===================== Product Identification =====================
MSDS NAME:199259 DIACETONE ALCOHOL
NIIN:00F030279
MSDS Number: BRXYH
=== Responsible Party ===
Company:SHELL CANADA CHEMICAL CO
Address:75 WYNFORD DR
City:DON MILLS
State:ON
Country:US
Info Phone Num:416-443-7270
Emergency Phone Num:416-443-7270
CAGE:36131
=== Contractor Identification ===
Company:SHELL CHEMICALS CANADA LIMITED
Address:400 4TH AVE SW STATION C
Box:4280
City:CALGARY, ALBERTA CANADA
Phone:403-691-2638/800-567-8860
CAGE:36131
============= Composition/Information on Ingredients =============
Name:DIACETONE ALCOHOL
CAS:123-42-2
RTECS #:SA9100000
Fraction by Wt: 100%
Other REC Limits:50 PPM
OSHA PEL:240 MG/CUM
ACGIH TLV:238 MG/CUM
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): >4000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: DEFATTING,
DERMATITIS, & IRRITATION. INHALATION: CNS DEPRESSION. ACCIDENTAL
INGESTION IS THE MOST LIKELY ROUTE OF EXPOSURE AS THE MATERIAL IS
POORLY & INCOMPLETELY ABSORBED THR OUGH SKIN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: HEADACHE, DIZZINESS, NAUSEA. EYES:
IRRITATION. SKIN: DRYING & IRRITATION.
======================= First Aid Measures =======================
Eyes: FLUSH W/WATER FOR AT LEAST 15 MINS WHILE HOLDING
EYELIDS OPEN. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T
INDUCE VOMITING. GUARD AGAINST ASPIRATION INTO LUNGS BY HAVING
INDIVIDUAL TURN ON LEFT SIDE. DON'T GIVE ANYTHING BY MOUTH IF
UNCONSCIOUS. SKIN: WASH CONTAMINATED SKIN W/MILD SOAP & WATER.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:52C
Lower Limits:1.8%
Upper Limits:6.9%
Extinguishing Media:DRY CHEMICAL, CO2, WATER SPRAY OR FOG
Fire Fighting Procedures:DON'T ENTER CONFINED FIRE SPACE W/OUT ADEQUATE
PROTECTIVE CLOTHING & AN APPROVED POSITIVE PRESSURE SCBA. DON'T USE
WATER EXCEPT AS A FOG.
Unusual Fire/Explosion Hazard:REACTS VIOLENTLY W/STRONG OXIDIZING
AGENTS. VAPOR FORMS AN EXPLOSIVE MIXTURE W/AIR BETWEEN UPPER &
LOWER FLAMMABLE LIMITS. COMBUSTIBLE.
================== Accidental Release Measures ==================
Spill Release Procedures:GROUND HANDLING EQUIPMENT. ELIMINATE ALL
IGNITION SOURCES. WEAR PROTECTIVE EQUIPMENT. FLUSH AREA W/WATER TO
REMOVE TRACE RESIDUE. ABSORB RESIDUE OR SMALLS SPILLS W/ABSORBENT
MATERIAL & REMOVE TO NON-L EAKING CONTAINERS FOR DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL/DRY/WELL VENTILATED
AREA. ALUMINUM CONTAINERS ARE NOT RECOMMENDED FOR STORAGE. AVOID
SKIN CONTACT. EMPTY CONTAINERS ARE HAZARDOUS.
Other Precautions:DON'T ALLOW TO ENTER STORM/SANITARY
SEWERS/LAKES/RIVERS/STREAMS/PUBLIC WATERWAYS. BLOCK OFF
DRAINS/DITCHES. SPILL AREA MUST BE CLEANED & RESTORED TO ORIGINAL
CONDITION OR TO THE SATISFACTION OF AUTHOR ITIES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR AN APPROVED ORGANIC CANISTER MASK OR AIR
SUPPLIED RESPIRATOR. MECHANICAL & ELECTRICAL EQUIPMENT SHOULD BE
EXPLOSION-PROOF.
Ventilation:GENERAL: TO CONTROL FUGITIVE EMISSIONS. LOCAL/MECHANICAL:
IN CONFINED SPACES. MAKE-UP AIR: TO BALANCE AIR EXHAUSTED.
Protective Gloves:IMPERVIOUS (BUTYL RUBBER)
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:IMPERVIOUS CLOTHING (APRON, COVERALLS)
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE.
Supplemental Safety and Health
DENSITY: 940 KG/CUBIC METER. EMPTY CONTAINERS ARE HAZARDOUS, MAY
CONTAIN FLAMMABLE/EXPLOSIVE LIQUID RESIDUE/VAPORS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:169C
Vapor Pres:>0.8
Vapor Density:4
Evaporation Rate & Reference:(N-BU AC = 1): 0.12
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS, MOBILE LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AIR, WATER, ACIDS, BASES, OXIDIZING AGENTS (CHLORINE DIOXIDE), ALUMINUM
Stability Condition to Avoid:HEAT, OPEN FLAMES, SPARKS, & OTHER SOURCES
OF IGNITION, HIGH TEMPERATURES.
Hazardous Decomposition Products:CO, CO2, & UNIDENTIFIED ORGANIC
COMPOUNDS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF BY CONTROLLED BURNING OR LANDFILL IN
AN APPROVED SITE. COMBUSTIBLE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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