===================== Product Identification =====================
MSDS NAME:SODIUM SULFIDE, 9-HYDRATE
NIIN:00-234-8378
MSDS Number: BQKNP
=== Responsible Party ===
Company:J.T. BAKER INC.
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:201-859-2151
Emergency Phone Num:201-859-2151, CHEMTREC 800-424-9300
CAGE:HO785
=== Contractor Identification ===
Company:J.T. BAKER INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:202-483-7616
CAGE:HO785
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:SODIUM SULFIDE, NONAHYDRATE
CAS:1313-82-2
RTECS #:WE1910000
Minumum % Wt:90.
Maxumum % Wt:100.
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (INTERPERITONEAL-MOUSE) 53 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE- CORROSIVE. INHALATION: SEVERE
IRRITATION TO UPPER RESPIRATORY TRACT. EYE/SKIN: SEVERE IRRITATION,
BURNS. INGESTION:SEVERE BURNS TO MOUTH, THROAT AND STOMACH.
CHRONIC- DERMATITIS, CONJUNCTIVITIS , HEADACHE.
Effects of Overexposure:INHALATION: COUGHING, SORE THROAT. EYES AND
SKIN:IRRITATION, REDNESS & PAIN. INGESTION: ABDOMINAL PAIN,
NAUSEA, VOMITING. MAY CAUSE SUDDEN COLLAPSE & DEATH.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IMMEDIATELY. EYE:IMMEDIATELY FLUSH WITH
WATER FOR AT LEAST 15 MINUTES HOLDING EYELIDS OPEN. SKIN:WASH WITH
SOAP & WATER. INHAL:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF
NEEDED. INGESTION:IF CONSCIOUS, DRINK MILK/WATER. CALL A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CO2, FOAM/DRY CHEMICAL. WATER SPRAY
MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS
AWAY.
Fire Fighting Procedures:WEAR NIOSH-APPROVED+PRESSURE SELF-CONTAINED
BREATHING APPARATUS WITH FULL FACEPIECE.FOR MASSIVE FIRE,USE
UNMANNED HOSE HOLDER.MOVE CONTAINERS AWAY IF POSSIBLE.
Unusual Fire/Explosion Hazard:VAPORS MAY FORM EXPLOSIVE MIXTURE WITH
AIR. CLOSED CONTAINERS MAY EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROPER PROTECTIVE EQUIPMENT. VENTILATE
AREA. DO NOT RELEASE INTO SOIL, SEWER, STREAM. STOP LEAK IF
POSSIBLE. WITH CLEAN SHOVEL, PLACE MATERIAL INTO CLEAN CONTAINER
FOR DISPOSAL. FOR LARGE SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER
DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE REFRIGERATED AT 2-8C,
AWAY FROM INCOMPATIBLE MATERIALS, SPARKS AND FLAMES IN A WELL
VENTILATED AREA.
Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY. FLAMMABLE,
POISONOUS GASES MAY ACCUMULATE IN TANKS. DO NOT BREATHE DUSTS.
AVOID CONTACT WITH EYES AND SKIN. WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR SUPPLIED-AIR
RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR
OTHER POSITIVE PRESSURE MODE .
Ventilation:LOCAL EXHAUST
Protective Gloves:RUBBER
Eye Protection:SAFETY GLASSES
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:B1
Boiling Pt:=173.9C, 345.F
Melt/Freeze Pt:=50.C, 122.F
Spec Gravity:1.86
Solubility in Water:10%
Appearance and Odor:WHITE TO YELLOW CRYSTALS, HYDROGEN SULFIDE ODOR
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CARBON, DIAZONIUM CHLORIDE SALTS, ACIDS, ZINC, ALUMINUM, OXIDANTS
Stability Condition to Avoid:FLAMES, EXCESSIVE HEAT, MOISTURE
Hazardous Decomposition Products:TOXIC OXIDES OF SULFUR AND HYDROGEN
GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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