===================== Product Identification =====================
MSDS NAME:W21780-8 BUTYL ALCOHOL,99.5+%,FCC
NIIN:00F030294
MSDS Number: BRXYZ
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO SUB OF SIGMA-ALDRICH
Address:1001 W ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Info Phone Num:800-325-5832-S/800-231-8327-A
Emergency Phone Num:800-325-5832-S/800-231-8327-A
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
Name:BUTANOL, N-BUTYL ALCOHOL, PROPYL CARBINOL, BUTYL ALCOHOL
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: >99.5%
Other REC Limits:300 MG/CUM
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 790 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL FOR INGESTION/INHALATION/SKIN
ABSORPTION. DESTRUCTIVE TO TISSUES OF UPPER RESPIRATORY
TRACT/EYES/SKIN. CNS DEPRESSION/GI
DISTURBANCES/LIVER/KIDNEY/BLOOD/EAR/SENSE ORGANS/SPECIAL
SENSES/LUNGS/T HORAX/URETER/BLADDER EFFECTS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OR BREATH, HEADACHE, NAUSEA, & VOMITING.
======================= First Aid Measures =======================
Eyes: FLUSH IMMEDIATELY FLUSH W/WATER FOR 15 MINS. ASSURE
ADEQUATE FLUSHING BY SEPARATING THE EYELIDS. SKIN: FLUSH W/WATER
FOR 15 MINS. REMOVE CONTAMINATED CLOTHING & SHOES. WASH
CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH
AIR. IF NECESSARY, GIVE OXYGEN OR CPR. INGESTION: WASH OUT MOUTH
W/WATER IF CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:95F
Lower Limits:1.4%
Upper Limits:11.2%
Extinguishing Media:CO2, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. WATER
MAY BE INEFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHING.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IGNITION & FLASH BACK. CONTAINER EXPLOSION MAY OCCUR
UNDER FIRE CONDITIONS. AUTOIGNITION TEMP: 649F.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL IGNITION SOURCES.
WEAR PROTECTIVE EQUIPMENT. COVER W/ACTIVATED CARBON ADSORBENT, TAKE
UP & PLACE IN CLOSED CONTAINERS. TRANSPORT OUTDOORS. VENTILATE AREA
& WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DON'T BREATHE VAPOR. AVOID CONTACT
W/SKIN, EYES, OR CLOTHING. KEEP TIGHTLY CLOSED. STORE IN COOL DRY
PLACE. KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:NO SMOKING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT (HEAVY RUBBER)
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:OTHER PROTECTIVE CLOTHING, FACESHIELD
(8-INCH MINIMUM), SAFETY SHOWER, EYE BATH, RUBBER BOOTS
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
THIS MATERIAL IS HYGROSCOPIC.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:117-119F
Melt/Freeze Pt:M.P/F.P Text:-89-0C
Vapor Pres:4
Vapor Density:2.55
Spec Gravity:0.808
Appearance and Odor:COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACID CHLORIDES/ACID ANHYDRIDES/OXIDIZING AGENTS/REDUCING AGENTS/COPPER
& COPPER ALLOYS/ALUMINUM/ALKALI METALS
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, & OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:TOXIC FUMES OF CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN CHEMICAL INCINERATOR EQUIPPED
W/AFTERBURNER & SCUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE. FLAMMABLE LIQUID. OBSERVE ALL
FEDERAL, STATE, & LOCAL LAWS. UN 1120 . RCRA WASTE NUMBER: U031.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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