===================== Product Identification =====================
MSDS NAME:P3653 PHENOL
NIIN:00F030308
MSDS Number: BRXZR
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO SUB OF SIGMA-ALDRICH
Address:1001 W ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Info Phone Num:800-325-5832-S/800-231-8327-A
Emergency Phone Num:800-325-5832-S/800-231-8327-A
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
Name:PHENOL, CARBOLIC ACID SOLUTION; HYDROXYBENZENE
CAS:108-95-2
RTECS #:SJ3325000
Other REC Limits:5 MG/CUM
OSHA PEL:19 MG/CUM
ACGIH TLV:19 MG/CUM (SKIN)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 317 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED/INHALED/ABSORBED
THROUGH SKIN. EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS
MEMBRANES/UPPER RESPIRATORY TRACT/EYES/SKIN. INHALATION MAY BE
FATAL AS A RESULT OF SPASM/INFLAMMATION/EDE MA OF LARYNX/BRONCHI,
CHEMICAL PNEUMONITIS & PULMONARY EDEMA. DAMAGE TO LIVER/KIDNEYS.
DERMATITIS. CNS DISTURBANCES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA &
VOMITING.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS WHILE
REMOVING CONTAMINATED CLOTHING & SHOES. INHALATION: REMOVE TO FRESH
AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIF FICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH W/WATER PROVIDED
PERSON IS CONSCIOUS. WASH CONTAMINATED CLOTHING BEFORE REUSE.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:175F
Lower Limits:1.7%
Upper Limits:8.6%
Extinguishing Media:CO2, DRY CHEMICAL POWDER OR APPROPRIATE FOAM, WATER
SPRAY.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
AUTOIGNITION TEMPERATURE: 1319F. COMBUSTIBLE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. COVER W/DRY LIME OR
SODA ASH, PICK UP. KEEP IN CLOSED CONTAINER & HOLD FOR WASTE
DISPOSAL. VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICKUP IS
COMPLETE. EVACUATE AREA.
Neutralizing Agent:DRY LIME OR SODA ASH
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. PRODUCT IS LIGHT
SENSITIVE. KEEP AWAY FROM HEAT & OPEN FLAME. REFRIGERATE. VESICANT.
COMBUSTIBLE.
Other Precautions:AVOID CONTACT W/EYES, SKIN, CLOTHING OR BREATHING OF
VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE AN APPRORPIATE NIOSH/MSHA APPROVED
RESPIRATOR.
Ventilation:CHEMICAL FUME HOOD
Protective Gloves:CHEMICAL RESISTANT, HEAVY RUBBER
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:RUBBER BOOTS, SAFETY SHOWER, EYE BATH
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:182C
Melt/Freeze Pt:M.P/F.P Text:40-42C
Vapor Pres:0.36
Vapor Density:3.24
Spec Gravity:1.071
Appearance and Odor:WHITE CRYSTALS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES, STRONG ACIDS
Stability Condition to Avoid:EXPOSURE TO LIGHT, HEAT & OPEN FLAME
Hazardous Decomposition Products:TOXIC FUMES OF CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN
AFTERBURNER & SCRUBBER. OBSERVE ALL FEDERAL, STATE & LOCAL LAWS.
UN1671, UN2312, UN2821
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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