===================== Product Identification =====================
MSDS NAME:S2002 SODIUM AZIDE
NIIN:00F035181
MSDS Number: BTKMG
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO INC.
Address:1001 WEST SAINTT PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Info Phone Num:414-273-3850/FAX -4979
Emergency Phone Num:414-273-3850, 800-231-8327/325-5832
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
Name:SODIUM AZIDE (SARA III)
CAS:26628-22-8
RTECS #:VY8050000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED BY M.
OSHA PEL:S, C 0.1 PPM(HN3)
ACGIH TLV:C 0.11 PPM; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 27 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE- MAY BE FATAL IF INHALED,
SWALLOWED, OR ABSORBED THROUGH SKIN. MAY CAUSE IRRITATION OF SKIN,
EYES AND MUCOUS MEMBRANES. CHRONIC-MUTAGENIC. TARGET ORGANS:
NERVES, HEART AND BRAIN.
Effects of Overexposure:NAUSEA, HEADACHE, VOMITING, IRRITATION.
Medical Cond Aggravated by Exposure:HEART, BRAIN AND NERVOUS SYSTEM
DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/OXYGEN IF NEEDED.
EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL HELP. SKIN
CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS
PERSIS T. INGESTION:INDUCE VOMITING, DRINK 1-2GLASSES OF WATER. GET
MEDICAL HELP IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL POWDER. DO NOT USE WATER
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR PROTECTIVE CLOTHING
AND SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:EXPLODES WHEN HEATED. AND MAY DECOMPOSE
TOGENERATE TOXIC NITROGEN OXIDES.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR RESPIRATOR, GLOVES. SWEEP
UP OR VACUUM UP AND SAVE IN BAG FOR LATER DISPOSAL. AVOID RAISING
DUST.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A DRY, COOL AREA. KEEP
CONTAINERS TIGHTLY CLOSED. DO NOT USE METAL CONTAINERS.
Other Precautions:MATERIAL IS HEAT SENSITIVE, REACTS WITH HEAVY METALS
(SUCH AS LEAD,COPPER, MERCURY, AND SILVER) TO PRODUCE EXPLOSIVE
COMPOUNDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS IF TLV IS EXCEEDED OR WHEN CREATING DUST.
Ventilation:GENERAL OR MECHANICAL
Protective Gloves:RUBBER
Eye Protection:SAFETY GOGGLES WITH SIDE SHIELDS
Other Protective Equipment:EYEWASH FOUNTAIN, WORK BOOTS, LONG SLEEVS
APRON.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. WASH
HANDS AFTER HANDLING. KEEP AWAY FROM FOOD.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T3
Melt/Freeze Pt:M.P/F.P Text:527F/275C
Spec Gravity:1.85
Solubility in Water:42%
Appearance and Odor:WHITE POWDER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
METALS, ACIDS, ACID CHLORIDES.
Stability Condition to Avoid:SELF-REACTIVE AT ELEVATED TEMPS. CAN REACT
W/SOME METALS, AND DRAIN PIPES, MAKES CMPDS SENSITVE TO
FRICTION,SHOCK,HEAT.
Hazardous Decomposition Products:TOXIC NITROGEN OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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