===================== Product Identification =====================
MSDS NAME:ETHYLENE GLYCOL
NIIN:00-006-4205
MSDS Number: BQKLS
=== Responsible Party ===
Company:EXCITON CHEMICAL CO INC
Address:400 LINDEN AVE
Box:31126
City:DAYTON
State:OH
ZIP:45431
Country:US
Info Phone Num:513-252-2989
Emergency Phone Num:513-252-2989
Preparer's Name:LARRY KNAAK
CAGE:9Z504
=== Contractor Identification ===
Company:EXCITON CHEMICAL CO INC
Address:400 LINDEN AVE
Box:31126
City:DAYTON
State:OH
ZIP:45431
Country:US
Phone:513-252-2989
CAGE:9Z504
============= Composition/Information on Ingredients =============
Name:ETHYLENE GLYCOL (SARA III)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: >99%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 50 PPM
ACGIH TLV:C 50 PPM,VAPOR; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:ACUTE ORAL LD50 (RAT) IS 4 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. VAPOR OR MIST IS IRRITATING TO THE
EYES, MUCOUS MEBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN
IRRITATION. PROLONGED EXPOSURE CAN CAUSE NAUSEA, HEADACHE AND
VOMITING. CHRONIC: MAY CAUSE REPRODUCTIVE DISORDERS; DAMAGE TO THE
KIDNEYS.
Explanation of Carcinogenicity:THIS MATERIAL IS NOT CONSIDERED TO BE A
CARCINOGEN BY NTP, IARC OR OSHA.
Effects of Overexposure:ACUTE: MAY BE HARMFUL BY INHALATION, INGESTION,
OR SKIN ABSORPTION. VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS
MEBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION.
PROLONGED EXPOSURE CAN CAUSE NAUSEA, HEADACHE AND VOMITING.
CHRONIC: MAY CAUSE REPRODUCTIVE DISORDERS; DAMAGE TO THE KIDNEYS.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF KIDNEY
DISORDERS MAYBE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. ASSURE ADEQUATE FLUSHING OF THE
EYES BY SEPARAT ING THE EYELIDS WITH FINGERS. IF INHALED, REMOVE TO
FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION, PREFERABLY
MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:230F,110C
Lower Limits:3.2
Upper Limits:15.3
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLED,
RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE
AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND
WASH SPILL SITE AFTER MATE RIAL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, AREA. KEEP
CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM
PHYSICAL DAMAGE.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID
PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR
INDUSTRIAL USE ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR
CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29
CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR
SELECTION.
Ventilation:MECHANICAL VENTILATION IS REQUIRED. LOCAL EXHAUST IS NEEDED
IF VENTED INTO WORK AREA.
Protective Gloves:NEOPRENE, NITRILE, PVC OR NATURAL RUBBER
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
HARMFUL LIQUID. REPRODUCTIVE HAZARD. IRRITANT.
================== Physical/Chemical Properties ==================
HCC:V5
Boiling Pt:=196.1C, 385.F
Melt/Freeze Pt:=-12.6C, 9.F
Vapor Pres:0.08
Vapor Density:2.1
Spec Gravity:1.113
Evaporation Rate & Reference:<0.01(N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID. MILD ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON
MONOXIDE AND CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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