===================== Product Identification =====================
MSDS NAME:1,4-DIOXANE
NIIN:00-174-6592
MSDS Number: BQKMW
=== Responsible Party ===
Company:FISHER SCIENTIFIC CO CHEMICAL DIV.
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100 OR 201-796-7523
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)
CAS:123-91-1
RTECS #:JG8225000
Fraction by Wt: 100.0%
Other REC Limits:NONE SPECIFIED BY M.
OSHA PEL:S, 100 PPM
ACGIH TLV:S, 25 PPM; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL, RABBIT = 2000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYE:CAUSES IRRITATION.
SKIN:IRRITATION. INHALATION:IRRITATION OF RESPIRATORY TRACT,
SYSTEMIC INJURY. INGESTION:GASTROINTESTINAL IRRITATION, LIVER AND
KIDNEY DAMAGE. CHRONIC: DERMATITIS, LIVER AN D KIDNEY DAMAGE,
LEUKEMIA, CANCER.
Explanation of Carcinogenicity:LISTED AS ANTICIPATED CARCINOGEN (NTP),&
POSSIBLY CARCINOGEN (IARC).
Effects of Overexposure:EYE:IRRITATION, REDNESS, BLURRED VISION.
SKIN:IRRITATION, REDNESS. INHALATION:COUGHING, DIZZINESS, NAUSEA,
FATIGUE, HEADACHE, ASPHYXIATION/ UNCONSCIOUSNESS. INGESTION:NAUSEA,
VOMITING & DIARRHEA.
Medical Cond Aggravated by Exposure:SKIN, LIVER AND KIDNEY.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:WASH WITH
SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES,HOLDING EYELIDS
OPEN. INHALATION:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF
NEEDED. INGESTI ON:DO NOT INDUCE VOMITING, KEEP WARM, GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:54.0F,12.2C
Autoignition Temp:Autoignition Temp Text:350F
Lower Limits:2.0
Upper Limits:22.0%
Extinguishing Media:CO2, FOAM, DRY CHEMICAL OR HALON. WATER SPRAY MAY
BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-
APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPOR-AIR MIXTURE ARE EXPLOSIVE. VAPORS
ARE HEAVIER THAN AIR & MAY TRAVEL LONG DISTANCE TO A SOURCE OF
IGNITION AND FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT.ELIMINATE SOURCES OF
IGNITION.VENTILATE THE AREA.STOP LEAK IF POSSIBLE.CONTAIN THE
SPILL.PICK UP LARGE SPILL WITH NON-SPARKING TOOLS;SMALL
SPILLS/RESIDUE WITH ABSORBENT MATER IAL.PLACE IN NON-LEAK
CONTAINERS.CONTAINRUN-OFF.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE IN COOL,DRY,WELL
VENTILATED AREA AWAY FROM ACIDS,ALKALIES & IGNITION SOURCES.
Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT.
WASH WITH SOAP AND WATER BEFORE EATING OR DRINKING. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. KEEP OUT OF SURFACE WATERS AND
SEWERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS ARE INADEQUATE TO
CONTROL VAPOR CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A
NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR SHOULD BE WORN.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GLASSES/GOGGLES/FACE SHIELD
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:214F,101C
Vapor Pres:40 MMHG
Vapor Density:3.0
Spec Gravity:1.0337
Evaporation Rate & Reference:2.7 (BU-ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID,ETHEREAL ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, FLAME AND OTHER IGNITION
SOURCES
Hazardous Decomposition Products:IRRITATING AND/OR TOXIC FUMES
INCLUDING CO AND CO2 MAY BE RELEASED.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE IN A CHEMICAL LANDFILL AS
APPROVED BY CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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