECESSARY.
ORAL:DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNT OF MILK/WATER.
NEVER GIVE ANYTHING BY MOUTH TO A N UNCONSCIOUS PERSON.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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