LABCHEM INC -- CHROMIC ACID, 10%, LC13100
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BWLYS
MSDS NAME: CHROMIC ACID, 10%, LC13100
Responsible Party
Name: LABCHEM INC
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Info Phone: 412-826-5230
Emergency Phone Number: 412-826-5230
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LABCHEM INC
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Phone: 412-826-5230
Name: LABCHEM, INC.
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Phone: 412-826-5230
=======================================================
Ingredients
=======================================================
Cas: 1333-82-0
RTECS #: GB6650000
Name: CHROMIUM (VI) OXIDE (1:3); (CHROMIUM TRIOXIDE, 10%) LD50: (ORAL, RAT)
80 MG/KG
% Wt: 10
OSHA PEL: 0.5 MG CR/M3
ACGIH TLV: 0.05 MG CR/M3
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: BALANCE
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: FIRST AID PROC: FOR AT LEAST 15 MIN, LIFTING UPPER/LOWER LIDS OCCAS UNTIL
ALL TRACE OF CHEM IS GONE. FOR BURNS,
-----------------------------
Name: ING 3: COVER EYES W/LOOSE STERILE, NON-MEDICATED BANDAGES. GET MED AID AT
ONCE. INGEST: GIVE CONSCIOUS VICTIM LG
-----------------------------
Name: ING 4: QTYS OF WATER/MILK TO DILUTE ACID. DO NOT INDUCE VOMIT OR USE
GASTRIC LAVAGE. GET MED AID AT ONCE.
-----------------------------
Name: RESP PROT: FLOW MODE. ESCAPE: NIOSH/MSHA APPRVD SCBA.
-----------------------------
Name: EYE PROT: AND FULL LENGTH FACESHIELD (FP N).
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENT 1
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: EYE, NOSE, THROAT, RESPIRATORY IRRITANT; MAY
PRODUCE BURNS & ULCERS. SYMPTOMS INCLUDE HEADACHE, COUGH, FLUID IN LUNGS,
BRONCHITIS, CHEST PAINS, EMPHYSEMA, LIVER & KIDNEY DAMAGE,
CONJUNCTIVITIS, CORNEAL DAMAGE (POSSIBLE BLINDNESS), ABDOMINAL PAIN,
VOMITING & DIARRHEA. CHRONIC: SENSITIZATION (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CHROMIUM (VI) OXIDE (1:3): IARC MONOGRAPHS ON
EVALUATION OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 49, 1990: (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: DERMATITIS, ULCERATION &
PERFORATION OF THE RESPIRATORY TRACT, DISCOLORATION OF TEETH & POTENTIAL
CARCINOGENIC EFFECTS. CERTAIN SALTS OF CHROMIUM ARE IMPLICATED IN INCREASED
INCIDENCE OF LUN G CANCER AMONG WORKERS EXPOSED; POSSIBILITY OF OTHER TUMOR
SITES EXISTS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL: MOVE TO FRESH AIR. GIVE ARTF RESP IF NEC. MAINTAIN AIRWAY
(THROAT MAY SWELL) & BLOOD PRESS; ADMIN OXYGEN IF NEEDED. KEEP WARM, AT
REST. GET MED AID AT ONCE. SKIN: REMOVE CONTAMD CLTHG & SHOES I MMED.
WASH W/MILD SOAP; FLUSH W/LG AMTSOF WATER (15-20 MIN) UNTIL CHEM IS GONE.
COVER BURNS W/DRY STERILE DRESSING (SECURE, NOT TIGHT). GET MED AID AT ONCE.
EYES: FLUSH W/LG AMTS OF WATER
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: CONTAIN IF POSS. ABSORB W/CEMENT, FLY ASH,
DIATOMACEOUS EARTH OR SUITABLE INERT MATL. MAY BE NEUTRALIZED W/LIME, CRUSHED
LIMESTONE, SODIUM BICARBONATE TO PH OF 7. SCOOP MATL INTO PLASTIC CNTNR FOR
DIS P. LABEL CNTNR, INDICATE MATL CONTAINS CHROMIUM.
Neutralizing Agent: MAY BE NEUTRALIZED W/LIME, CRUSHED LIMESTONE, SODIUM
BICARBONATE TO A PH OF 7.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. KEEP OUT OF SEWERS AND DRAINS WHERE HARMFUL CHEMICAL REACTIONS
COULD OCCUR OR CHROMIUM MAY PERSIST IN THE ENVIRONMENT.
Handling And Storage Precautions: STORE AS CORROSIVE ACID. PROTECT FROM HEAT
& INCOMPATIBLE MATERIALS. KEEP CONTAINERS CAPPED. STORE IN
GLASS/POLYETHYLENE - NO UNMARKED CONTAINERS.
Other Precautions: DO NOT POUR WASTE INTO DRAINS OR SEWERS. DO NOT WEAR CONTACT
LENSES WHEN WORKING WITH CHEMICALS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NON-FLAMMABLE
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY, FOG OR FOAM FOR
LARGE FIRES.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). KEEP CONTAINERS COOL; MOVE IF POSSIBLE. AVOID BREATHING
TOXIC & CORROSIVE VAPORS - KEEP UPWIND.
Unusual Fire/Explosion Hazard: NEGLIG FIRE HAZ; MOD FIRE & EXPLO HAZ WHEN
IN CNTCT W/METALS (EXPLO HYDROGEN GAS IS FORMED) OR COMBUST ORGANIC OR
READILY OXIDIZABLE MATLS. WHEN TOX (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: AT 5MG/M3 & 50MG/M3 H*2SO*4 - USE NIOSH/MSHA APPRVD
SUPPLIED AIR RESP W/FULL FACEPIECE (SAF) OR NIOSH/MSHA APPRVD SCBA W/FULL
FACEPIECE. AT 20MG/M3 CR & 100MF/M3 H*2SO*4 - USE NIOSH/MSHA APPRVD SAF
IN PRESS DEMAND OR CONTINUOUS
Ventilation: PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION TO MEET
PERMISSABLE EXPOSURE LIMITS (PEL).
Protective Gloves: ACID PROOF GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS
Other Protective Equipment: DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N).
PROVIDE EYE-WASH FOUNTAIN IN IMMED WORK AREA. WEAR ACID PROOF CLTHG.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLO HAZ: CHROMIUM TRIOXIDE IS FORMED, OXYGEN
IS ALSO RELEASED INCREASING FIRE HAZ. MATLS TO AVOID: ALCOHOLS, FUELS, ACETIC
ANHYDRIDE, PYRIDINE, NITRIC & PERCHLORIC ACIDS. EXPLAN OF CARCIN: GROUP
1. NTP 7TH ANNUAL REPORT ON CARCINS, 1991:KNOWN TO BE CARCIN. HUMAN:LUNG
TUMORS.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: T6
Vapor Pres: 14 @ 20C
Spec Gravity: >1
PH: ACIDIC
Evaporation Rate & Reference: >1 ETHER =1
Solubility in Water: SOLUBLE
Appearance and Odor: CLEAR ORANGE SOLUTION; ODORLESS.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT OR EXPOSURE TO ORGANIC MATERIALS THAT RESULT
IN VIOLENT EXOTHERMIC REACTIONS.
Materials To Avoid: REACTS VIOLENTLY OR EXPLO W/METALS (ESP POWDERED),
CARBIDES, CHLORATES, FULMINATES, PICRATES, PERMANGANATES, (SUPDAT)
Hazardous Decomposition Products: THERMAL DECOMPOSITION RESULTS IN POSSIBLE
TRIVALENT CHROMIUM FORMATION WITH LIBERATED OXYGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: CHROMIC ACID, 10%, LC13100
Assigned IND: Y
Company: LABCHEM INC
Street: 200 WILLIAM PITT WAY
City: PITTSBURGH PA
Zipcode: 15238
Health Emergency Phone: 412-826-5230
Label Required IND: Y
Date Of Label Review: 01/11/1995
Status Code: C
Label Date: 01/11/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: FIRE/EXPLOSION HAZARD IN CONTACT WITH METALS, ALCOHOLS,
FUELS & OTHER MATERIALS. ACUTE: EYE, NOSE, THROAT, RESPIRATORY IRRITANT;
MAY PRODUCE BURNS & ULCERS. SYMPTOMS INCLUDE HEADACHE, COUGH, FLUID IN
LUNGS, BRONCHITIS, CHEST PAINS, EMPHYSEMA, LIVER & KIDNEY DAMAGE,
CONJUNCTIVITIS, CORNEAL DAMAGE (POSSIBLE BLINDNESS), ABDOMINAL PAIN, VOMITING
& DIARRHEA. CHRONIC: CANCER HAZARD. CONTAINS CHROMIUM (V I) OXIDE (1:3),
WHICH IS LISTED AS A HUMAN LUNG CARCINOGEN (FP N). SENSITIZATION DERMATITIS,
ULCERATION & PERFORATION OF THE RESPIRATORY TRACT, DISCOLORATION OF
TEETH.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|