===================== Product Identification =====================
MSDS NAME:CRYSTALLINE SILICA (QUARTZ)
NIIN:00N027796
MSDS Number: BPCVL
=== Responsible Party ===
Company:WHIBCO INC
Address:RIVER ROAD
Box:259
City:LEESBURG
State:NJ
ZIP:08327
Country:US
Info Phone Num:609-785-2090
Emergency Phone Num:609-785-2090
CAGE:WHIBC
=== Contractor Identification ===
Company:WHIBCO INC
Address:RIVER ROAD
Box:259
City:LEESBURG
State:NJ
ZIP:08237
Country:US
Phone:609-785-2090
CAGE:WHIBC
============= Composition/Information on Ingredients =============
Name:SILICA, CRYSTALLINE-QUARTZ; (CRYSTALLINE QUARTZ) (SILICON
DIOXIDE). OTHER REC LIMIT: 0.05 MG/M3 RDUST (NIOSH).
CAS:14808-60-7
RTECS #:VV7330000
Other REC Limits:SEE INGREDIENT NAME
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Name:SUPP DATA:TEST NIOSH/MSHA APPRVD RESP I/A/W OSHA
REGS.MAINTAIN & TEST VENT & DUST COLLECTION EQUIP.WASH/VACCUM (ING
3)
RTECS #:9999999ZZ
Name:ING 2:CLTHG WHICH HAS BECOME DUSTY.WE REC SMOKING BE
PROHIBITED IN ALL AREAS WHERE NIOSH/MSHA APPRVD RESP MUST BE(ING 4)
RTECS #:9999999ZZ
Name:ING 3: USED. WARN YOUR EMPLOYEES (AND YOUR CUSTOMERS-USERS
IN CASE OF RESALE) BY POSTING & OTHER MEANS OF THE (ING 5)
RTECS #:9999999ZZ
Name:ING 4: HAZARD AND OSHA PRECAUTIONS TO BE USED. PROVIDE
TRAINING FOR YOUR EMPLOYEES ABOUT THE OSHA PRECAUTIONS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:(ACUTE & CHRONIC) PRLNGD EXPOS TO RESP
CRYSTALLINE QUARTZ MAY CAUSE DELAYED (CHRONIC) LUNG INJURY
(SILICOSIS). ACUTE/RAPIDLY DEVELOPING SILICOSIS MAY OCCUR IN SHORT
PERIOD OF TIME IN HEAVY EXPOS IN CE RTAIN OCCUP SUCH AS
SANDBLASTERS. SILICOSIS IS FORM OF DISABLING PULM FIBROSIS WHICH
CAN BE PROGRESSIVE & LEAD TO DEATH.
Explanation of Carcinogenicity:SILICA CRYSTALLINE (QUARTZ): ANTICIPATED
TO BE A CARCINOGEN (NTP), GROUP 2A (IARC).
Effects of Overexposure:UNDUE BREATHLESSNESS, WHEEZING, COUGH, AND
SPUTUM PRODUCTION.
Medical Cond Aggravated by Exposure:PULM FUNC MAY BE REDUCED BY INHAL
OF RESP SILICA. ALSO LUNG SCARRING PRODUCED BY SUCH INHAL MAY LEAD
TO A PROGRESSIVE MASSIVE FIBROSIS OF THE LUNG WHICH MAY AGGRAVATE
OTHER PULM CNDTNS & (SUPP DATA)
======================= First Aid Measures =======================
Eyes: WASH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. IF
IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. INHAL: REMOVE PERSON
IMMEDIATELY TO FRESH AIR, GIVE ARTF RESP AS NEEDED, SEEK MEDICAL
ATTN AS NEEDED. INGEST: CALL MD IMMEDIATELY . SKIN: FLUSH WITH
COPIOUS AMOUNTS OF WATER. CALL MD .
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NONE REQUIRED; SAND MAY BE USED AS EXTINGUISHING
MEDIA.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CRYSTALLINE SILICA IS NEITHER A FIRE NOR
AN EXPLOSION HAZARD. CRYSTALLINE SILICA MAY BE USED TO PUT OUT
CLASS A AND B FIRES.
================== Accidental Release Measures ==================
Spill Release Procedures:USE DUSTLESS METHODS (VACUUM) AND PLACE INTO
CLOSABLE CONTAINER FOR DISPOSAL, OR FLUSH WITH WATER. DO NOT DRY
SWEEP. WEAR PROTECTIVE EQUIPMENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID BREAKAGE OF BAGGED MATERIAL OR
SPILLS OF BULK MATERIAL.
Other Precautions:USE DUSTLESS SYSTEMS FOR HNDLG, STORAGE & CLEAN UP SO
THAT AIRBORNE DUST DOES NOT EXCEED PEL. USE ADEQ VENT & DUST
COLLECTION. PRACTICE GOOD HOUSEKEEPING. DO NOT PERMIT DUST TO
COLLECT ON WALLS, FLOOR S, SILLS, LEDGES, MACHINERY, (SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ONLY NIOSH/MSHA APPROVED EQUIPMENT SHOULD BE
USED. (SEE 29 CFR 1910.134). FOR ADDITIONAL INFORMATION REFER TO
ORIGINAL MSDS . SEE ANSI STANDARD Z88.2-1980 "PRACTICES FOR
RESPIRATORY PROTECTION".
Ventilation:USE ADEQ VENT & DUST COLLECTION. SEE ANSI STANDARD
Z9.4-1984 "VENT & SAFE PRACTICES OF ABRASIVE BLASTING OPER".
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:SEE ASTM STANDARD PRACTICE E1132-86, "STANDARD
PRACTICE FOR HLTH REQ RELATING TO OCCUP EXPOS TO QUARTZ DUST".
Supplemental Safety and Health
MATL TO AVOID: DIFLUORIDE, MAY CAUSE FIRES. MED CNDTNS: DISEASES AND
WHICH INCREASES SUSCEPTIBILITY TO PULM TUBERCULOSIS. PROGRESSIVE
MASSIVE FIBROSIS MAY BE ACCOMPANIED BY RIGHT HEART ENLARGEMENT, HE
ART FAILURE & PULM FAILURE. SMOKING AGGRAVATES EFTS OF EXPOS. OTHER
PREC: OR EQUIP. MAINTAIN, CLEAN, AND FIT (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:4046F,2230C
Melt/Freeze Pt:M.P/F.P Text:3050F,1677C
Vapor Pres:NONE
Vapor Density:NONE
Spec Gravity:2.65 (H*2O=1)
Evaporation Rate & Reference:NONE (BUTYL ACETATE = 1)
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE OR TAN SAND, GRANULAR, CRUSHED, OR GROUND -
NO ODOR OR TASTE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTACT WITH POWERFUL OXIDIZING AGENTS SUCH AS FLUORINE, CHLORINE
TRIFLUORIDE, MANGANESE TRIOXIDE, OXYGEN (SUPP DATA)
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:SILICA WILL DISSOLVE IN HYDROFLUORIC
ACID AND PRODUCE A CORROSIVE GAS - SILICON TETRAFLUORIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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